Chemistry booster series
A. Diborane has two 3-centre-2-electron bonds B. All BโH bonds in diborane are equivalent C. Boranes are electron-deficient compounds D. Terminal BโH bonds are longer than bridge BโH bonds ๐ Correct option(s): 1๏ธโฃ A and C 2๏ธโฃ A, B and C 3๏ธโฃ B and D 4๏ธโฃ A,โฆ
โ Answer: Option 1 (A and C)
Diborane me 2 banana bonds โ
Terminal & bridge bonds same nahi โ
Boranes electron-deficient โ
Bridge bonds longer hote hain โ
โ Answer: Option 2 (B, C and D)
Lewis acidity: BFโ < BClโ < BBrโ < BIโ โ
AlClโ = Lewis acid โ
BFโ hydrolysis nahi karta โ (others karte)
A statement ulta likha โ
โ Answer: Option 2 (A, B and C)
BโOโ acidic โ
AlโOโ amphoteric โ
TlโOโ basic โ
Basic character increase hota hai down the group โ
๐4๐3๐1
#ELECTROMAGNETICRADIATION
Electromagnetic radiation is a form of energy propagated as waves with electric and magnetic fields oscillating perpendicular to each other.
#๏ธโฃ 1๏ธโฃ Characteristics of EM Radiation
โญ Wave Nature
โ๏ธ Travels in space as waves
โ๏ธ Characterized by wavelength (ฮป), frequency (ฮฝ), speed (c)
โ๏ธ Relationship: c = ฮปฮฝ
โญ Particle Nature
โ๏ธ Light also behaves as particles (photons)
โ๏ธ Energy of photon: E = hฮฝ
โ๏ธ Momentum of photon: p = h/ฮป
๐ Constants
โ๏ธ h = Planckโs constant = 6.626 ร 10โปยณโด Jยทs
โ๏ธ c = speed of light = 3 ร 10โธ m/s
๐ Constants
โ๏ธ h = Planckโs constant = 6.626 ร 10โปยณโด Jยทs
โ๏ธ c = speed of light = 3 ร 10โธ m/s
2#TypesofElectromagneticRadiation (NCERT)
๐ Order of increasing wavelength / decreasing frequency:
ฮณ-rays < X-rays < UV < Visible < IR < Microwaves < Radio waves
โ๏ธ UV, Visible, IR โ Important in Atomic Spectra
3๏ธโฃ #ImportantRelations (Atom Chapter)
โ๏ธ Energy of photon: E = hฮฝ = hc/ฮป
โ๏ธ Frequency & wavelength inversely proportional: ฮฝ = c/ฮป
4๏ธโฃ #NEETIMPORTANTPOINTS โญ
โ๏ธ EM radiation has dual nature โ wave + particle
โ๏ธ Wave nature โ explains interference, diffraction, refraction
โ๏ธ Particle nature โ explains photoelectric effect, Compton effect
โ๏ธ Photon energy proportional to frequency (E โ ฮฝ)
@Ayano1me @Neetugpoll @Neetugquiz
Electromagnetic radiation is a form of energy propagated as waves with electric and magnetic fields oscillating perpendicular to each other.
#๏ธโฃ 1๏ธโฃ Characteristics of EM Radiation
โญ Wave Nature
โ๏ธ Travels in space as waves
โ๏ธ Characterized by wavelength (ฮป), frequency (ฮฝ), speed (c)
โ๏ธ Relationship: c = ฮปฮฝ
โญ Particle Nature
โ๏ธ Light also behaves as particles (photons)
โ๏ธ Energy of photon: E = hฮฝ
โ๏ธ Momentum of photon: p = h/ฮป
๐ Constants
โ๏ธ h = Planckโs constant = 6.626 ร 10โปยณโด Jยทs
โ๏ธ c = speed of light = 3 ร 10โธ m/s
๐ Constants
โ๏ธ h = Planckโs constant = 6.626 ร 10โปยณโด Jยทs
โ๏ธ c = speed of light = 3 ร 10โธ m/s
2#TypesofElectromagneticRadiation (NCERT)
๐ Order of increasing wavelength / decreasing frequency:
ฮณ-rays < X-rays < UV < Visible < IR < Microwaves < Radio waves
โ๏ธ UV, Visible, IR โ Important in Atomic Spectra
3๏ธโฃ #ImportantRelations (Atom Chapter)
โ๏ธ Energy of photon: E = hฮฝ = hc/ฮป
โ๏ธ Frequency & wavelength inversely proportional: ฮฝ = c/ฮป
4๏ธโฃ #NEETIMPORTANTPOINTS โญ
โ๏ธ EM radiation has dual nature โ wave + particle
โ๏ธ Wave nature โ explains interference, diffraction, refraction
โ๏ธ Particle nature โ explains photoelectric effect, Compton effect
โ๏ธ Photon energy proportional to frequency (E โ ฮฝ)
@Ayano1me @Neetugpoll @Neetugquiz
โค5๐3๐1
#PBLOCK ELEMENTSGROUP 14 (CARBON FAMILY)
Elements: C, Si, Ge, Sn, Pb
โ๏ธ General electronic configuration: nsยฒ npยฒ
โ๏ธ Valency: 4
โ๏ธ Oxidation states: +4, +2
๐ Stability of +2 state increases down the group (inert pair effect)
1๏ธโฃ #PHYSICALPROPERTIES
โญ Atomic & Ionic Radii
โ๏ธ Increases down the group (C < Si < Ge < Sn < Pb)
โญ Ionisation Enthalpy
โ๏ธ Decreases down the group
๐ Carbon has very high IE โ strong covalent bonding
โญ Electronegativity
โ๏ธ Decreases down the group
๐ C highest, Pb lowest
โญ Catenation (NEET HOT ๐ฅ)
โ๏ธ Ability to form long chains
๐ Order: C >> Si > Ge > Sn > Pb
๐ Strong CโC bond + small size
2๏ธโฃ #ALLOTROPY
โญ Carbon Allotropes
โ๏ธ Crystalline โ Diamond, Graphite, Fullerene
โ๏ธ Amorphous โ Coal, Coke, Charcoal
๐ Diamond
โ๏ธ spยณ hybridised
โ๏ธ Hardest substance
โ๏ธ Electrical insulator
๐ Graphite
โ๏ธ spยฒ hybridised
โ๏ธ Good conductor of electricity
โ๏ธ Layered structure
3๏ธโฃ #CHEMICALPROPERTIES
โญ Oxidation States
โ๏ธ C, Si โ mainly +4
โ๏ธ Ge, Sn, Pb โ +2 & +4
๐ +2 becomes more stable down the group (inert pair effect)
โญ Inert Pair Effect
โ๏ธ nsยฒ electrons do not participate in bonding
๐ Maximum in Pb โ Pbยฒโบ more stable than Pbโดโบ
4๏ธโฃ #HYDRIDES (EHโ)
โ๏ธ CHโ, SiHโ, GeHโ, SnHโ
๐ Trend:
โ๏ธ Thermal stability โ down the group
โ๏ธ Reducing character โ down the group
5๏ธโฃ #HALIDES (MXโ / MXโ)
โญ Tetrahalides (MXโ)
โ๏ธ CClโ, SiClโ โ covalent
โ๏ธ Stability โ down the group
โญ Dihalides (MXโ)
โ๏ธ SnClโ, PbClโ โ more stable down the group
๐ Due to inert pair effect
๐ PbClโ unstable, PbClโ stable
6๏ธโฃ #OXIDES (IMPORTANT ๐ฅ)
โ๏ธ COโ, SiOโ โ Acidic
โ๏ธ GeOโ โ Weakly acidic
โ๏ธ SnOโ โ Amphoteric
โ๏ธ PbO โ Amphoteric / basic
๐ Acidity decreases down the group
7๏ธโฃ #CARBONSPECIALCASE
โญ Shows maximum catenation
โญ Forms multiple bonds (C=C, CโกC)
โญ Large number of organic compounds
โญ No d-orbitals โ strong ฯ bonding
8๏ธโฃ #COMPARISON ( NEET MCQ)
Property :Carbon :Lead
Catenation :Maximum :Negligible
Oxidation state :+4 :+2 more stable
Nature of oxide :Acidic :Amphoteric
Inert pair effect :Absent :Maximum
โ ๏ธ #NCERTLINES
โ Pbโดโบ more stable than Pbยฒโบ โ WRONG
โ๏ธ CClโ does NOT hydrolyse
โ๏ธ SiClโ hydrolyses easily
โ๏ธ Graphite conducts electricity, diamond does not
@Ayano1me @Neetugpoll @Neetugquiz
Elements: C, Si, Ge, Sn, Pb
โ๏ธ General electronic configuration: nsยฒ npยฒ
โ๏ธ Valency: 4
โ๏ธ Oxidation states: +4, +2
๐ Stability of +2 state increases down the group (inert pair effect)
1๏ธโฃ #PHYSICALPROPERTIES
โญ Atomic & Ionic Radii
โ๏ธ Increases down the group (C < Si < Ge < Sn < Pb)
โญ Ionisation Enthalpy
โ๏ธ Decreases down the group
๐ Carbon has very high IE โ strong covalent bonding
โญ Electronegativity
โ๏ธ Decreases down the group
๐ C highest, Pb lowest
โญ Catenation (NEET HOT ๐ฅ)
โ๏ธ Ability to form long chains
๐ Order: C >> Si > Ge > Sn > Pb
๐ Strong CโC bond + small size
2๏ธโฃ #ALLOTROPY
โญ Carbon Allotropes
โ๏ธ Crystalline โ Diamond, Graphite, Fullerene
โ๏ธ Amorphous โ Coal, Coke, Charcoal
๐ Diamond
โ๏ธ spยณ hybridised
โ๏ธ Hardest substance
โ๏ธ Electrical insulator
๐ Graphite
โ๏ธ spยฒ hybridised
โ๏ธ Good conductor of electricity
โ๏ธ Layered structure
3๏ธโฃ #CHEMICALPROPERTIES
โญ Oxidation States
โ๏ธ C, Si โ mainly +4
โ๏ธ Ge, Sn, Pb โ +2 & +4
๐ +2 becomes more stable down the group (inert pair effect)
โญ Inert Pair Effect
โ๏ธ nsยฒ electrons do not participate in bonding
๐ Maximum in Pb โ Pbยฒโบ more stable than Pbโดโบ
4๏ธโฃ #HYDRIDES (EHโ)
โ๏ธ CHโ, SiHโ, GeHโ, SnHโ
๐ Trend:
โ๏ธ Thermal stability โ down the group
โ๏ธ Reducing character โ down the group
5๏ธโฃ #HALIDES (MXโ / MXโ)
โญ Tetrahalides (MXโ)
โ๏ธ CClโ, SiClโ โ covalent
โ๏ธ Stability โ down the group
โญ Dihalides (MXโ)
โ๏ธ SnClโ, PbClโ โ more stable down the group
๐ Due to inert pair effect
๐ PbClโ unstable, PbClโ stable
6๏ธโฃ #OXIDES (IMPORTANT ๐ฅ)
โ๏ธ COโ, SiOโ โ Acidic
โ๏ธ GeOโ โ Weakly acidic
โ๏ธ SnOโ โ Amphoteric
โ๏ธ PbO โ Amphoteric / basic
๐ Acidity decreases down the group
7๏ธโฃ #CARBONSPECIALCASE
โญ Shows maximum catenation
โญ Forms multiple bonds (C=C, CโกC)
โญ Large number of organic compounds
โญ No d-orbitals โ strong ฯ bonding
8๏ธโฃ #COMPARISON ( NEET MCQ)
Property :Carbon :Lead
Catenation :Maximum :Negligible
Oxidation state :+4 :+2 more stable
Nature of oxide :Acidic :Amphoteric
Inert pair effect :Absent :Maximum
โ ๏ธ #NCERTLINES
โ Pbโดโบ more stable than Pbยฒโบ โ WRONG
โ๏ธ CClโ does NOT hydrolyse
โ๏ธ SiClโ hydrolyses easily
โ๏ธ Graphite conducts electricity, diamond does not
@Ayano1me @Neetugpoll @Neetugquiz
โค4๐2๐1๐ณ1
Chemistry booster series pinned ยซ๐ง๐ข๐ฃ ๐ฎ๐ฌ ๐๐๐๐ ๐ช๐๐๐๐๐ง๐๐๐ ๐ง๐ข๐ฃ๐๐๐ฆ โ ๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ โญ #๐ฃ๐๐ฌ๐ฆ๐๐๐๐๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ ๐๐๐๐ฃ๐ง๐๐ฅ ๐ญ: ๐ฆ๐ข๐๐จ๐ง๐๐ข๐ก โญ ๐๐๐๐๐ ๐ฆ๐ข๐๐จ๐ง๐๐ข๐ก โญ ๐๐ข๐๐๐๐๐๐ง๐๐ฉ๐ ๐ฃ๐ฅ๐ข๐ฃ๐๐ฅ๐ง๐๐๐ฆ ๐๐๐๐ฃ๐ง๐๐ฅ ๐ฎ๐๐๐๐๐ง๐ฅ๐ข๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ โญ ๐ก๐๐ฅ๐ก๐ฆ๐ง ๐๐ค๐จ๐๐ง๐๐ข๐ก โญ ๐๐ข๐ก๐๐จ๐๐ง๐๐ฉ๐๐ง๐ฌ ๐๐๐๐ฃ๐ง๐๐ฅ ๐ฏ: ๐๐๐๐ ๐๐๐๐ ๐๐๐ก๐๐ง๐๐๐ฆ โญ ๐๐๐ฅ๐ฆ๐ง ๐ข๐ฅ๐๐๐ฅ ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ โญ ๐๐ฅ๐ฅ๐๐๐ก๐๐จ๐ฆโฆยป
Chemistry booster series
๐ง๐ข๐ฃ ๐ฎ๐ฌ ๐๐๐๐ ๐ช๐๐๐๐๐ง๐๐๐ ๐ง๐ข๐ฃ๐๐๐ฆ โ ๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ โญ #๐ฃ๐๐ฌ๐ฆ๐๐๐๐๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ ๐๐๐๐ฃ๐ง๐๐ฅ ๐ญ: ๐ฆ๐ข๐๐จ๐ง๐๐ข๐ก โญ ๐๐๐๐๐ ๐ฆ๐ข๐๐จ๐ง๐๐ข๐ก โญ ๐๐ข๐๐๐๐๐๐ง๐๐ฉ๐ ๐ฃ๐ฅ๐ข๐ฃ๐๐ฅ๐ง๐๐๐ฆ ๐๐๐๐ฃ๐ง๐๐ฅ ๐ฎ๐๐๐๐๐ง๐ฅ๐ข๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ โญ ๐ก๐๐ฅ๐ก๐ฆ๐ง ๐๐ค๐จ๐๐ง๐๐ข๐ก โญ ๐๐ข๐ก๐๐จ๐๐ง๐๐ฉ๐๐ง๐ฌ ๐๐๐๐ฃ๐ง๐๐ฅ ๐ฏ: ๐๐๐๐ ๐๐๐๐ ๐๐๐ก๐๐ง๐๐๐ฆ โญ ๐๐๐ฅ๐ฆ๐ง ๐ข๐ฅ๐๐๐ฅ ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ โญ ๐๐ฅ๐ฅ๐๐๐ก๐๐จ๐ฆโฆ
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Or jo jo topic ka revision ka mood ๐ถh krlo read
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๐ฅฐ4๐4โคโ๐ฅ1๐ฏ1
โค5๐2๐1
#BOHRMODELOFHYDROGENATOM
Proposed by Niels Bohr (1913) to explain the line spectrum of hydrogen.
1. #POSTULATES OF BOHR MODEL
โ๏ธ Atom has a small, positively charged nucleus at the centre
โ๏ธ Electron revolves around nucleus in fixed circular orbits (stationary states)
โ๏ธ Each orbit has a definite energy
โ๏ธ Electron does not radiate energy while revolving in a permitted orbit
๐ Allowed orbits โ n = 1, 2, 3, 4โฆ
โ๏ธ Angular momentum of electron is quantised:
๐ mvr = n(h / 2ฯ)
2. #ENERGYOFELECTRON IN HYDROGEN ATOM
โ๏ธ Energy of electron in nth orbit:
๐ Eโ = โ13.6 / nยฒ eV
โ๏ธ Negative sign โ electron is bound to nucleus
๐ Ground state (n = 1):
Eโ = โ13.6 eV
๐ Excited state (n > 1):
Energy becomes less negative
3. #RADIUSOFBOHRORBIT
โ๏ธ Radius of nth orbit:
๐ rโ = 0.529 ร nยฒ ร
๐ For ground state (n = 1):
rโ = 0.529 ร
โ๏ธ Radius increases as nยฒ
4. #SPECTRALLINES (EMISSION & ABSORPTION)
โ๏ธ Electron jumps from higher to lower orbit โ emission of energy
โ๏ธ Electron jumps from lower to higher orbit โ absorption of energy
๐ Energy difference:
๐ ฮE = Eโ โ Eโ = hฮฝ
5 #HYDROGENEMISSION SPECTRUM (IMPORTANT )
โ๏ธ Spectrum consists of discrete lines
๐ Series based on final orbit:
Slines :Final n :Region
Lyman: 1 :UV
Balmer :2 :Visible
Paschen :3 :IR
Brackett :4 :IR
Pfund :5 :IR
๐ Balmer series โ only visible series
6. #RYDBERGEQUATION
โ๏ธ Explains wavelength of spectral lines:
๐ 1/ฮป = R (1/nโยฒ โ 1/nโยฒ)
โ๏ธ nโ > nโ
๐ R = 1.097 ร 10โท mโปยน
7. #SUCCESSOFBOHRMODEL
โ๏ธ Explains hydrogen line spectrum
โ๏ธ Explains stability of hydrogen atom
โ๏ธ Gives correct values of energy & radius for H atom
8. #LIMITATIONSOFBOHRMODEL (VERY IMP โ ๏ธ)
โ Cannot explain spectra of multi-electron atoms
โ Cannot explain Zeeman effect
โ Cannot explain Stark effect
โ Violates Heisenberg uncertainty principle
9. #NCERT ONELINEFACTS (NEET DIRECT)
โ๏ธ Valid only for one-electron systems (H, Heโบ, Liยฒโบ)
โ๏ธ Energy levels are quantised
โ๏ธ Lower n โ more stability
โ๏ธ Higher n โ larger orbit, higher energy
#IMP
Electron radiates energy in stationary orbit โ WRONG
โ๏ธ Ground state has minimum energy
โ๏ธ Transition n=3 โ n=2 โ Balmer series
@Ayano1me @Neetugpoll @Neetugquiz
Proposed by Niels Bohr (1913) to explain the line spectrum of hydrogen.
1. #POSTULATES OF BOHR MODEL
โ๏ธ Atom has a small, positively charged nucleus at the centre
โ๏ธ Electron revolves around nucleus in fixed circular orbits (stationary states)
โ๏ธ Each orbit has a definite energy
โ๏ธ Electron does not radiate energy while revolving in a permitted orbit
๐ Allowed orbits โ n = 1, 2, 3, 4โฆ
โ๏ธ Angular momentum of electron is quantised:
๐ mvr = n(h / 2ฯ)
2. #ENERGYOFELECTRON IN HYDROGEN ATOM
โ๏ธ Energy of electron in nth orbit:
๐ Eโ = โ13.6 / nยฒ eV
โ๏ธ Negative sign โ electron is bound to nucleus
๐ Ground state (n = 1):
Eโ = โ13.6 eV
๐ Excited state (n > 1):
Energy becomes less negative
3. #RADIUSOFBOHRORBIT
โ๏ธ Radius of nth orbit:
๐ rโ = 0.529 ร nยฒ ร
๐ For ground state (n = 1):
rโ = 0.529 ร
โ๏ธ Radius increases as nยฒ
4. #SPECTRALLINES (EMISSION & ABSORPTION)
โ๏ธ Electron jumps from higher to lower orbit โ emission of energy
โ๏ธ Electron jumps from lower to higher orbit โ absorption of energy
๐ Energy difference:
๐ ฮE = Eโ โ Eโ = hฮฝ
5 #HYDROGENEMISSION SPECTRUM (IMPORTANT )
โ๏ธ Spectrum consists of discrete lines
๐ Series based on final orbit:
Slines :Final n :Region
Lyman: 1 :UV
Balmer :2 :Visible
Paschen :3 :IR
Brackett :4 :IR
Pfund :5 :IR
๐ Balmer series โ only visible series
6. #RYDBERGEQUATION
โ๏ธ Explains wavelength of spectral lines:
๐ 1/ฮป = R (1/nโยฒ โ 1/nโยฒ)
โ๏ธ nโ > nโ
๐ R = 1.097 ร 10โท mโปยน
7. #SUCCESSOFBOHRMODEL
โ๏ธ Explains hydrogen line spectrum
โ๏ธ Explains stability of hydrogen atom
โ๏ธ Gives correct values of energy & radius for H atom
8. #LIMITATIONSOFBOHRMODEL (VERY IMP โ ๏ธ)
โ Cannot explain spectra of multi-electron atoms
โ Cannot explain Zeeman effect
โ Cannot explain Stark effect
โ Violates Heisenberg uncertainty principle
9. #NCERT ONELINEFACTS (NEET DIRECT)
โ๏ธ Valid only for one-electron systems (H, Heโบ, Liยฒโบ)
โ๏ธ Energy levels are quantised
โ๏ธ Lower n โ more stability
โ๏ธ Higher n โ larger orbit, higher energy
#IMP
Electron radiates energy in stationary orbit โ WRONG
โ๏ธ Ground state has minimum energy
โ๏ธ Transition n=3 โ n=2 โ Balmer series
@Ayano1me @Neetugpoll @Neetugquiz
โค5โคโ๐ฅ3๐1๐ฏ1๐1
1๏ธโฃ #PBLOCKGROUP15 โญ (Nitrogen Family / Pnictogens)
๐ Group members:
โ๏ธ Nitrogen (N)
โ๏ธ Phosphorus (P)
โ๏ธ Arsenic (As)
โ๏ธ Antimony (Sb)
โ๏ธ Bismuth (Bi)
๐ General electronic configuration:
โ๏ธ nsยฒ npยณ
NEET point:
โ๏ธ 5 valence electrons โ trivalent nature common
2๏ธโฃ #GENERALTRENDS โญ
๐ Atomic & ionic size:
โ๏ธ Increases down the group
๐ Ionisation enthalpy:
โ๏ธ Decreases down the group
โ๏ธ Nitrogen โ highest (small size)
๐ Electronegativity:
โ๏ธ Decreases down the group
๐ Metallic character:
โ๏ธ Increases down the group
โ๏ธ N & P โ non-metals
โ๏ธ As & Sb โ metalloids
โ๏ธ Bi โ metal
3๏ธโฃ #OXIDATIONSTATES โญ
โ๏ธ Common oxidation states: โ3, +3, +5
๐ Trends:
โ๏ธ โ3 โ stability decreases down the group
โ๏ธ +5 โ stability decreases down the group
โ๏ธ +3 โ stability increases down the group
๐ง Reason:
โ๏ธ Inert pair effect increases down the group
๐ Examples:
โ๏ธ NโOโ โ +5 (stable)
โ๏ธ Biยณโบ โ more stable than Biโตโบ
4๏ธโฃ #HYDRIDES (NHโ TYPE) โญ
๐ General formula:
โ๏ธ EHโ
๐ Bond angle:
โ๏ธ NHโ > PHโ > AsHโ > SbHโ > BiHโ
๐ Basic nature:
โ๏ธ NHโ โ most basic
โ๏ธ Basicity decreases down the group
Reason:
โ๏ธ Lone pair availability decreases
๐ Thermal stability:
โ๏ธ Decreases down the group
5๏ธโฃ #OXIDES โญ
โ๏ธ Form EโOโ and EโOโ
๐ Nature of oxides:
โ๏ธ NโOโ , PโOโ โ acidic
โ๏ธ AsโOโ โ amphoteric
โ๏ธ BiโOโ โ basic
Trend:
โ๏ธ Acidic โ basic character increases down the group
6๏ธโฃ #HALIDES โญ
๐ Trihalides (EXโ):
โ๏ธ All elements form EXโ
๐ Pentahalides (EXโ ):
โ๏ธ Formed by P, As, Sb
โ๏ธ Nitrogen โ (no d-orbitals)
โ๏ธ Bi โ (inert pair effect)
Important:
โ๏ธ PClโ โ exists as solid (ionic) & gas (covalent)
7๏ธโฃ #ANOMALOUSBEHAVIOUROFNITROGEN โญ
โ๏ธ Small size
โ๏ธ High electronegativity
โ๏ธ High ionisation enthalpy
โ๏ธ Absence of d-orbitals
๐ Results:
โ๏ธ Nโ has strong triple bond
โ๏ธ Limited oxidation states
โ๏ธ Different properties from rest of group
8๏ธโฃ #IMPORTANTCOMPOUNDS
โ๏ธ Ammonia (NHโ):
โข Basic gas
โข Forms hydrogen bonding
โ๏ธ Phosphine (PHโ):
โข Weak base
โข Toxic gas
โ๏ธ PโOโ :
Strong dehydrating agent
#NEETTAKEAWAY
โ๏ธ Inert pair effect โ key to oxidation states
โ๏ธ NHโ strongest base in group
โ๏ธ Acidic โ basic oxide trend important
โ๏ธ Nitrogen always exceptional
@Ayano1me @Neetugpoll @Neetugquiz
๐ Group members:
โ๏ธ Nitrogen (N)
โ๏ธ Phosphorus (P)
โ๏ธ Arsenic (As)
โ๏ธ Antimony (Sb)
โ๏ธ Bismuth (Bi)
๐ General electronic configuration:
โ๏ธ nsยฒ npยณ
NEET point:
โ๏ธ 5 valence electrons โ trivalent nature common
2๏ธโฃ #GENERALTRENDS โญ
๐ Atomic & ionic size:
โ๏ธ Increases down the group
๐ Ionisation enthalpy:
โ๏ธ Decreases down the group
โ๏ธ Nitrogen โ highest (small size)
๐ Electronegativity:
โ๏ธ Decreases down the group
๐ Metallic character:
โ๏ธ Increases down the group
โ๏ธ N & P โ non-metals
โ๏ธ As & Sb โ metalloids
โ๏ธ Bi โ metal
3๏ธโฃ #OXIDATIONSTATES โญ
โ๏ธ Common oxidation states: โ3, +3, +5
๐ Trends:
โ๏ธ โ3 โ stability decreases down the group
โ๏ธ +5 โ stability decreases down the group
โ๏ธ +3 โ stability increases down the group
๐ง Reason:
โ๏ธ Inert pair effect increases down the group
๐ Examples:
โ๏ธ NโOโ โ +5 (stable)
โ๏ธ Biยณโบ โ more stable than Biโตโบ
4๏ธโฃ #HYDRIDES (NHโ TYPE) โญ
๐ General formula:
โ๏ธ EHโ
๐ Bond angle:
โ๏ธ NHโ > PHโ > AsHโ > SbHโ > BiHโ
๐ Basic nature:
โ๏ธ NHโ โ most basic
โ๏ธ Basicity decreases down the group
Reason:
โ๏ธ Lone pair availability decreases
๐ Thermal stability:
โ๏ธ Decreases down the group
5๏ธโฃ #OXIDES โญ
โ๏ธ Form EโOโ and EโOโ
๐ Nature of oxides:
โ๏ธ NโOโ , PโOโ โ acidic
โ๏ธ AsโOโ โ amphoteric
โ๏ธ BiโOโ โ basic
Trend:
โ๏ธ Acidic โ basic character increases down the group
6๏ธโฃ #HALIDES โญ
๐ Trihalides (EXโ):
โ๏ธ All elements form EXโ
๐ Pentahalides (EXโ ):
โ๏ธ Formed by P, As, Sb
โ๏ธ Nitrogen โ (no d-orbitals)
โ๏ธ Bi โ (inert pair effect)
Important:
โ๏ธ PClโ โ exists as solid (ionic) & gas (covalent)
7๏ธโฃ #ANOMALOUSBEHAVIOUROFNITROGEN โญ
โ๏ธ Small size
โ๏ธ High electronegativity
โ๏ธ High ionisation enthalpy
โ๏ธ Absence of d-orbitals
๐ Results:
โ๏ธ Nโ has strong triple bond
โ๏ธ Limited oxidation states
โ๏ธ Different properties from rest of group
8๏ธโฃ #IMPORTANTCOMPOUNDS
โ๏ธ Ammonia (NHโ):
โข Basic gas
โข Forms hydrogen bonding
โ๏ธ Phosphine (PHโ):
โข Weak base
โข Toxic gas
โ๏ธ PโOโ :
Strong dehydrating agent
#NEETTAKEAWAY
โ๏ธ Inert pair effect โ key to oxidation states
โ๏ธ NHโ strongest base in group
โ๏ธ Acidic โ basic oxide trend important
โ๏ธ Nitrogen always exceptional
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅ3๐3โค1๐1๐1
๐พ๐๐๐ข๐๐จ๐ฉ๐ง๐ฎ ๐๐๐ฃ๐ ๐ฝ๐ค๐ค๐จ๐ฉ๐๐ง ๐๐๐โ๐ ๐พ๐๐ผ๐พ๐ ๐๐ ๐๐๐๐๐ โ๏ธ ๐๐๐ฎ ๐ฉ๐ค ๐จ๐ช๐๐๐๐จ๐จ:
1๏ธโฃ #PERIODICCLASSIFICATIONOFELEMENTS โญ
โ๏ธ Elements ko increasing atomic number ke order me arrange karna
โ๏ธ Purpose โ study of properties in a systematic way
๐ Modern periodic law:
โ๏ธ Physical & chemical properties of elements are periodic functions of their atomic numbers
#NEETpoint:
โ๏ธ Atomic number (Z) is basis, not atomic mass
2๏ธโฃ #HISTORICALDEVELOPMENT โญ
โ๏ธ Dobereinerโs Triads
โข Middle element mass โ average of other two
โ๏ธ Newlandsโ Law of Octaves
โข Every 8th element similar properties
โ๏ธ Mendeleevโs Periodic Table
โข Based on atomic mass
โข Left gaps for undiscovered elements
โ๏ธ Modern Periodic Table (Moseley)
โข Based on atomic number
#NEETIMP
โ๏ธ Anomalies of Mendeleev solved by modern table
3๏ธโฃ #MODERNPERIODICTABLE โญ
๐ Structure:
โ๏ธ 7 periods (horizontal rows)
โ๏ธ 18 groups (vertical columns)
๐ Blocks:
โ๏ธ s-block
โ๏ธ p-block
โ๏ธ d-block
โ๏ธ f-block
#NEETpoint:
โ๏ธ Period number = highest principal quantum number (n)
4๏ธโฃ #PERIODICITYINPROPERTIES โญ
โ๏ธ Repetition of properties at regular intervals
๐ Important properties:
โ๏ธ Atomic radius
โ๏ธ Ionisation enthalpy
โ๏ธ Electron affinity
โ๏ธ Electronegativity
โ๏ธ Metallic & non-metallic character
5๏ธโฃ #ATOMICRADIUS โญ
๐ Trend:
โ๏ธ Decreases across a period โ left to right
โ๏ธ Increases down a group
#Reason:
โ๏ธ Effective nuclear charge โ across period
โ๏ธ New shell added down the group
๐ Ionic radius:
โ๏ธ Cation < atom
โ๏ธ Anion > atom
6๏ธโฃ #IONISATIONENTHALPY โญ
โ๏ธ Energy required to remove an electron
๐ Trend:
โ๏ธ Increases across a period
โ๏ธ Decreases down a group
#Exceptions (NEET favourite ๐ฅ):
โ๏ธ Be > B
โ๏ธ N > O
7๏ธโฃ #ELECTRONAFFINITY โญ
โ๏ธ Energy released when electron is added
๐ Trend:
โ๏ธ Increases across a period
โ๏ธ Decreases down a group
#NEETpoint:
โ๏ธ Halogens โ highest electron affinity
โ๏ธ Noble gases โ ~0
8๏ธโฃ #ELECTRONEGATIVITY โญ
โ๏ธ Tendency to attract shared electron pair
๐ Trend:
โ๏ธ Increases across a period
โ๏ธ Decreases down a group
โญNEETpoint:
โ๏ธ Fluorine โ most electronegative
9๏ธโฃ #METALLICCHARACTER โญ
๐ Trend:
โ๏ธ Decreases across a period
โ๏ธ Increases down a group
โญNEETclarity:
โ๏ธ Metals โ lose electrons
โ๏ธ Non-metals โ gain electrons
๐ #ANOMALOUSBEHAVIOUR โญ
โ๏ธ First element of each group shows different properties
๐ Reason:
โ๏ธ Small size
โ๏ธ High electronegativity
โ๏ธ Absence of d-orbitals
โญExample:
โ๏ธ Li โ Na
โ๏ธ Be โ Mg
1๏ธโฃ1๏ธโฃ #NEETONELINERS๐ฅ
โ๏ธ Basis of modern periodic table โ atomic number
โ๏ธ Periodicity due to electronic configuration
โ๏ธ s-block โ highly electropositive
โ๏ธ p-block โ variable oxidation states
โ๏ธ d-block โ transition elements
1๏ธโฃ2๏ธโฃ #SUMMARY โญ
โ๏ธ Periodic table = map of chemistry
โ๏ธ Trends help predict properties
โ๏ธ Exceptions are more important for NEET
@Ayano1me @Neetugpoll @Neetugquiz
1๏ธโฃ #PERIODICCLASSIFICATIONOFELEMENTS โญ
โ๏ธ Elements ko increasing atomic number ke order me arrange karna
โ๏ธ Purpose โ study of properties in a systematic way
๐ Modern periodic law:
โ๏ธ Physical & chemical properties of elements are periodic functions of their atomic numbers
#NEETpoint:
โ๏ธ Atomic number (Z) is basis, not atomic mass
2๏ธโฃ #HISTORICALDEVELOPMENT โญ
โ๏ธ Dobereinerโs Triads
โข Middle element mass โ average of other two
โ๏ธ Newlandsโ Law of Octaves
โข Every 8th element similar properties
โ๏ธ Mendeleevโs Periodic Table
โข Based on atomic mass
โข Left gaps for undiscovered elements
โ๏ธ Modern Periodic Table (Moseley)
โข Based on atomic number
#NEETIMP
โ๏ธ Anomalies of Mendeleev solved by modern table
3๏ธโฃ #MODERNPERIODICTABLE โญ
๐ Structure:
โ๏ธ 7 periods (horizontal rows)
โ๏ธ 18 groups (vertical columns)
๐ Blocks:
โ๏ธ s-block
โ๏ธ p-block
โ๏ธ d-block
โ๏ธ f-block
#NEETpoint:
โ๏ธ Period number = highest principal quantum number (n)
4๏ธโฃ #PERIODICITYINPROPERTIES โญ
โ๏ธ Repetition of properties at regular intervals
๐ Important properties:
โ๏ธ Atomic radius
โ๏ธ Ionisation enthalpy
โ๏ธ Electron affinity
โ๏ธ Electronegativity
โ๏ธ Metallic & non-metallic character
5๏ธโฃ #ATOMICRADIUS โญ
๐ Trend:
โ๏ธ Decreases across a period โ left to right
โ๏ธ Increases down a group
#Reason:
โ๏ธ Effective nuclear charge โ across period
โ๏ธ New shell added down the group
๐ Ionic radius:
โ๏ธ Cation < atom
โ๏ธ Anion > atom
6๏ธโฃ #IONISATIONENTHALPY โญ
โ๏ธ Energy required to remove an electron
๐ Trend:
โ๏ธ Increases across a period
โ๏ธ Decreases down a group
#Exceptions (NEET favourite ๐ฅ):
โ๏ธ Be > B
โ๏ธ N > O
7๏ธโฃ #ELECTRONAFFINITY โญ
โ๏ธ Energy released when electron is added
๐ Trend:
โ๏ธ Increases across a period
โ๏ธ Decreases down a group
#NEETpoint:
โ๏ธ Halogens โ highest electron affinity
โ๏ธ Noble gases โ ~0
8๏ธโฃ #ELECTRONEGATIVITY โญ
โ๏ธ Tendency to attract shared electron pair
๐ Trend:
โ๏ธ Increases across a period
โ๏ธ Decreases down a group
โญNEETpoint:
โ๏ธ Fluorine โ most electronegative
9๏ธโฃ #METALLICCHARACTER โญ
๐ Trend:
โ๏ธ Decreases across a period
โ๏ธ Increases down a group
โญNEETclarity:
โ๏ธ Metals โ lose electrons
โ๏ธ Non-metals โ gain electrons
๐ #ANOMALOUSBEHAVIOUR โญ
โ๏ธ First element of each group shows different properties
๐ Reason:
โ๏ธ Small size
โ๏ธ High electronegativity
โ๏ธ Absence of d-orbitals
โญExample:
โ๏ธ Li โ Na
โ๏ธ Be โ Mg
1๏ธโฃ1๏ธโฃ #NEETONELINERS๐ฅ
โ๏ธ Basis of modern periodic table โ atomic number
โ๏ธ Periodicity due to electronic configuration
โ๏ธ s-block โ highly electropositive
โ๏ธ p-block โ variable oxidation states
โ๏ธ d-block โ transition elements
1๏ธโฃ2๏ธโฃ #SUMMARY โญ
โ๏ธ Periodic table = map of chemistry
โ๏ธ Trends help predict properties
โ๏ธ Exceptions are more important for NEET
@Ayano1me @Neetugpoll @Neetugquiz
โค4๐2๐1๐คฉ1๐1๐1
Q1. (AssertionโReason type)
Assertion (A): Atomic radius generally decreases from left to right in a period.
Reason (R): Nuclear charge increases while number of shells remains same.
Options:
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q2.
Which element has maximum electronegativity?
(1) Oxygen
(2) Nitrogen
(3) Fluorine
(4) Chlorine
Question:3 Which of the following has largest atomic size?
(1) Na
(2) Mg
(3) Al
(4) Si
Question 4
Assertion (A): Ionization enthalpy generally increases from left to right in a period.
Reason (R): Atomic size decreases and nuclear charge increases across a period.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Question:5
Assertion (A): Electron affinity of halogens is high.
Reason (R): Halogens have one electron less than noble gas configuration.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Question:6
Assertion (A): Metallic character increases down a group.
Reason (R): Atomic size increases and ionization enthalpy decreases down the group.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
๐ฅ3๐ฅฐ3๐คฉ1
1๏ธโฃ #DUALBEHAVIOUROFMATTER โญ
โ๏ธ Matter shows dual nature:
๐ Particle nature
๐ Wave nature
โ๏ธ This concept proved that classical physics fails at atomic scale
NEET point:
โ๏ธ Dual behaviour mainly observed for microscopic particles (electron, proton)
2๏ธโฃ #PARTICLENATUREOFMATTER โญ
โ๏ธ Matter consists of discrete particles
โ๏ธ Particle nature supported by:
๐ Photoelectric effect
๐ Compton effect
๐ Evidence:
โ๏ธ Emission of electrons only when threshold frequency is reached
3๏ธโฃ #WAVENATUREOFMATTER โญ
โ๏ธ Proposed by de Broglie
โ๏ธ Every moving particle behaves like a wave
๐ de Broglie hypothesis:
โ๏ธ ฮป โ 1/p
๐ de Broglie wavelength:
โ๏ธ ฮป = h / mv
Where:
โ๏ธ h = Planckโs constant
โ๏ธ m = mass
โ๏ธ v = velocity
NEET point:
โ๏ธ Wave nature important for electrons
4๏ธโฃ #ELECTROMAGNETICRADIATION โญ
โ๏ธ Energy travels as waves
โ๏ธ Does not require medium
๐ Examples:
โ๏ธ Radio waves
โ๏ธ Microwaves
โ๏ธ Infrared
โ๏ธ Visible light
โ๏ธ UV, X-rays, ฮณ-rays
๐ Relation:
โ๏ธ c = ฮฝฮป
5๏ธโฃ #PHOTOELECTRICEFFECT โก โญ
โ๏ธ Emission of electrons when light falls on metal surface
๐ Key observations:
โ๏ธ Threshold frequency (ฮฝโ) exists
โ๏ธ No emission below ฮฝโ
โ๏ธ Intensity โ โ number of electrons โ
โ๏ธ Frequency โ โ kinetic energy โ
๐ Einsteinโs photoelectric equation:
โ๏ธ hฮฝ = hฮฝโ + ยฝmvยฒ
NEET trap
โ๏ธ KE depends on frequency, NOT intensity
6๏ธโฃ #WAVEPARTICLEDUALITY โญ
โ๏ธ Light behaves as:
๐ Wave โ interference, diffraction
๐ Particle โ photoelectric effect
โ๏ธ Matter behaves as:
๐ Particle โ mass, momentum
๐ Wave โ de Broglie wavelength
NEET clarity:
โ๏ธ Dual behaviour is complementary, not simultaneous
7๏ธโฃ #IMPORTANCEOFDEBROGLIEWAVE โญ
โ๏ธ Basis of Bohrโs model modification
โ๏ธ Explains stability of orbits
โ๏ธ Used in electron microscope
๐ Special cases:
โ๏ธ For electron (accelerated by V):
ฮป = h / โ(2meV)
8๏ธโฃ #NEETONELINERS
โ๏ธ Dual nature โ matter + radiation
โ๏ธ Threshold frequency โ metal dependent
โ๏ธ de Broglie wavelength inversely โ velocity
โ๏ธ Electron shows wave nature more clearly
9๏ธโฃ #FORMULASUMMARY (MUST REVISE )
โ๏ธ ฮป = h / mv
โ๏ธ c = ฮฝฮป
โ๏ธ E = hฮฝ
โ๏ธ hฮฝ = hฮฝโ + ยฝmvยฒ
โ๏ธ ฮป = h / โ(2meV)
๐ #REAL_SENSESUMMARY โญ
โ๏ธ Classical physics โ at atomic scale
โ๏ธ Quantum ideas โ๏ธ required
โ๏ธ Wave nature dominates for small particles
โ๏ธ Foundation of modern chemistry & physics
@Ayano1me @Neetugpoll @Neetugquiz
โ๏ธ Matter shows dual nature:
๐ Particle nature
๐ Wave nature
โ๏ธ This concept proved that classical physics fails at atomic scale
NEET point:
โ๏ธ Dual behaviour mainly observed for microscopic particles (electron, proton)
2๏ธโฃ #PARTICLENATUREOFMATTER โญ
โ๏ธ Matter consists of discrete particles
โ๏ธ Particle nature supported by:
๐ Photoelectric effect
๐ Compton effect
๐ Evidence:
โ๏ธ Emission of electrons only when threshold frequency is reached
3๏ธโฃ #WAVENATUREOFMATTER โญ
โ๏ธ Proposed by de Broglie
โ๏ธ Every moving particle behaves like a wave
๐ de Broglie hypothesis:
โ๏ธ ฮป โ 1/p
๐ de Broglie wavelength:
โ๏ธ ฮป = h / mv
Where:
โ๏ธ h = Planckโs constant
โ๏ธ m = mass
โ๏ธ v = velocity
NEET point:
โ๏ธ Wave nature important for electrons
4๏ธโฃ #ELECTROMAGNETICRADIATION โญ
โ๏ธ Energy travels as waves
โ๏ธ Does not require medium
๐ Examples:
โ๏ธ Radio waves
โ๏ธ Microwaves
โ๏ธ Infrared
โ๏ธ Visible light
โ๏ธ UV, X-rays, ฮณ-rays
๐ Relation:
โ๏ธ c = ฮฝฮป
5๏ธโฃ #PHOTOELECTRICEFFECT โก โญ
โ๏ธ Emission of electrons when light falls on metal surface
๐ Key observations:
โ๏ธ Threshold frequency (ฮฝโ) exists
โ๏ธ No emission below ฮฝโ
โ๏ธ Intensity โ โ number of electrons โ
โ๏ธ Frequency โ โ kinetic energy โ
๐ Einsteinโs photoelectric equation:
โ๏ธ hฮฝ = hฮฝโ + ยฝmvยฒ
NEET trap
โ๏ธ KE depends on frequency, NOT intensity
6๏ธโฃ #WAVEPARTICLEDUALITY โญ
โ๏ธ Light behaves as:
๐ Wave โ interference, diffraction
๐ Particle โ photoelectric effect
โ๏ธ Matter behaves as:
๐ Particle โ mass, momentum
๐ Wave โ de Broglie wavelength
NEET clarity:
โ๏ธ Dual behaviour is complementary, not simultaneous
7๏ธโฃ #IMPORTANCEOFDEBROGLIEWAVE โญ
โ๏ธ Basis of Bohrโs model modification
โ๏ธ Explains stability of orbits
โ๏ธ Used in electron microscope
๐ Special cases:
โ๏ธ For electron (accelerated by V):
ฮป = h / โ(2meV)
8๏ธโฃ #NEETONELINERS
โ๏ธ Dual nature โ matter + radiation
โ๏ธ Threshold frequency โ metal dependent
โ๏ธ de Broglie wavelength inversely โ velocity
โ๏ธ Electron shows wave nature more clearly
9๏ธโฃ #FORMULASUMMARY (MUST REVISE )
โ๏ธ ฮป = h / mv
โ๏ธ c = ฮฝฮป
โ๏ธ E = hฮฝ
โ๏ธ hฮฝ = hฮฝโ + ยฝmvยฒ
โ๏ธ ฮป = h / โ(2meV)
๐ #REAL_SENSESUMMARY โญ
โ๏ธ Classical physics โ at atomic scale
โ๏ธ Quantum ideas โ๏ธ required
โ๏ธ Wave nature dominates for small particles
โ๏ธ Foundation of modern chemistry & physics
@Ayano1me @Neetugpoll @Neetugquiz
โค3๐ฅฐ2๐2๐2
1๏ธโฃ #DIPOLEMOMENT
๐ Measure of polarity of a bond or molecule
2๏ธโฃ #DEFINITION
โ๏ธ Product of magnitude of charge (q) and distance (d) between centres of +ve and โve charges
โ๏ธ ฮผ = q ร d
โ๏ธ Vector quantity
โ๏ธ Direction โ from negative to positive charge
3๏ธโฃ #UNITS
โ๏ธ SI unit โ Coulomb metre (Cยทm)
โ๏ธ Practical unit โ Debye (D)
๐ 1 Debye = 3.336 ร 10โปยณโฐ Cยทm
4๏ธโฃ #BONDDIPOLEMOMENT
โ๏ธ Due to electronegativity difference
โ๏ธ Greater ฮEN โ greater dipole moment
๐ HโCl > HโBr > HโI
5๏ธโฃ #MOLECULARDIPOLEMOMENT
โ๏ธ Vector sum of all bond dipoles
โ๏ธ Depends on molecular shape & symmetry
6๏ธโฃ #EFFECTOFSHAPE
โ๏ธ Symmetrical molecule โ ฮผ = 0
โ๏ธ Unsymmetrical molecule โ ฮผ โ 0
๐ Examples:
โ๏ธ COโ โ ฮผ = 0 (linear)
โ๏ธ BFโ โ ฮผ = 0 (trigonal planar)
โ๏ธ HโO โ ฮผ โ 0 (bent)
โ๏ธ NHโ โ ฮผ โ 0 (pyramidal)
7๏ธโฃ #APPLICATIONS
โ๏ธ Polarity determination
โ๏ธ Molecular geometry
โ๏ธ Ionic character
โ๏ธ Distinguishing cisโtrans isomers
๐ cis โ ฮผ โ 0
๐ trans โ ฮผ = 0
8๏ธโฃ #IMPORTANTNCERTPOINTS
โ๏ธ Lone pair increases dipole moment
โ๏ธ Symmetry can cancel dipole moment
โ๏ธ Polar bonds may give zero ฮผ
9๏ธโฃ #NEETTRAPS
โ Polar bond โ polar molecule
โ Zero ฮผ โ non-polar bonds
โ Shape ignored = wrong answer
HF>HCL but ch3cl>ch3F ( DM)
@Ayano1me @Neetugpoll @Neetugquiz
๐ Measure of polarity of a bond or molecule
2๏ธโฃ #DEFINITION
โ๏ธ Product of magnitude of charge (q) and distance (d) between centres of +ve and โve charges
โ๏ธ ฮผ = q ร d
โ๏ธ Vector quantity
โ๏ธ Direction โ from negative to positive charge
3๏ธโฃ #UNITS
โ๏ธ SI unit โ Coulomb metre (Cยทm)
โ๏ธ Practical unit โ Debye (D)
๐ 1 Debye = 3.336 ร 10โปยณโฐ Cยทm
4๏ธโฃ #BONDDIPOLEMOMENT
โ๏ธ Due to electronegativity difference
โ๏ธ Greater ฮEN โ greater dipole moment
๐ HโCl > HโBr > HโI
5๏ธโฃ #MOLECULARDIPOLEMOMENT
โ๏ธ Vector sum of all bond dipoles
โ๏ธ Depends on molecular shape & symmetry
6๏ธโฃ #EFFECTOFSHAPE
โ๏ธ Symmetrical molecule โ ฮผ = 0
โ๏ธ Unsymmetrical molecule โ ฮผ โ 0
๐ Examples:
โ๏ธ COโ โ ฮผ = 0 (linear)
โ๏ธ BFโ โ ฮผ = 0 (trigonal planar)
โ๏ธ HโO โ ฮผ โ 0 (bent)
โ๏ธ NHโ โ ฮผ โ 0 (pyramidal)
7๏ธโฃ #APPLICATIONS
โ๏ธ Polarity determination
โ๏ธ Molecular geometry
โ๏ธ Ionic character
โ๏ธ Distinguishing cisโtrans isomers
๐ cis โ ฮผ โ 0
๐ trans โ ฮผ = 0
8๏ธโฃ #IMPORTANTNCERTPOINTS
โ๏ธ Lone pair increases dipole moment
โ๏ธ Symmetry can cancel dipole moment
โ๏ธ Polar bonds may give zero ฮผ
9๏ธโฃ #NEETTRAPS
โ Polar bond โ polar molecule
โ Zero ฮผ โ non-polar bonds
โ Shape ignored = wrong answer
HF>HCL but ch3cl>ch3F ( DM)
@Ayano1me @Neetugpoll @Neetugquiz
๐2โค1๐1๐ฅ1๐1
Aaj 8 bje all book module ka link
โค3๐ฅ3๐2๐1
1๏ธโฃ #VSEPRTHEORY
๐ VSEPR = Valence Shell Electron Pair Repulsion theory
๐ Used to predict shape of molecules and ions.
2๏ธโฃ #BASICIDEA
โ๏ธ Electron pairs in valence shell repel each other
โ๏ธ They arrange themselves to minimise repulsion
โ๏ธ Shape depends on number of electron pairs around central atom
3๏ธโฃ #TYPESOFELECTRONPAIRS
โ๏ธ Bond pair (BP) โ shared electrons
โ๏ธ Lone pair (LP) โ unshared electrons
๐ Lone pair occupies more space than bond pair
4๏ธโฃ #ORDEROFREPULSION (VERY IMP ๐ฅ)
โ๏ธ LPโLP > LPโBP > BPโBP
๐ This order decides distortion in shape
5๏ธโฃ #ELECTRONGEOMETRYVS MOLECULARGEOMETRY
โ๏ธ Electron geometry โ arrangement of all electron pairs
โ๏ธ Molecular geometry โ arrangement of atoms only
๐ Lone pairs affect molecular shape, not electron geometry
6๏ธโฃ #IDEALGEOMETRIES (NO LONE PAIR)
โ๏ธ 2 BP โ Linear โ 180ยฐ โ BeClโ
โ๏ธ 3 BP โ Trigonal planar โ 120ยฐ โ BFโ
โ๏ธ 4 BP โ Tetrahedral โ 109.5ยฐ โ CHโ
โ๏ธ 5 BP โ Trigonal bipyramidal โ PClโ
โ๏ธ 6 BP โ Octahedral โ SFโ
7๏ธโฃ #EFFECTOFLONEPAIR
โ๏ธ Lone pair reduces bond angle
โ๏ธ More lone pairs โ more deviation from ideal shape
๐ Examples:
โ๏ธ CHโ โ 109.5ยฐ
โ๏ธ NHโ โ 107ยฐ
โ๏ธ HโO โ 104.5ยฐ
8๏ธโฃ #SPECIALCASESTRIGONALBIPYRAMIDAL
โ๏ธ Axial positions โ more repulsion
โ๏ธ Equatorial positions โ less repulsion
๐ Lone pair occupies equatorial position first
๐ Example:
โ๏ธ SFโ โ seesaw
โ๏ธ ClFโ โ T-shape
โ๏ธ XeFโ โ linear
9๏ธโฃ #SPECIALCASEOFOCTAHEDRAL
โ๏ธ One lone pair โ square pyramidal
โ๏ธ Two lone pairs โ square planar
๐ Examples:
โ๏ธ BrFโ โ square pyramidal
โ๏ธ XeFโ โ square planar
๐ #NEETIMPORTANTPOINTS ๐จ
โ๏ธ Lone pair causes maximum repulsion
โ๏ธ Shape decided by LP + BP count
โ๏ธ VSEPR explains shape, not bonding strength
โ๏ธ Used mainly for p-block compounds
1๏ธโฃ1๏ธโฃ #LIMITATIONSOFVSEPR
โ๏ธ Cannot explain bond length accurately
โ๏ธ Not applicable for transition metals
โ๏ธ Fails for odd-electron molecules
1๏ธโฃ2๏ธโฃ #ONELINEREVISION
Molecular shape is decided by repulsion between electron pairs around the central atom.
@Ayano1me @Neetugpoll @Neetugquiz
๐ VSEPR = Valence Shell Electron Pair Repulsion theory
๐ Used to predict shape of molecules and ions.
2๏ธโฃ #BASICIDEA
โ๏ธ Electron pairs in valence shell repel each other
โ๏ธ They arrange themselves to minimise repulsion
โ๏ธ Shape depends on number of electron pairs around central atom
3๏ธโฃ #TYPESOFELECTRONPAIRS
โ๏ธ Bond pair (BP) โ shared electrons
โ๏ธ Lone pair (LP) โ unshared electrons
๐ Lone pair occupies more space than bond pair
4๏ธโฃ #ORDEROFREPULSION (VERY IMP ๐ฅ)
โ๏ธ LPโLP > LPโBP > BPโBP
๐ This order decides distortion in shape
5๏ธโฃ #ELECTRONGEOMETRYVS MOLECULARGEOMETRY
โ๏ธ Electron geometry โ arrangement of all electron pairs
โ๏ธ Molecular geometry โ arrangement of atoms only
๐ Lone pairs affect molecular shape, not electron geometry
6๏ธโฃ #IDEALGEOMETRIES (NO LONE PAIR)
โ๏ธ 2 BP โ Linear โ 180ยฐ โ BeClโ
โ๏ธ 3 BP โ Trigonal planar โ 120ยฐ โ BFโ
โ๏ธ 4 BP โ Tetrahedral โ 109.5ยฐ โ CHโ
โ๏ธ 5 BP โ Trigonal bipyramidal โ PClโ
โ๏ธ 6 BP โ Octahedral โ SFโ
7๏ธโฃ #EFFECTOFLONEPAIR
โ๏ธ Lone pair reduces bond angle
โ๏ธ More lone pairs โ more deviation from ideal shape
๐ Examples:
โ๏ธ CHโ โ 109.5ยฐ
โ๏ธ NHโ โ 107ยฐ
โ๏ธ HโO โ 104.5ยฐ
8๏ธโฃ #SPECIALCASESTRIGONALBIPYRAMIDAL
โ๏ธ Axial positions โ more repulsion
โ๏ธ Equatorial positions โ less repulsion
๐ Lone pair occupies equatorial position first
๐ Example:
โ๏ธ SFโ โ seesaw
โ๏ธ ClFโ โ T-shape
โ๏ธ XeFโ โ linear
9๏ธโฃ #SPECIALCASEOFOCTAHEDRAL
โ๏ธ One lone pair โ square pyramidal
โ๏ธ Two lone pairs โ square planar
๐ Examples:
โ๏ธ BrFโ โ square pyramidal
โ๏ธ XeFโ โ square planar
๐ #NEETIMPORTANTPOINTS ๐จ
โ๏ธ Lone pair causes maximum repulsion
โ๏ธ Shape decided by LP + BP count
โ๏ธ VSEPR explains shape, not bonding strength
โ๏ธ Used mainly for p-block compounds
1๏ธโฃ1๏ธโฃ #LIMITATIONSOFVSEPR
โ๏ธ Cannot explain bond length accurately
โ๏ธ Not applicable for transition metals
โ๏ธ Fails for odd-electron molecules
1๏ธโฃ2๏ธโฃ #ONELINEREVISION
Molecular shape is decided by repulsion between electron pairs around the central atom.
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅ2๐2โค1๐1
โค2๐คฉ1๐ฏ1๐1
Chemistry booster series
https://t.me/+5VTfeOK6KxJkYWQ1
Old m Copyright aa gya ๐again upload krenge 3500+ video
Btw share krdo needy students ko baad m link na milegi
Btw share krdo needy students ko baad m link na milegi
๐ฏ4โค2๐1๐1
1๏ธโฃ #MOLECULARORBITALTHEORY
๐ Molecular Orbital Theory (MOT) explains bonding, bond order and magnetic nature of molecules.
๐ Proposed by Hund and Mulliken.
2๏ธโฃ #BASICIDEA
โ๏ธ Atomic orbitals of bonded atoms combine to form molecular orbitals
โ๏ธ Molecular orbitals belong to the entire molecule
โ๏ธ Number of MOs formed = number of AOs combined
3๏ธโฃ #CONDITIONSFORCOMBINATION
โ๏ธ Comparable energy of AOs
โ๏ธ Proper orientation
โ๏ธ Significant overlap
4๏ธโฃ #TYPESOFMOLECULARORBITALS
โ๏ธ Bonding MO
โ๏ธ Antibonding MO
โ๏ธ Non-bonding MO (rare in diatomic molecules)
5๏ธโฃ #BONDINGMO
โ๏ธ Formed by constructive overlap
โ๏ธ Lower energy than AOs
โ๏ธ Increases stability
๐ Denoted by: ฯ, ฯ
6๏ธโฃ #ANTIBONDINGMO
โ๏ธ Formed by destructive overlap
โ๏ธ Higher energy
โ๏ธ Decreases stability
๐ Denoted by: ฯ*, ฯ*
7๏ธโฃ #ELECTRONFILLINGRULES
โ๏ธ Aufbau principle
โ๏ธ Pauli exclusion principle
โ๏ธ Hundโs rule of maximum multiplicity
8๏ธโฃ #ENERGYORDEROFDIATOMICMOLECULES โญ
๐ For Bโ, Cโ, Nโ:
ฯ1s < ฯ1s < ฯ2s < ฯ2s < ฯ2p < ฯ2p < ฯ2p < ฯ2p
๐ For Oโ, Fโ, Neโ:
ฯ1s < ฯ1s < ฯ2s < ฯ2s < ฯ2p < ฯ2p < ฯ2p < ฯ2p
9๏ธโฃ #BONORDER (VERY IMP )
๐ Formula:
Bond order = (Nb โ Na) / 2
โ๏ธ Nb = bonding electrons
โ๏ธ Na = antibonding electrons
๐ Interpretation:
โ๏ธ Higher bond order โ stronger bond
โ๏ธ Bond order = 0 โ molecule does not exist
๐ #MAGNETICNATURE
โ๏ธ Unpaired electrons โ paramagnetic
โ๏ธ All electrons paired โ diamagnetic
๐ Example:
โ๏ธ Oโ โ paramagnetic
โ๏ธ Nโ โ diamagnetic
1๏ธโฃ1๏ธโฃ #IMPORTANTEXAMPLES (NEET ๐ฅ)
โ๏ธ Hโ โ bond order = 1
โ๏ธ Heโ โ bond order = 0 (does not exist)
โ๏ธ Oโโบ โ bond order increases
โ๏ธ Oโโป โ bond order decreases
1๏ธโฃ2๏ธโฃ #LIMITATIONSOFMOT
โ๏ธ Complex for polyatomic molecules
โ๏ธ Does not explain shape clearly
1๏ธโฃ3๏ธโฃ #NEETIMPORTANTPOINTS
โ๏ธ MOT explains paramagnetism of Oโ
โ๏ธ Energy order changes after Nโ
โ๏ธ Bond order decides stability
1๏ธโฃ4๏ธโฃ #ONELINEREVISION
Molecular Orbital Theory explains bonding by delocalised molecular orbitals and predicts bond order and magnetic nature
@Ayano1me @Neetugpoll @Neetugquiz
๐ Molecular Orbital Theory (MOT) explains bonding, bond order and magnetic nature of molecules.
๐ Proposed by Hund and Mulliken.
2๏ธโฃ #BASICIDEA
โ๏ธ Atomic orbitals of bonded atoms combine to form molecular orbitals
โ๏ธ Molecular orbitals belong to the entire molecule
โ๏ธ Number of MOs formed = number of AOs combined
3๏ธโฃ #CONDITIONSFORCOMBINATION
โ๏ธ Comparable energy of AOs
โ๏ธ Proper orientation
โ๏ธ Significant overlap
4๏ธโฃ #TYPESOFMOLECULARORBITALS
โ๏ธ Bonding MO
โ๏ธ Antibonding MO
โ๏ธ Non-bonding MO (rare in diatomic molecules)
5๏ธโฃ #BONDINGMO
โ๏ธ Formed by constructive overlap
โ๏ธ Lower energy than AOs
โ๏ธ Increases stability
๐ Denoted by: ฯ, ฯ
6๏ธโฃ #ANTIBONDINGMO
โ๏ธ Formed by destructive overlap
โ๏ธ Higher energy
โ๏ธ Decreases stability
๐ Denoted by: ฯ*, ฯ*
7๏ธโฃ #ELECTRONFILLINGRULES
โ๏ธ Aufbau principle
โ๏ธ Pauli exclusion principle
โ๏ธ Hundโs rule of maximum multiplicity
8๏ธโฃ #ENERGYORDEROFDIATOMICMOLECULES โญ
๐ For Bโ, Cโ, Nโ:
ฯ1s < ฯ1s < ฯ2s < ฯ2s < ฯ2p < ฯ2p < ฯ2p < ฯ2p
๐ For Oโ, Fโ, Neโ:
ฯ1s < ฯ1s < ฯ2s < ฯ2s < ฯ2p < ฯ2p < ฯ2p < ฯ2p
9๏ธโฃ #BONORDER (VERY IMP )
๐ Formula:
Bond order = (Nb โ Na) / 2
โ๏ธ Nb = bonding electrons
โ๏ธ Na = antibonding electrons
๐ Interpretation:
โ๏ธ Higher bond order โ stronger bond
โ๏ธ Bond order = 0 โ molecule does not exist
๐ #MAGNETICNATURE
โ๏ธ Unpaired electrons โ paramagnetic
โ๏ธ All electrons paired โ diamagnetic
๐ Example:
โ๏ธ Oโ โ paramagnetic
โ๏ธ Nโ โ diamagnetic
1๏ธโฃ1๏ธโฃ #IMPORTANTEXAMPLES (NEET ๐ฅ)
โ๏ธ Hโ โ bond order = 1
โ๏ธ Heโ โ bond order = 0 (does not exist)
โ๏ธ Oโโบ โ bond order increases
โ๏ธ Oโโป โ bond order decreases
1๏ธโฃ2๏ธโฃ #LIMITATIONSOFMOT
โ๏ธ Complex for polyatomic molecules
โ๏ธ Does not explain shape clearly
1๏ธโฃ3๏ธโฃ #NEETIMPORTANTPOINTS
โ๏ธ MOT explains paramagnetism of Oโ
โ๏ธ Energy order changes after Nโ
โ๏ธ Bond order decides stability
1๏ธโฃ4๏ธโฃ #ONELINEREVISION
Molecular Orbital Theory explains bonding by delocalised molecular orbitals and predicts bond order and magnetic nature
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅฐ2โค1๐ฏ1
1๏ธโฃ #VALENCEBONDTHEORY
๐ Valence Bond Theory (VBT) explains formation of covalent bonds by overlap of atomic orbitals.
๐ Proposed by Heitler and London.
2๏ธโฃ #BASICIDEA
โ๏ธ Atoms bond to achieve stable electronic configuration
โ๏ธ Half-filled atomic orbitals overlap
โ๏ธ Electrons pair with opposite spins
๐ Greater overlap โ stronger bond
3๏ธโฃ #CONDITIONSFOROVERLAP
โ๏ธ Half-filled orbitals
โ๏ธ Comparable energy of orbitals
โ๏ธ Proper orientation
4๏ธโฃ #TYPESOFOBOND
โ๏ธ Sigma (ฯ) bond
โ๏ธ Pi (ฯ) bond
5๏ธโฃ #SIGMABOND
โ๏ธ Formed by head-on overlap
โ๏ธ Stronger than ฯ bond
โ๏ธ Electron density along internuclear axis
๐ Overlap types:
โ๏ธ sโs
โ๏ธ sโp
โ๏ธ pโp
6๏ธโฃ #PIBOND
โ๏ธ Formed by sidewise overlap
โ๏ธ Weaker than ฯ bond
โ๏ธ Electron density above & below axis
๐ Formed by pโp overlap only
7๏ธโฃ #HYBRIDISATION
๐ Mixing of atomic orbitals of similar energy to form hybrid orbitals.
โ๏ธ Number of hybrid orbitals = number of AOs mixed
8๏ธโฃ #TYPESOFHYBRIDISATION
โ๏ธ sp โ linear โ 180ยฐ โ BeClโ
โ๏ธ spยฒ โ trigonal planar โ 120ยฐ โ BFโ
โ๏ธ spยณ โ tetrahedral โ 109.5ยฐ โ CHโ
โ๏ธ dspยฒ โ square planar โ [Ni(CN)โ]ยฒโป
โ๏ธ dยฒspยณ โ octahedral โ [Co(NHโ)โ]ยณโบ
9๏ธโฃ #VALENCEBONDTHEORYINCOORDINATIONCOMPOUNDS
โ๏ธ Central metal provides empty orbitals
โ๏ธ Ligands donate lone pair
โ๏ธ Coordinate bond formed by overlap
๐ #MAGNETICNATURE
โ๏ธ Unpaired electrons โ paramagnetic
โ๏ธ Paired electrons โ diamagnetic
๐ Example:
โ๏ธ [Ni(CN)โ]ยฒโป โ diamagnetic
โ๏ธ [NiClโ]ยฒโป โ paramagnetic
1๏ธโฃ1๏ธโฃ #LIMITATIONSOFVBT
โ๏ธ Cannot explain colour of compounds
โ๏ธ Cannot explain strong vs weak ligands clearly
โ๏ธ No quantitative explanation of spectra
1๏ธโฃ2๏ธโฃ #NEETIMPORTANTPOINTS
โ๏ธ ฯ bond is stronger than ฯ bond
โ๏ธ Multiple bonds = 1 ฯ + remaining ฯ
โ๏ธ Hybridisation explains geometry
1๏ธโฃ3๏ธโฃ #ONELINEREVISION
Valence Bond Theory explains bonding by orbital overlap and predicts bond type, strength and geometry.
@Ayano1me @Neetugpoll @Neetugquiz
๐ Valence Bond Theory (VBT) explains formation of covalent bonds by overlap of atomic orbitals.
๐ Proposed by Heitler and London.
2๏ธโฃ #BASICIDEA
โ๏ธ Atoms bond to achieve stable electronic configuration
โ๏ธ Half-filled atomic orbitals overlap
โ๏ธ Electrons pair with opposite spins
๐ Greater overlap โ stronger bond
3๏ธโฃ #CONDITIONSFOROVERLAP
โ๏ธ Half-filled orbitals
โ๏ธ Comparable energy of orbitals
โ๏ธ Proper orientation
4๏ธโฃ #TYPESOFOBOND
โ๏ธ Sigma (ฯ) bond
โ๏ธ Pi (ฯ) bond
5๏ธโฃ #SIGMABOND
โ๏ธ Formed by head-on overlap
โ๏ธ Stronger than ฯ bond
โ๏ธ Electron density along internuclear axis
๐ Overlap types:
โ๏ธ sโs
โ๏ธ sโp
โ๏ธ pโp
6๏ธโฃ #PIBOND
โ๏ธ Formed by sidewise overlap
โ๏ธ Weaker than ฯ bond
โ๏ธ Electron density above & below axis
๐ Formed by pโp overlap only
7๏ธโฃ #HYBRIDISATION
๐ Mixing of atomic orbitals of similar energy to form hybrid orbitals.
โ๏ธ Number of hybrid orbitals = number of AOs mixed
8๏ธโฃ #TYPESOFHYBRIDISATION
โ๏ธ sp โ linear โ 180ยฐ โ BeClโ
โ๏ธ spยฒ โ trigonal planar โ 120ยฐ โ BFโ
โ๏ธ spยณ โ tetrahedral โ 109.5ยฐ โ CHโ
โ๏ธ dspยฒ โ square planar โ [Ni(CN)โ]ยฒโป
โ๏ธ dยฒspยณ โ octahedral โ [Co(NHโ)โ]ยณโบ
9๏ธโฃ #VALENCEBONDTHEORYINCOORDINATIONCOMPOUNDS
โ๏ธ Central metal provides empty orbitals
โ๏ธ Ligands donate lone pair
โ๏ธ Coordinate bond formed by overlap
๐ #MAGNETICNATURE
โ๏ธ Unpaired electrons โ paramagnetic
โ๏ธ Paired electrons โ diamagnetic
๐ Example:
โ๏ธ [Ni(CN)โ]ยฒโป โ diamagnetic
โ๏ธ [NiClโ]ยฒโป โ paramagnetic
1๏ธโฃ1๏ธโฃ #LIMITATIONSOFVBT
โ๏ธ Cannot explain colour of compounds
โ๏ธ Cannot explain strong vs weak ligands clearly
โ๏ธ No quantitative explanation of spectra
1๏ธโฃ2๏ธโฃ #NEETIMPORTANTPOINTS
โ๏ธ ฯ bond is stronger than ฯ bond
โ๏ธ Multiple bonds = 1 ฯ + remaining ฯ
โ๏ธ Hybridisation explains geometry
1๏ธโฃ3๏ธโฃ #ONELINEREVISION
Valence Bond Theory explains bonding by orbital overlap and predicts bond type, strength and geometry.
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅ2๐1๐1
Q1.
Assertion (A): In Oโ molecule, two electrons remain unpaired in molecular orbitals.
Reason (R): The last electrons of Oโ occupy degenerate ฯ* antibonding orbitals according to Hundโs rule.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q2.
Assertion (A): Bond order of Nโ molecule is 3.
Reason (R): Nโ has more electrons in bonding molecular orbitals than in antibonding molecular orbitals.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q3.
Assertion (A): Heโ molecule does not exist.
Reason (R): Number of electrons in bonding and antibonding orbitals of Heโ are equal.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q1.
Assertion (A): According to VBT, a covalent bond is formed by overlap of half-filled atomic orbitals.
Reason (R): Overlap of orbitals increases electron density between two nuclei.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q2.
Assertion (A): A ฯ-bond is stronger than a ฯ-bond.
Reason (R): ฯ-bond is formed by head-on overlap whereas ฯ-bond is formed by sidewise overlap.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q3.
Assertion (A): Valence Bond Theory cannot explain paramagnetism of Oโ molecule.
Reason (R): VBT does not consider molecular orbitals and electron delocalisation.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
โค1๐1๐ณ1๐1
๐1๐ฅ1๐1๐ฏ1
1๏ธโฃ #KINETICTHEORYOFGASES
โ๏ธ Explains macroscopic properties of gases
โ๏ธ Based on molecular motion
โ๏ธ Applies mainly to ideal gases
2๏ธโฃ #BASICPOSTULATES
โ๏ธ Gas consists of very large number of molecules
โ๏ธ Molecules are point masses (negligible volume)
โ๏ธ Distance between molecules โซ molecular size
โ๏ธ Molecules move randomly in all directions
3๏ธโฃ #NATUREOFMOLECULARMOTION
โ๏ธ Continuous
โ๏ธ Random
โ๏ธ Straight-line motion between collisions
๐ Velocity constantly changes due to collisions
4๏ธโฃ #INTERMOLECULARFORCES
โ๏ธ Negligible attractive forces
โ๏ธ No repulsion except during collision
๐ Valid only for ideal gases
5๏ธโฃ #COLLISIONS (VERY IMP ๐ฅ)
โ๏ธ Collisions are perfectly elastic
โ๏ธ Occur between:
โช๏ธ Moleculeโmolecule
โช๏ธ Moleculeโwall
๐ No loss of kinetic energy
6๏ธโฃ #PRESSUREOFGAS
โ๏ธ Due to collision of gas molecules with container walls
โ๏ธ More collisions โ more pressure
๐ Pressure โ number of collisions
7๏ธโฃ #KINETICENERGY
โ๏ธ Average kinetic energy depends only on temperature
โ๏ธ Independent of pressure & volume
๐ Formula:
Average K.E. = (3/2) kT (per molecule)
Average K.E. = (3/2) RT (per mole)
8๏ธโฃ #TEMPERATURESIGNIFICANCE
โ๏ธ Measure of average kinetic energy
โ๏ธ At 0 K โ molecular motion stops (ideal case)
๐ Higher T โ higher molecular speed
9๏ธโฃ #SPEEDOFGASMOLECULES
โ๏ธ Three types:
โช๏ธ Most probable speed (vโ)
โช๏ธ Average speed (vโแตฅ)
โช๏ธ RMS speed (vแตฃโโ)
๐ Relation:
vโ < vโแตฅ < vแตฃโโ
๐ #SPEEDFORMULAE (NEET FAVORITE โค๏ธ)
โ๏ธ vโ = โ(2RT / M)
โ๏ธ vโแตฅ = โ(8RT / ฯM)
โ๏ธ vแตฃโโ = โ(3RT / M)
๐ M in kg molโปยน
1๏ธโฃ1๏ธโฃ #GRAHAMLAW (LINKED CONCEPT)
โ๏ธ Rate โ 1 / โM
โ๏ธ Lighter gas diffuses faster
1๏ธโฃ2๏ธโฃ #DEVIATIONFROMIDEALBEHAVIOUR
โ๏ธ Real gases deviate at:
โช๏ธ High pressure
โช๏ธ Low temperature
๐ Cause:
โ๏ธ Finite molecular volume
โ๏ธ Intermolecular attraction
1๏ธโฃ3๏ธโฃ #LIMITATIONSOFKTG
โ Cannot explain liquefaction
โ Fails at high pressure
โ Assumes zero molecular volume
1๏ธโฃ4๏ธโฃ #NEETONELINERS
โ๏ธ Pressure independent of mass of gas
โ๏ธ KE โ absolute temperature
โ๏ธ Elastic collision = KE conserved
โ๏ธ At same T โ all gases have same average KE
@Ayano1me @Neetugpoll @Neetugquiz
โ๏ธ Explains macroscopic properties of gases
โ๏ธ Based on molecular motion
โ๏ธ Applies mainly to ideal gases
2๏ธโฃ #BASICPOSTULATES
โ๏ธ Gas consists of very large number of molecules
โ๏ธ Molecules are point masses (negligible volume)
โ๏ธ Distance between molecules โซ molecular size
โ๏ธ Molecules move randomly in all directions
3๏ธโฃ #NATUREOFMOLECULARMOTION
โ๏ธ Continuous
โ๏ธ Random
โ๏ธ Straight-line motion between collisions
๐ Velocity constantly changes due to collisions
4๏ธโฃ #INTERMOLECULARFORCES
โ๏ธ Negligible attractive forces
โ๏ธ No repulsion except during collision
๐ Valid only for ideal gases
5๏ธโฃ #COLLISIONS (VERY IMP ๐ฅ)
โ๏ธ Collisions are perfectly elastic
โ๏ธ Occur between:
โช๏ธ Moleculeโmolecule
โช๏ธ Moleculeโwall
๐ No loss of kinetic energy
6๏ธโฃ #PRESSUREOFGAS
โ๏ธ Due to collision of gas molecules with container walls
โ๏ธ More collisions โ more pressure
๐ Pressure โ number of collisions
7๏ธโฃ #KINETICENERGY
โ๏ธ Average kinetic energy depends only on temperature
โ๏ธ Independent of pressure & volume
๐ Formula:
Average K.E. = (3/2) kT (per molecule)
Average K.E. = (3/2) RT (per mole)
8๏ธโฃ #TEMPERATURESIGNIFICANCE
โ๏ธ Measure of average kinetic energy
โ๏ธ At 0 K โ molecular motion stops (ideal case)
๐ Higher T โ higher molecular speed
9๏ธโฃ #SPEEDOFGASMOLECULES
โ๏ธ Three types:
โช๏ธ Most probable speed (vโ)
โช๏ธ Average speed (vโแตฅ)
โช๏ธ RMS speed (vแตฃโโ)
๐ Relation:
vโ < vโแตฅ < vแตฃโโ
๐ #SPEEDFORMULAE (NEET FAVORITE โค๏ธ)
โ๏ธ vโ = โ(2RT / M)
โ๏ธ vโแตฅ = โ(8RT / ฯM)
โ๏ธ vแตฃโโ = โ(3RT / M)
๐ M in kg molโปยน
1๏ธโฃ1๏ธโฃ #GRAHAMLAW (LINKED CONCEPT)
โ๏ธ Rate โ 1 / โM
โ๏ธ Lighter gas diffuses faster
1๏ธโฃ2๏ธโฃ #DEVIATIONFROMIDEALBEHAVIOUR
โ๏ธ Real gases deviate at:
โช๏ธ High pressure
โช๏ธ Low temperature
๐ Cause:
โ๏ธ Finite molecular volume
โ๏ธ Intermolecular attraction
1๏ธโฃ3๏ธโฃ #LIMITATIONSOFKTG
โ Cannot explain liquefaction
โ Fails at high pressure
โ Assumes zero molecular volume
1๏ธโฃ4๏ธโฃ #NEETONELINERS
โ๏ธ Pressure independent of mass of gas
โ๏ธ KE โ absolute temperature
โ๏ธ Elastic collision = KE conserved
โ๏ธ At same T โ all gases have same average KE
@Ayano1me @Neetugpoll @Neetugquiz
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