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๐Ÿ”ฐโ”โ€•โ” PHYSICS WALLAH โ”โ€•โ” ๐Ÿ”ฐ
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โ™ป๏ธImportant Notes - Electrochemical Cellsโ™ป๏ธ


โ–บ An electrochemical cell can convert electrical energy to chemical energy and can also convert electrical energy to chemical energy. There are two types of electrochemical cells- Galvanic cell and Electrolytic cell.

โ–บ Cathodes are usually metal electrodes. It is the electrode where reduction takes place. The cathode is the positive electrode in a galvanic cell and a negative electrode in an electrolytic cell. Electrons move into the cathode.

โ–บ A half-cell is half of an electrochemical cell (electrolytic or galvanic), where either oxidation or reduction occurs. At equilibrium, there is no transfer of electrons across the half cells. Therefore, the potential difference between them is nil.

โ–บ A salt bridge is a device used to connect the oxidation and reduction half-cells of a galvanic cell (a type of electrochemical cell). Strong electrolytes are generally used to make the salt bridges in electrochemical cells. Since ZnSO4 is not a strong electrolyte, it is not used to make salt bridges.

โ–บ Emf of a cell is equal to the maximum potential difference across its electrodes, which occurs when no current is drawn through the cell. It can also be defined as the net voltage between the oxidation and reduction half-reactions.

โ–บ Cell potential is an intensive property as it is independent of the amount of material present. Gibbs free energy is defined for an electrochemical cell and is an extensive property as it depends on the quantity of the material.

โ–บ Electrode potential is the tendency of an electrode to accept or to lose electrons. Electrode potential depends on the nature of the electrode, temperature of the solution and the concentration of metal ions in the solution. It doesnโ€™t depend on the size of the electrode.

โ–บ The salt bridge connects the two half-cell solutions to complete the circuit of the electrochemical cell. The electrolytes of the salt bridge are generally prepared in agar-agar or gelatin so that the electrolytes are kept in a semi-solid phase and do not mix with the half-cell solutions and interfere with the electrochemical reaction.

โ–บ A salt bridge is a junction that connects the anodic and cathodic compartments in a cell or electrolytic solution. It maintains electrical neutrality within the internal circuit, preventing the cell from rapidly running its reaction to equilibrium.

โ–บ A Voltaic or Galvanic cell is a type of electrochemical cell that converts chemical energy into electrical energy. Photovoltaic cells are used to convert light energy into electrical energy. An Electrolytic cell is a type of electrochemical cell that converts electrical energy into chemical energy. A fuel cell is an electrochemical cell that converts the chemical energy of a fuel and an oxidizing agent into electricity.

โ–บ For all spontaneous chemical reactions, the change in Gibbs free energy (ฮ”Gยฐ) is always negative. For a spontaneous reaction in an electrolytic cell, the cell potential (Eยฐcell) should be positive.

โ–บ In an electrochemical cell, when an opposing externally potential is applied and increased slowly, the reaction continues to take place. When the external potential is equal to the potential of the cell, the reaction stops. Once the externally applied potential is greater than the potential of the cell, the reaction goes in the opposite direction and the cell behaves like an electrolytic cell.

โ–บ Primary cells cannot be used again and again. Since there is no fluid inside, these cells are also known as dry cells. The internal resistance is high and the chemical reaction is irreversible. Their initial cost is cheap.

โ–บ A secondary battery (a series of cells) is one which can be charged, discharged into a load, and recharged many times. Nickel-cadmium cell, Lead storage cell and Mercury cell are examples of secondary cells. Leclanche cell is an example of a primary cell.
โญ•๏ธAlgebra - Revision Notes on Permutationsโญ•๏ธ

โž–The concept of permutation is used for the arrangement of objects in a specific order i.e. whenever the order is important, permutation is used.

โž–The total number of permutations on a set of n objects is given by n! and is denoted as nPn = n!

โž–The total number of permutations on a set of n objects taken r at a time is given by nPr = n!/ (n-r)!

โž–The number of ways of arranging n objects of which r are the same is given by n!/ r!

โž–If we wish to arrange a total of n objects, out of which โ€˜pโ€™ are of one type, q of second type are alike, and r of a third kind are same, then such a computation is done as n!/p!q!r!

โž–Al most all permutation questions involve putting things in order from a line where the order matters. For example ABC is a different permutation to ACB.

โž–The number of permutations of n distinct objects when a particular object is not to be considered in the arrangement is given by n-1Pr

โž–The number of permutations of n distinct objects when a specific object is to be always included in the arrangement is given by r.n-1Pr-1.

โž–If we need to compute the number of permutations of n different objects, out of which r have to be selected and each object has the probability of occurring once, twice or thriceโ€ฆ up to r times in any arrangement is given by (n)r.

โž–Circular permutation is used when some arrangement is to be made in the form of a ring or circle.

โž–When โ€˜nโ€™ different or unlike objects are to be arranged in a ring in such a way that the clockwise and anticlockwise arrangements are different, then the number of such arrangements is given by (n โ€“ 1)!

โž–If n persons are to be seated around a round table in such a way that no person has similar neighbor then it is given as ยฝ (n โ€“ 1)!

โž–The number of necklaces formed with n beads of different colors = ยฝ (n โ€“ 1)!

โž–nP0 =1

โž–nP1 = n

โž–nPn = n!/(n-n)! = n! /0! = n! /1= n!
๐ŸŽฏImportant Points of NCERT ๐ŸŽฏ

๐ŸŒŸ1. The world's first National Park (America) โ€“ Yellow stone National Park
๐ŸŒŸ2. India's first National Park โ€“ Jim Corbett National Park โ€“ Nainital (Uttaranchal)
๐ŸŒŸ3. Smallest tiger reserve in India โ€“ Ranthambore National Park - Sawaimadhopur (Rajasthan).
๐ŸŒŸ4. Largest Tiger reserve in India โ€“ Nagarjuna Sagar Saisailum Sanctuary - Guntoor - Andhra Pradesh.
๐ŸŒŸ5. Nandan-Kanan zoo (Bhubaneshwar - Orissa) is known for - White tiger.

๐ŸŒŸSome Important Info.๐ŸŒŸ โœ”๏ธ

(i) National Forest Policy revised in โ€“ 1988.
(ii) Biodiversity act of India was passed by the Parliament in the year-2002
(iii) Forest Actโ€“1927.
(iv) Biosphere Reserve Schemeโ€“ 1986

๐ŸŒŸ2. Wild life protection act 1972 (Revised in 1991) :
โšก๏ธDifference between Fimbriae and Pili

๐Ÿท The fimbriae differ from the pili in the following ways:

ใ€ฝ๏ธPili are fine hair like microfibers having pilin โ€“ a thick tubular structure while the fimbriae are tiny bristle-like fibers emerging from the surface of the bacterial cells

ใ€ฝ๏ธPili are longer than fimbriae
Occurrence of the fimbriae in each cell is about 200-400 while the occurrence of pili are lesser than one to ten every cell

ใ€ฝ๏ธFimbriae are found in the both the gram negative and positive bacteria both, pili are present in the gram negative bacteria only

ใ€ฝ๏ธThe fimbriae are composed of fibrillin protein while the pilin protein makes up the pili

ใ€ฝ๏ธThe fimbriae are less rigid compared to the pili

ใ€ฝ๏ธThe formation of fimbriae is administered by the bacterial genes in the nucleoid area while the pili is administered by the plasmid genes

ใ€ฝ๏ธFimbriae plays a role in attaching cells to the surface while pili are critical in bacterial conjugation
๐™ˆ๐™ค๐™ง๐™ฅ๐™๐™ค๐™ก๐™ค๐™œ๐™ฎ ๐™›๐™ช๐™ง๐™ฉ๐™๐™š๐™ง:-

โšœUnderground Stems:-

The stem of some plants lie below the soil surface. They are non-green, store food as means of perennation and vegetative propagation.

They are of following types:-

(a) Rhizome It is a prostrate thick stem growing horizontally beneath the soil surface. It has distinct nodes and internodes. The. nodes bear small scale leaves with buds in their axils, e.g., Zingiber (ginger officinale), Curcuma domestica (turmeric).

(b) Suckers These are non-green slender stem that grows horizontally in the soil and ultimately comes out to form a new aerial shoot. Each sucker contains one or more nodes with scale leaves and axillary buds, e.g., Mentha (podina), Chrysanthemum (guldaudi).

(c) Corm It is a swollen condensed form of rhizome which grows in the vertical direction in the soil. It stores a large amount of food, e.g., Amorphophallus, Colocasia (taro).

(d) Tuber It is a swollen end of underground stem branches. Each tuber has many notches on the surface called eyes or buds, which grow into new plants, e.g, Solanum tuberosum (potato).

(e) Bulb It is a highly reduced disc like stem. It bears a large number of fibrous adventitious roots at its base. Leaf bases form bulblets. The bulblets grow into new plants, e.g., Allium cepa (onion), Allium sativum (garlic
).
Forwarded from Garima Goel Official
IMP TOPIC ....๐Ÿ”ฅ

Chromosomal Theory of Inheritance ........โ›“๐Ÿงช
Chromosomal theory of inheritance was given by Walter Sutton in 1902. This theory also explains the linear structure of chromosomes with genes in particular sites which was mentioned as loci while Boveri also studied this theory separately. So, this theory is also known as the Boveri-Sutton chromosome theory. According to this theory-

(i) Genes are found at specific locations on the chromosomes.

(ii) During meiosis the homologous chromosomes separate.

(iii) After fertilization the number of chromosomes becomes diploid.

(iv) Chromosomes segregate as well as assort independently.

Mutation...๐Ÿงถ
The sudden changes in the sequence of DNA are known as mutations. The changes in the DNA may be heritable and will be passed onto the next generations affecting both the genotype, as well as the phenotype of an individual. The different types of mutation are frameshift mutations, insertions, deletions, duplications, substitutions, etc. Mutations may be harmful or may not affect at all.

(i) The addition or deletion of DNA bases will lead to changes in the reading frame called the Frameshift mutations.

(ii) The addition of DNA bases is known as insertions.

(iii) Removal of DNA bases is known as deletions.

(iv) If a piece of DNA is copied for more than one time is known as duplication.

Thus, these mutations will lead to a change in the DNA sequence resulting in the formation of the wrong protein
.
Movement and locomotion skeletal system:-

1. Skull bones
2. Vertebral column
3. Sternum
4. Ribs
5. Fore limbs , Hind limbs
6. Girdles
7. Joints
8. Disorders of bones

P.S. hyoid bone is only bone which is not attached with any other one of the body.

Tongue is attached with hyoid boneโœจ ๐ŸŒธ
Chemistry formula
โค๏ธSOME TERMS RELATED TO EVOLUTIONโค๏ธ

๐Ÿ’ Adaptation:

๐Ÿ”ถChanging to fit a niche or survive in an environment

๐Ÿ’ Anatomy:

๐Ÿ”ถStudy of the structures of organisms

๐Ÿ’ Artificial Selection:

๐Ÿ”ถCharacteristics selected by humans

๐Ÿ’ Biogeography:

๐Ÿ”ถStudy of how species are distributed across the Earth

๐Ÿ’ Biological Species:

๐Ÿ”ถIndividuals that can interbreed and produce viable offspring

๐Ÿ’ Catastrophism:

๐Ÿ”ถChanges in species that happen because of quick and often violent natural phenomena

๐Ÿ’ Cladistics:

๐Ÿ”ถMethod of classifying species in groups based on ancestral relationships

๐Ÿ’ Cladogram:

๐Ÿ”ถDiagram of how species are related

๐Ÿ’ Coevolution:

๐Ÿ”ถOne species changing in response to changes in another species that it interacts with, particularly predator/prey relationships

๐Ÿ’ Creationism:

๐Ÿ”ถBelief that a higher power created all life

๐Ÿ’ Darwinism:

๐Ÿ”ถTerm commonly used as a synonym for evolution

๐Ÿ’ Descent With Modification:

๐Ÿ”ถPassing down traits that might change over time

๐Ÿ’ Directional Selection:

๐Ÿ”ถType of natural selection in which an extreme characteristic is favored


๐Ÿ’ Disruptive Selection:

๐Ÿ”ถType of natural selection that favors both extremes and selects against the average characteristics

๐Ÿ’ Embryology:

๐Ÿ”ถStudy of the earliest stages of development of an organism

๐Ÿ’ Endosymbiotic Theory:

๐Ÿ”ถCurrently accepted theory as to how cells evolved

๐Ÿ’ Eukaryote:

๐Ÿ”ถOrganism made of cells that have membrane-bound organelles

๐Ÿ’ Evolution:

๐Ÿ”ถChange in populations over time

๐Ÿ’ Fossil Record:

๐Ÿ”ถAll known traces of past life ever found

๐Ÿ’ Fundamental Niche:

๐Ÿ”ถAll available roles an individual can play in an ecosystem

๐Ÿ’ Genetics:

๐Ÿ”ถStudy of traits and how they are passed down from generation to generation

๐Ÿ’ Gradualism:

๐Ÿ”ถChanges in species that happen over long periods of time

๐Ÿ’ Habitat:

๐Ÿ”ถArea in which an organism lives

๐Ÿ’ Homologous Structures:

๐Ÿ”ถBody parts on different species that are similar and most likely evolved from a common ancestor

๐Ÿ’ Hydrothermal Vents:

๐Ÿ”ถVery hot areas in the ocean where primitive life might have begun

๐Ÿ’ Intelligent Design:

๐Ÿ”ถBelief that a higher power created life and its changes

๐Ÿ’ Macroevolution:

๐Ÿ”ถChanges in populations at the species level, including ancestral relationships

๐Ÿ’ Mass Extinction:

๐Ÿ”ถEvent in which large numbers of species died out completely

๐Ÿ’ Microevolution:

๐Ÿ”ถChanges in species at a molecular or gene level.....
Name Reactions Of Halides๐Ÿ™‚
โœŒ๏ธIMP OF PLANT KINGDOMโœŒ๏ธ

๐Ÿ‘‰Isogamous sexual reproduction in algae- Ulothrix (flagellated)
Spirogyra (non-flagellated)

๐Ÿ‘‰Anisogamous sexual reproduction in algae- Udorina

๐Ÿ‘‰Oogamous sexual reproduction in algae- Volvox, Fucus

๐Ÿ‘‰Algin- Brown Algae

๐Ÿ‘‰Carragreen - Red Algae

๐Ÿ‘‰Agar- Gelidium, Gracilaria
(Red algae)

๐Ÿ‘‰Motile asexual spores in algae- Zoospores

๐Ÿ‘‰Laminarin, Mannitol- Complex carbohydrates of Brown algae

๐Ÿ‘‰Fucoxanthin- Brown Algae

๐Ÿ‘‰Phycoerythrin- Red Algae

๐Ÿ‘‰Floridean Starch Found in Red algae, similar to amylopectin and glycogen

๐Ÿ‘‰The main plant body is a gametophyte- Bryophytes

๐Ÿ‘‰Peat- Sphagnum

๐Ÿ‘‰Microphylls- Selaginella

๐Ÿ‘‰Macrophylls- Fern
๐Ÿ’BORON:
โ€ขIn casting of copper as a dioxidizer
โ€ขBoron rods used in automic reactor.
โ€ขBoron fiber used in bullet proof jacket,
โ€ขIn composite material of aircraft
โ€ขUsed in braintumer therapy.

๐Ÿ’ BORAX:
โ€ขAs a flux for soldring metal.
โ€ขIn borex bead test
โ€ขIn softning of water
โ€ขAntiseptic
โ€ขManufacturing of enamels of glazes, tiles.
โ€ขFor making optical and borosilicals SS.
โ€ขFood preservative

๐Ÿ’ ALUMINIUM:
โ€ข Making house hold, untensils, frames, roof,aircrafts.
โ€ข Electric wire.
โ€ขThermite process (In metallurgy of Cr, Mn, Fe)
โ€ขFor transportin nitric acid.
โ€ขAI, Hg used as reducing agent.
โ€ขAluminium powder + Ammonium nitrate.

๐Ÿ’ LEAD [Pb]:
โ€ขIn making telegraph and telephone wires
โ€ขMaking bullets
โ€ขMaking chamber in HSO, process.

๐Ÿ’ NITROGEN:
โ€ขIn the manufacturing of HNO3, NH3, CaCN2.
โ€ขLiquid nitrogen used as refrigrant.
โ€ขInert atmosphere in metallurgy.
โ€ขGas thermometer and electrical bulb

๐Ÿ’ NH3:
โ€ข Refrigeration
โ€ขManufacturing HNO3, NaHCO3
โ€ขArtificial Silk.
โ€ข Urea Formation
โ€ขFor solvent

๐Ÿ’ HNO3:
โ€ข Manufacturing of ammonium nitrateas fertilizer.
โ€ขIn explosive
โ€ข For making nitroglycerine.
โ€ข Making TNT.
โ€ข Pickling against of stainless steel.
โ€ข Etching of Metal
โ€ขOxidizer in rocket fule
.
Important Points For NEET ๐ŸŒŸ

Evidences from comparative morphology and anatomy :-

โšก๏ธExamples of homologous organs:โšก๏ธ

(i) Forelimbs of mammals
(ii) Thorn of Bougainvillea and tendril of Cucurbita both are modification of axillary bud.
(iii)Vertebrate hearts or brains
(iv)Mouth parts of insects :
Cockroach Honey bee Mosquito
(Biting & chewing) (Chewing & lapping) (Piercing & Sucking)
(v) Testes in male and ovaries in female
(vi) Potato and Ginger - both are modified shoot
(vii) Radish and Carrot - both are modified roots

โšก๏ธExamples of Analogous organs :โšก๏ธ

(i) Wings of butterfly and birds
(ii) Eye of the octopus and of mammals
(iii) Flippers of Penguins and Dolphins
(iv) Sweet potato (root modification) and potato (stem modification)
(v) Sting of bee and scorpion
(vi) Chloragogen cells of earthworm and liver of vertebrates
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