Chemistry booster series
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Conductivity
๐ŸŒฑ Electrical Conductance (G)
๐Ÿ“Œ Reciprocal of resistance
G=1/R
Unit: Siemens (S)

โญ Specific Conductivity (ฮบ)
Conductance of solution of: โœ”๏ธ 1 cm length
โœ”๏ธ 1 cmยฒ area
Depends on:
Concentration
Temperature
Nature of electrolyte

โญ Molar Conductivity (ฮ›m)
(ฮ›m)=kร—1000/C
Unit: S cmยฒ molโปยน

๐Ÿ“Œ C = molarity
โœ”๏ธ Increases on dilution
โœ”๏ธ Maximum value at infinite dilution โ†’ ฮ›ยฐm

Strong vs Weak Electrolyte
Feature :Strong :Weak
Ionisation :Complete :Partial
ฮ›m with dilution :Slight โ†‘ :Sharp โ†‘
Kohlrausch law :โœ”๏ธ Applicable
: โœ”๏ธ Applicable

#Kohlrauschโ€™s Law
At infinite dilution:
ฮ›mยฐ=(ฮ›mยฐ+) + ((ฮ›mยฐ_)

โœ”๏ธ Helps calculate:
ฮ›ยฐm of weak electrolytes
Degree of dissociation
Ka, Kb

#NEETHOTPOINTS
โœ”๏ธ Nernst eqn at 298 K โ†’ 0.0591/n
โœ”๏ธ At equilibrium โ†’ E = 0
โœ”๏ธ Unit of ฮบ โ†’ S cmโปยน
โœ”๏ธ ฮ›m increases with dilution
โœ”๏ธ Maximum conductivity โ†’ Infinite dilution

@Ayano1me @Neetugpoll @neetugquiz
๐Ÿ”ฅ2โค1๐ŸŽ‰1๐Ÿ’ฏ1
#ChemicalKinetics

โญ First Order Reaction
๐ŸŒฑ Definition
Reaction whose rate depends on concentration of one reactant raised to power 1

๐Ÿ“Œ Rate law:
Rate =k(A)

๐Ÿ”ข Integrated Rate Equation
K=2.303/t log (A)โ€ข/(A)
๐Ÿ“Œ Where:
๏ฟฝ = rate constant
๏ฟฝ = time
๏ฟฝ = initial concentration
๏ฟฝ = concentration at time t

#Halflife (tยฝ)
Time for concentration to become half
t1/2=0.693/k

โญIndependent of initial concentration (#veryimp )
Units
โœ”๏ธ Rate constant (k) โ†’ sโปยน
Graph (Direct MCQ)
โœ”๏ธ log[A] vs t โ†’ Straight line
โœ”๏ธ Slope โ†’ โ€“k/2.303

Examples
โœ”๏ธ Radioactive decay
โœ”๏ธ Decomposition of Nโ‚‚Oโ‚…
โœ”๏ธ Acid hydrolysis of esters (pseudo-first order)

#NEETHOTPOINTS (1st Order)
โœ”๏ธ Half-life independent of concentration
โœ”๏ธ Unit of k โ†’ sโปยน
โœ”๏ธ Straight line graph โ†’ log[A] vs t
โœ”๏ธ Pseudo-first order โ†’ One reactant in excess

@Ayano1me @Neetugpoll @NeetugQuiz
๐Ÿ™1๐Ÿ•Š1๐Ÿ˜1
#Arrhenius Equation
๐ŸŒฑ Shows effect of temperature on rate constant
โญ Equation

K=Ae^-ea/Rt
๐Ÿ“Œ Where:
๏ฟฝ = rate constant
๏ฟฝ = Arrhenius factor / frequency factor
๏ฟฝ = Activation energy
๏ฟฝ = Gas constant
๏ฟฝ = Temperature (K)

โญ Log Form (Most Used)
LogK=logA-Ea/2.303RT

โญ Two Temperature Form
Log K2/K2=Ea/2.303R(T2-T1/T2โ€ขT1)

#Graph
โœ”๏ธ log k vs 1/T โ†’ Straight line
โœ”๏ธ Slope โ†’ โ€“Ea / 2.303R
โœ”๏ธ Intercept โ†’ log A

#Effect of Catalyst
โœ”๏ธ Lowers Ea
โœ”๏ธ Does NOT change ฮ”H
โœ”๏ธ Increases rate

#NEETHOTPOINTS
โœ”๏ธ Higher Ea โ†’ Slower reaction
โœ”๏ธ Catalyst โ†’ lowers Ea
โœ”๏ธ Temperature โ†‘ โ†’ k โ†‘
โœ”๏ธ Straight line โ†’ log k vs 1/T
โœ”๏ธ Unit of Ea โ†’ J molโปยน

@Ayano1me @Neetugpoll Neetugquiz
๐Ÿฅฐ1๐Ÿ•Š1๐Ÿ†1
General Physical Properties (d-Block)
โญ Atomic & Ionic Size
โœ”๏ธ Size decreases from left โ†’ right (โ†‘ nuclear charge)
โœ”๏ธ After middle โ†’ almost constant (poor shielding by d-electrons)

โญ Density
โœ”๏ธ Increases from 3d โ†’ 4d โ†’ 5d
๐Ÿ“Œ Reason:
Increase in atomic mass
Lanthanide contraction (5d elements smaller โ†’ higher density)

โญ Melting & Boiling Points
โœ”๏ธ Very high
๐Ÿ“Œ Reason:
Strong metallic bonding
Involvement of d-electrons
๐Ÿ“Œ Exceptions:
Zn, Cd, Hg โ†’ low m.p.
โœ”๏ธ Hg โ†’ liquid (weak metallic bonding)

โญ Variable Oxidation States
โœ”๏ธ Due to similar energy of (nโˆ’1)d & ns electrons
๐Ÿ“Œ Example:
Fe โ†’ +2, +3
Mn โ†’ +2 to +7

โญ Magnetic Properties
โœ”๏ธ Paramagnetic โ†’ unpaired electrons
โœ”๏ธ Diamagnetic โ†’ all paired
๐Ÿ“Œ Magnetic moment:
U=โˆšn(n+2)

โญ Colour
โœ”๏ธ Due to dโ€“d transitions
โœ”๏ธ Znยฒโบ, Cdยฒโบ โ†’ colourless (dยนโฐ)
@Ayano1me @Neetugpoll @neetugquiz
โšก1๐Ÿ•Š1๐Ÿ˜˜1
๐ŸŒŸ Lanthanide Contraction (VERY HIGH YIELD ๐Ÿ”ฅ)
๐ŸŒฑ Definition
Gradual decrease in atomic & ionic radii of lanthanides from La โ†’ Lu
#Reason
โœ”๏ธ Poor shielding effect of 4f-electrons
โœ”๏ธ Effective nuclear charge increases
๐Ÿ”ฅ Consequences of Lanthanide Contraction
1๏ธโƒฃ Similar size of 4d & 5d elements
๐Ÿ“Œ Zr โ‰ˆ Hf
๐Ÿ“Œ Chemical properties similar
2๏ธโƒฃ High density of 5d elements
๐Ÿ“Œ Reason:
Smaller size
Higher mass
3๏ธโƒฃ Difficulty in separation of lanthanides
๐Ÿ“Œ Very similar radii & properties
4๏ธโƒฃ Basic strength of hydroxides decreases
๐Ÿ“Œ La(OH)โ‚ƒ > Lu(OH)โ‚ƒ
5๏ธโƒฃ Decrease in ionic radii of Lnยณโบ ions
๐Ÿ“Œ Affects coordination number & complex formation
#NEETHOTPOINTS
โœ”๏ธ Poor shielding โ†’ 4f electrons
โœ”๏ธ Cause of Zrโ€“Hf similarity โ†’ Lanthanide contraction
โœ”๏ธ Colour in d-block โ†’ dโ€“d transition
โœ”๏ธ Colour in f-block โ†’ fโ€“f transition
โœ”๏ธ Most stable oxidation state of lanthanides โ†’ +3
@Ayano1me @Neetugpoll @neetugquiz
๐Ÿ‘1๐Ÿ”ฅ1๐Ÿ•Š1
#CoordinationCompounds
Valence Bond Theory (VBT) & Isomerism (NCERT โ€ข NEET)

๐ŸŒฑ Coordination Compound
A compound in which: โœ”๏ธ Central metal atom/ion
โœ”๏ธ Surrounded by ligands
โœ”๏ธ Linked by coordinate bonds
๐Ÿ“Œ Example: [Co(NHโ‚ƒ)โ‚†]Clโ‚ƒ

โญ #ValenceBondTheory (VBT)
๐ŸŒฑ Explains: โœ”๏ธ Geometry
โœ”๏ธ Magnetic behaviour
โœ”๏ธ Hybridisation

๐Ÿ”น Postulates of VBT
โœ”๏ธ Metal ion provides empty orbitals
โœ”๏ธ Ligands donate lone pair
โœ”๏ธ Overlap โ†’ coordinate bond
โœ”๏ธ Paired/unpaired electrons decide magnetic nature

โญ #Hybridisation&Geometry
Hybridisation :Geometry
dยฒspยณ / spยณdยฒ :Octahedral
spยณ : Tetrahedral
dspยฒ : Square planar

#InnerOrbitalvsOuterOrbitalComplex
โญ Inner Orbital Complex (Low spin)
โœ”๏ธ Uses (nโˆ’1)d orbitals
โœ”๏ธ Pairing of electrons occurs
โœ”๏ธ Strong field ligands
๐Ÿ“Œ Example:
[Co(NHโ‚ƒ)โ‚†]ยณโบ โ†’ dยฒspยณ (octahedral)

โญ Outer Orbital Complex (High spin)
โœ”๏ธ Uses nd orbitals
โœ”๏ธ No pairing
โœ”๏ธ Weak field ligands
๐Ÿ“Œ Example:
[FeFโ‚†]ยณโป โ†’ spยณdยฒ (octahedral)

#MagneticNature (VBT)
โœ”๏ธ Unpaired eโป โ†’ Paramagnetic
โœ”๏ธ Paired eโป โ†’ Diamagnetic
๐Ÿ“Œ Example:
[Ni(CN)โ‚„]ยฒโป โ†’ Diamagnetic (dspยฒ)
[NiClโ‚„]ยฒโป โ†’ Paramagnetic (spยณ)
โš ๏ธ Limitations of VBT
โŒ Cannot explain colour
โŒ Cannot explain strong vs weak ligands clearly
โŒ No quantitative explanation of spectra

@Ayano1me @Neetugpoll @Neetugquiz
๐ŸŽ‰1๐Ÿณ1๐Ÿ™ˆ1
Isomerism in Coordination Compounds
๐ŸŒฑ Compounds with same formula but different arrangement

โญ #Structural Isomerism
1๏ธโƒฃ Ionisation Isomerism
โœ”๏ธ Exchange between ligand & counter ion
๐Ÿ“Œ Example:
[Co(NHโ‚ƒ)โ‚…SOโ‚„]Br
[Co(NHโ‚ƒ)โ‚…Br]SOโ‚„

2๏ธโƒฃ Solvate (Hydrate) Isomerism
โœ”๏ธ Water inside or outside coordination sphere
๐Ÿ“Œ Example:
[Cr(Hโ‚‚O)โ‚†]Clโ‚ƒ
[Cr(Hโ‚‚O)โ‚…Cl]Clโ‚‚ยทHโ‚‚O

3๏ธโƒฃ Linkage Isomerism
โœ”๏ธ Ambidentate ligands
๐Ÿ“Œ Example:
NOโ‚‚โป โ†’ nitro / nitrito
SCNโป โ†’ thiocyanato / isothiocyanato

4๏ธโƒฃ Coordination Isomerism
โœ”๏ธ Between cationic & anionic complexes
๐Ÿ“Œ Example:
[Co(NHโ‚ƒ)โ‚†][Cr(CN)โ‚†]
[Cr(NHโ‚ƒ)โ‚†][Co(CN)โ‚†]

โญ #Stereoisomerism
1๏ธโƒฃ Geometrical Isomerism
โœ”๏ธ cisโ€“trans
๐Ÿ“Œ Examples:
[Pt(NHโ‚ƒ)โ‚‚Clโ‚‚]
[Co(NHโ‚ƒ)โ‚„Clโ‚‚]โบ

2๏ธโƒฃ Optical Isomerism
โœ”๏ธ Non-superimposable mirror images
โœ”๏ธ d & l forms
๐Ÿ“Œ Example:
[Co(en)โ‚ƒ]ยณโบ

#NEETHOTPOINTS
โœ”๏ธ Square planar โ†’ dspยฒ
โœ”๏ธ Strong ligand โ†’ pairing โ†’ inner orbital
โœ”๏ธ Ambidentate ligand โ†’ linkage isomerism
โœ”๏ธ cisโ€“trans in square planar & octahedral
โœ”๏ธ Optical isomerism โ†’ no plane of symmetry

@Ayano1me @Neetugpoll @Neetugquiz
๐ŸŽ‰1๐Ÿคฉ1๐Ÿ‘Œ1
#Haloalkanes
Alkanes in which H is replaced by halogen (F, Cl, Br, I)
๐Ÿ“Œ General formula: Rโ€“X
๐Ÿ”„ Nucleophilic Substitution Reactions
โญ SN1 Reaction (Unimolecular)
๐ŸŒฑ Rate depends on only one species
๐Ÿ“Œ Rate = k[Rโ€“X]
๐Ÿ”น Mechanism (2 Step)
1๏ธโƒฃ Rโ€“X โ†’ Rโบ + Xโป (Slow, RDS)
2๏ธโƒฃ Rโบ + Nuโป โ†’ Rโ€“Nu (Fast)
โญ Key Features
โœ”๏ธ Formation of carbocation
โœ”๏ธ Rearrangement possible
โœ”๏ธ Racemisation occurs
โœ”๏ธ Favoured by polar protic solvents
โญ Order of Reactivity
3ยฐ > 2ยฐ > 1ยฐ > CHโ‚ƒ
๐Ÿ“Œ Reason: Carbocation stability
โญ SN2 Reaction (Bimolecular)
๐ŸŒฑ Single step reaction
๐Ÿ“Œ Rate = k[Rโ€“X][Nuโป]
๐Ÿ”น Mechanism
โœ”๏ธ Backside attack
โœ”๏ธ Transition state formation
โœ”๏ธ Simultaneous bond making & breaking
โญ Key Features
โœ”๏ธ No carbocation
โœ”๏ธ No rearrangement
โœ”๏ธ Inversion of configuration (Walden inversion)
โœ”๏ธ Favoured by polar aprotic solvents
โญ Order of Reactivity
CHโ‚ƒ > 1ยฐ > 2ยฐ >> 3ยฐ
๐Ÿ“Œ Reason: Steric hindrance

SN1 vs SN2 (Direct MCQ)
Feature :SN1 :SN2
Steps :2 :1
Rate depends on :Rโ€“X :Rโ€“X & Nuโป
Intermediate :Carbocation :None
Rearrangement :โœ”๏ธ :โŒ
Stereochemistry :Racemisation
: Inversion
Favoured by ;3ยฐ haloalkane
: 1ยฐ haloalkane

@Ayano1me @Neetugpoll @Neetugquiz
๐Ÿ•Š1๐Ÿณ1๐Ÿ†1
#PreparationofHaloalkanes
โญ 1๏ธโƒฃ From Alcohols
โœ”๏ธ Using HX
๐Ÿ“Œ Reactivity:
3ยฐ > 2ยฐ > 1ยฐ
โœ”๏ธ Using PClโ‚ƒ / PClโ‚… / SOClโ‚‚
๐Ÿ“Œ SOClโ‚‚ best โ†’ gaseous by-products
โญ 2๏ธโƒฃ From Alkenes
โœ”๏ธ Addition of HX (Markovnikov rule)
โœ”๏ธ Anti-Markovnikov (HBr + peroxide)
โญ 3๏ธโƒฃ From Alkanes
โœ”๏ธ Free radical halogenation
โœ”๏ธ Less selective
โญ 4๏ธโƒฃ Finkelstein Reaction
โœ”๏ธ Rโ€“Cl / Rโ€“Br + NaI (acetone) โ†’ Rโ€“I
โญ 5๏ธโƒฃ Swarts Reaction
โœ”๏ธ Rโ€“Cl / Rโ€“Br โ†’ Rโ€“F
โœ”๏ธ Using AgF / Hgโ‚‚Fโ‚‚
#NEETHOTPOINTS
โœ”๏ธ SN1 โ†’ Carbocation intermediate
โœ”๏ธ SN2 โ†’ Walden inversion
โœ”๏ธ 3ยฐ haloalkane โ†’ SN1 favoured
โœ”๏ธ SOClโ‚‚ โ†’ best for Rโ€“Cl
โœ”๏ธ Anti-Markovnikov โ†’ HBr + peroxide

@Ayano1me @Neetugpoll @Neetugquiz
โค1๐Ÿฅฐ1๐Ÿ˜1๐Ÿ’ฏ1
#Alcohols
Organic compounds containing โ€“OH group attached to spยณ carbon
๐Ÿ“Œ General formula: Rโ€“OH

โญ #PreparationofAlcohols
1๏ธโƒฃ From Alkenes
โœ”๏ธ Acid-catalysed hydration
RCH=CH2+H+/H20 = RCH(OH) -CH3
๐Ÿ“Œ Follows Markovnikovโ€™s rule

Hydroborationโ€“Oxidation
RCH=CH2+BH3/THF, H2O2/OH^- = RCH2-CH2OH
๐Ÿ“Œ Anti-Markovnikov, no rearrangement

2๏ธโƒฃ From Haloalkanes
R-X+Aq KOH= ROH

3๏ธโƒฃ From Aldehydes & Ketones
โœ”๏ธ Reduction using:
NaBHโ‚„
LiAlHโ‚„
๐Ÿ“Œ Aldehyde โ†’ 1ยฐ alcohol
๐Ÿ“Œ Ketone โ†’ 2ยฐ alcohol

4๏ธโƒฃ From Grignard Reagent
RMGX+ HCHO=1ยฐ alcohol
RMGX+ RCHO=2ยฐalcohol
RMGX+R2CO=3ยฐalcohol


#NEETHOTPOINTS (Alcohol)
โœ”๏ธ Hydroboration โ†’ Anti-Markovnikov
โœ”๏ธ NaBHโ‚„ milder than LiAlHโ‚„
โœ”๏ธ Grignard reagent + HCHO โ†’ 1ยฐ alcohol

@Ayano1me @Neetugpoll @Neetugquiz
๐Ÿ”ฅ1๐Ÿ•Š1๐Ÿณ1
Ethers
Organic compounds with โ€“Oโ€“ linkage
๐Ÿ“Œ General formula: Rโ€“Oโ€“Rโ€ฒ

Williamson Ether Synthesis (Very High Yield ๐Ÿ”ฅ)
๐Ÿ“Œ Best method to prepare ethers
RONA+R'X = ROR' + Nax
โœ”๏ธ Involves SN2 mechanism
โœ”๏ธ Best with 1ยฐ haloalkane
โŒ 3ยฐ haloalkane โ†’ Elimination occurs
๐Ÿ“Œ For unsymmetrical ether:
Use bulky group as alkoxide
Smaller group as haloalkane

โญ Reaction of Ether with HI
๐Ÿ“Œ Ether cleavage by HI / HBr
๐Ÿ”น Mechanism
โœ”๏ธ Protonation of ether oxygen
โœ”๏ธ Iโป attacks alkyl group

#CaseWiseReaction

1๏ธโƒฃ Symmetrical Ether
R-O-R+ 2HI = 2RI + H20

2๏ธโƒฃ Unsymmetrical Ether
โœ”๏ธ If one group is 3ยฐ โ†’ Cleavage at 3ยฐ carbon (SN1)
โœ”๏ธ If both are 1ยฐ โ†’ Iโป attacks less hindered carbon (SN2)
๐Ÿ“Œ Example:

CH3-O-C2H5 + HI = Ch3I + C2H5OH

NEETHOTPOINTS (Ether)
โœ”๏ธ Williamson โ†’ SN2 reaction
โœ”๏ธ Best haloalkane โ†’ 1ยฐ
โœ”๏ธ Ether cleavage โ†’ HI > HBr
โœ”๏ธ 3ยฐ ether โ†’ SN1 cleavage
โœ”๏ธ Unsymmetrical ether โ†’ less hindered side breaks

@Ayano1me @Neetugpoll @Neetugquiz
๐Ÿณ2โค1
Aldehyde Ketone & Carbohydrates

1๏ธโƒฃ Important Name Reactions & Tests
โœ… #Aldehydes
โญTollensโ€™ Test
Aldehyde + [Ag(NH3) 2}^+โ†’ Silver mirror
๐Ÿ‘‰ Ketone โŒ (except ฮฑ-hydroxy ketone

โญFehlingโ€™s Test ๐Ÿ”ตโžก๏ธ๐Ÿ”ด
Aliphatic aldehyde โ†’ Red ppt (Cuโ‚‚O)
๐Ÿ‘‰ Aromatic aldehyde โŒ

โญBenedictโ€™s Test
Similar to Fehlingโ€™s (for reducing sugars)

โญSchiffโ€™s Test
Pink colour โ†’ Aldehyde present


#Ketones
โญIodoform Test ๐ŸŸก
Group present: โ€“COCHโ‚ƒ
Positive for:
Acetone
Ethanol
2ยฐ alcohol with โ€“CHOHโ€“CHโ‚ƒ

โญ 2,4-DNP Test
Orange / yellow ppt โ†’ Carbonyl present (Ald/Ket)

#ImportantNameReactions

โญAldol Condensation
Aldehyde/Ketone with ฮฑ-H โ†’ ฮฒ-hydroxy aldehyde โ†’ ฮฑ,ฮฒ-unsat compound

โญ Cannizzaro Reaction
Aldehyde without ฮฑ-H โ†’ Alcohol + Acid (base medium)

โญClemmensen Reduction
Zn-Hg /HCL - C=O โ†’ โ€“CHโ‚‚โ€“

โญWolffโ€“Kishner Reduction
NH2NH2/KOHโ†’ C=O โ†’ โ€“CHโ‚‚โ€“

#CarbohydratesImportantTests
Molisch Test โ†’ Violet ring (general test)
Fehling / Benedict โ†’ Red ppt (reducing sugar)
Barfoed Test โ†’ Monosaccharide (+ fast)
Iodine Test โ†’ Blue colour (starch)
Osazone Test โ†’ Needle shaped crystals (glucose = fructose)

@Ayano1me @Neetugpoll @Neetugquiz
๐Ÿ˜2
2: #NucleophilicAdditionReactions
๐Ÿ“Œ General Reaction
RCHO/R-CO-R'+NU^- = Additional product

๐Ÿ“Œ Reactivity Order
Aldehyde > Ketone
(H- > CHโ‚ƒ- > bulky alkyl)

#ImportantNucleophiles
HCN โ†’ Cyanohydrin
NaHSOโ‚ƒ โ†’ Bisulphite compound
RMgX (Grignard)
HCHO โ†’ 1ยฐ alcohol
Aldehyde โ†’ 2ยฐ alcohol
Ketone โ†’ 3ยฐ alcohol
NHโ‚‚OH โ†’ Oxime
NHโ‚‚NHโ‚‚ โ†’ Hydrazone
2,4-DNP โ†’ Orange ppt

#NCERTDirectPoints
Aldehydes oxidise easily โœ”๏ธ
Ketones resist oxidation โŒ
Formaldehyde is most reactive
Benzaldehyde โŒ Fehling test

@Ayano1me @Neetugpoll @Neetugquiz
๐Ÿฅฐ2๐Ÿ‘Œ1
#AMINES Topic : 9

1๏ธโƒฃ Important Name Reactions & Tests
#NameReactions

Hoffmann Bromamide Reaction

1โญ Amide โ†’ 1ยฐ amine (one C less)
RCONH2+ BR2+KOH = RNH2

2โญGabriel Phthalimide Synthesis
Alkyl halide โ†’ 1ยฐ aliphatic amine only
๐Ÿ‘‰ Aromatic โŒ

3โญ Carbylamine Reaction (Confirmatory for 1ยฐ amine)
(bad smell)
R-NH2+CHCl3+KOH=R-NC
Hinsberg Test
1ยฐ amine โ†’ soluble sulphonamide
2ยฐ amine โ†’ insoluble
3ยฐ amine โ†’ no reaction
Diazotisation Reaction
Aromatic 1ยฐ amine + Nano2/HCL(0ยฐ-5ยฐ)โ†’ Diazonium salt

#Tests

โญNitrous Acid Test
1ยฐ aliphatic โ†’ Nโ‚‚ gas
1ยฐ aromatic โ†’ diazonium salt
2ยฐ โ†’ nitrosoamine
3ยฐ โ†’ salt formation

โญAcetylation Test
1ยฐ & 2ยฐ amines react; 3ยฐ โŒ

@Ayano1me @Neetugpoll @Neetugquiz
๐Ÿ•Š2๐ŸŽ‰1๐Ÿ†1
2๏ธโƒฃ Basic Nature of Amines
๐Ÿ“Œ #ReasonofBasicity
Due to lone pair on N
Electron donating groups โ†‘ basicity
Electron withdrawing groups โ†“ basicity
๐Ÿ“Š Basic Strength Order (NCERT)

โญGas phase:
3ยฐ>2ยฐ>1ยฐ>NH3

โญAqueous solution:
2ยฐ>1ยฐ>3ยฐ>NH3
๐Ÿ‘‰ Due to solvation + steric hindrance

โญAromatic ๐Ÿ†š Aliphatic

โญAliphatic amines > NHโ‚ƒ > Aromatic amines

โญAniline less basic due to resonance (lone pair delocalisation)

โš ๏ธ #ImportantNCERTPoints

โญAniline reacts with HNOโ‚‚ at low temp
โญBasicity increases with +I effect
โญOrtho substituted aniline โ†’ less basic (steric + H-bonding)

#NEETTrapLines
โญCarbylamine test โ†’ only 1ยฐ amine
โญGabriel synthesis โ†’ only 1ยฐ aliphatic amine
โญAromatic amines form diazonium salts

@Ayano1me @Neetugpoll @Neetugquiz
๐Ÿ”ฅ2๐Ÿ‘2๐Ÿ˜1
#BIOMOLECULES
โญ1๏ธโƒฃ CARBOHYDRATES
Definition
Polyhydroxy aldehydes or ketones or substances which give them on hydrolysis

๐Ÿ“Œ General formula: Cโ‚™(Hโ‚‚O)โ‚™
โญ Classification of Carbohydrates

โญ 1๏ธโƒฃ Monosaccharides
โœ”๏ธ Cannot be hydrolysed further
โœ”๏ธ Sweet, crystalline
๐Ÿ“Œ Examples:
Glucose (Aldohexose)
Fructose (Ketohexose)
Ribose

โญ 2๏ธโƒฃ Oligosaccharides
โœ”๏ธ 2โ€“10 monosaccharide units
๐Ÿ“Œ Examples:
Sucrose (Glucose + Fructose) โŒ reducing
Maltose (Glucose + Glucose) โœ”๏ธ reducing
Lactose (Glucose + Galactose) โœ”๏ธ reducing


โญ3๏ธโƒฃ Polysaccharides
โœ”๏ธ High molecular weight
โœ”๏ธ Non-sweet
๐Ÿ“Œ Examples:
Starch โ†’ plant storage
Glycogen โ†’ animal storage
Cellulose โ†’ structural (

Reducing ๐Ÿ†š Non-Reducing Sugars
โœ”๏ธ Free aldehyde / ketone group โ†’ Reducing
๐Ÿ“Œ Reducing: Glucose, Fructose, Maltose, Lactose
๐Ÿ“Œ Non-reducing: Sucrose

#ImportantNCERTConcepts
โญ D & L Configuration
Based on position of โ€“OH on penultimate carbon
Glucose โ†’ D-glucose

โญ Anomers
Differ at anomeric carbon (C-1 in glucose)
ฮฑ-glucose & ฮฒ-glucose

โญ Epimers
Differ at one carbon (except anomeric)
Glucose & Galactose (C-4)

โญ Glycosidic Bond
Link between two monosaccharides
In sucrose โ†’ ฮฑ-1,ฮฒ-2

#RemeberGuys
Tollenโ€™s / Fehlingโ€™s โ†’ reducing sugars
Iodine test โ†’ starch (blue-black)

@Ayano1me @Neetugpoll @Neetugquiz
๐Ÿ”ฅ2๐Ÿฅฐ2๐Ÿ˜˜1
#PROTEINS
โญ Definition
Polymers of ฮฑ-amino acids joined by peptide bonds
๐Ÿ“Œ Peptide bond: โ€“COโ€“NHโ€“

โญ Amino Acids
๐Ÿ“Œ General formula:
NHโ‚‚โ€“CH(R)โ€“COOH
โœ”๏ธ Zwitterion in aqueous solution
โœ”๏ธ 20 standard amino acids

#Classificationof AminoAcids
โญ Based on Nutrition
Essential โ†’ Diet required
Non-essential โ†’ Synthesised in body

โญBased on Charge
Acidic: Aspartic, Glutamic
Basic: Lysine, Arginine
Neutral: Glycine, Alanine

#ProteinStructureLevels
โญ 1๏ธโƒฃ Primary
โœ”๏ธ Sequence of amino acids
โœ”๏ธ Most specific

โญ 2๏ธโƒฃ Secondary
โœ”๏ธ ฮฑ-helix
โœ”๏ธ ฮฒ-pleated sheet
๐Ÿ“Œ Stabilised by H-bonds

โญ 3๏ธโƒฃ Tertiary
โœ”๏ธ 3D folding
โœ”๏ธ Stabilised by:
Disulfide bonds
Ionic bonds
H-bonds

โญ 4๏ธโƒฃ Quaternary
โœ”๏ธ More than one polypeptide chain
๐Ÿ“Œ Example: Haemoglobin

#TypesofProteins
โญFibrous โ†’ Structural (Keratin, Collagen)

โญGlobular โ†’ Functional (Enzymes)

โญDenaturation
โœ”๏ธ Loss of biological activity
โŒ Primary structure unchanged
๐Ÿ“Œ Causes:
Heat
pH change

๐Ÿ“Œ Example:
Boiled egg white

#NEETHOTPOINTS
โœ”๏ธ Disulfide bond โ†’ Cysteine
โœ”๏ธ Enzymes โ†’ globular proteins
โœ”๏ธ Sucrose โ†’ non-reducing
โœ”๏ธ Cellulose โ†’ ฮฒ-glucose polymer

@Ayano1me @Neetugpoll @Neetugquiz
๐Ÿ˜Ž3๐Ÿ’ฏ1
๐—ง๐—ข๐—ฃ ๐Ÿฎ๐Ÿฌ ๐—›๐—œ๐—š๐—› ๐—ช๐—˜๐—œ๐—š๐—›๐—ง๐—”๐—š๐—˜ ๐—ง๐—ข๐—ฃ๐—œ๐—–๐—ฆ โ€” ๐—–๐—›๐—˜๐— ๐—œ๐—ฆ๐—ง๐—ฅ๐—ฌ


โญ #๐—ฃ๐—›๐—ฌ๐—ฆ๐—œ๐—–๐—”๐—Ÿ๐—–๐—›๐—˜๐— ๐—œ๐—ฆ๐—ง๐—ฅ๐—ฌ

๐—–๐—›๐—”๐—ฃ๐—ง๐—˜๐—ฅ ๐Ÿญ: ๐—ฆ๐—ข๐—Ÿ๐—จ๐—ง๐—œ๐—ข๐—ก

โญ ๐—œ๐——๐—˜๐—”๐—Ÿ ๐—ฆ๐—ข๐—Ÿ๐—จ๐—ง๐—œ๐—ข๐—ก

โญ ๐—–๐—ข๐—Ÿ๐—Ÿ๐—œ๐—š๐—”๐—ง๐—œ๐—ฉ๐—˜ ๐—ฃ๐—ฅ๐—ข๐—ฃ๐—˜๐—ฅ๐—ง๐—œ๐—˜๐—ฆ


๐—–๐—›๐—”๐—ฃ๐—ง๐—˜๐—ฅ ๐Ÿฎ๐—˜๐—Ÿ๐—˜๐—–๐—ง๐—ฅ๐—ข๐—–๐—›๐—˜๐— ๐—œ๐—ฆ๐—ง๐—ฅ๐—ฌ

โญ ๐—ก๐—˜๐—ฅ๐—ก๐—ฆ๐—ง ๐—˜๐—ค๐—จ๐—”๐—ง๐—œ๐—ข๐—ก

โญ ๐—–๐—ข๐—ก๐——๐—จ๐—–๐—ง๐—œ๐—ฉ๐—œ๐—ง๐—ฌ

๐—–๐—›๐—”๐—ฃ๐—ง๐—˜๐—ฅ ๐Ÿฏ: ๐—–๐—›๐—˜๐— ๐—œ๐—–๐—”๐—Ÿ ๐—ž๐—œ๐—ก๐—˜๐—ง๐—œ๐—–๐—ฆ

โญ ๐—™๐—œ๐—ฅ๐—ฆ๐—ง ๐—ข๐—ฅ๐——๐—˜๐—ฅ ๐—ฅ๐—˜๐—”๐—–๐—ง๐—œ๐—ข๐—ก๐—ฆ

โญ ๐—”๐—ฅ๐—ฅ๐—›๐—˜๐—ก๐—œ๐—จ๐—ฆ ๐—˜๐—ค๐—จ๐—”๐—ง๐—œ๐—ข๐—ก



โญ #๐—œ๐—ก๐—ข๐—ฅ๐—š๐—”๐—ก๐—œ๐—– ๐—–๐—›๐—˜๐— ๐—œ๐—ฆ๐—ง๐—ฅ๐—ฌ

๐—–๐—›๐—”๐—ฃ๐—ง๐—˜๐—ฅ ๐Ÿฐ: ๐—— & ๐—™ ๐—•๐—Ÿ๐—ข๐—–๐—ž ๐—˜๐—Ÿ๐—˜๐— ๐—˜๐—ก๐—ง๐—ฆ

โญ ๐—ฃ๐—›๐—ฌ๐—ฆ๐—œ๐—–๐—”๐—Ÿ ๐—ฃ๐—ฅ๐—ข๐—ฃ๐—˜๐—ฅ๐—ง๐—œ๐—˜๐—ฆ & ๐—ฅ๐—˜๐—”๐—ฆ๐—ข๐—ก๐—œ๐—ก๐—š

โญ ๐—Ÿ๐—”๐—ก๐—ง๐—›๐—”๐—ก๐—ข๐—œ๐—— ๐—–๐—ข๐—ก๐—ง๐—ฅ๐—”๐—–๐—ง๐—œ๐—ข๐—ก

๐—–๐—›๐—”๐—ฃ๐—ง๐—˜๐—ฅ ๐Ÿฑ: ๐—–๐—ข๐—ข๐—ฅ๐——๐—œ๐—ก๐—”๐—ง๐—œ๐—ข๐—ก ๐—–๐—›๐—˜๐— ๐—œ๐—ฆ๐—ง๐—ฅ๐—ฌ

โญ ๐—ฉ๐—”๐—Ÿ๐—˜๐—ก๐—–๐—˜ ๐—•๐—ข๐—ก๐—— ๐—ง๐—›๐—˜๐—ข๐—ฅ๐—ฌ (๐—ฉ๐—•๐—ง)

โญ ๐—œ๐—ฆ๐—ข๐— ๐—˜๐—ฅ๐—œ๐—ฆ๐— 


โญ #๐—ข๐—ฅ๐—š๐—”๐—ก๐—œ๐—– ๐—–๐—›๐—˜๐— ๐—œ๐—ฆ๐—ง๐—ฅ๐—ฌ

๐—–๐—›๐—”๐—ฃ๐—ง๐—˜๐—ฅ ๐Ÿฒ: ๐—›๐—”๐—Ÿ๐—ข๐—”๐—Ÿ๐—ž๐—”๐—ก๐—˜๐—ฆ & ๐—›๐—”๐—Ÿ๐—ข๐—”๐—ฅ๐—˜๐—ก๐—˜๐—ฆ

โญ ๐—ฆ๐—ก๐Ÿญ & ๐—ฆ๐—ก๐Ÿฎ ๐—ฅ๐—˜๐—”๐—–๐—ง๐—œ๐—ข๐—ก๐—ฆ

โญ ๐—ฃ๐—ฅ๐—˜๐—ฃ๐—”๐—ฅ๐—”๐—ง๐—œ๐—ข๐—ก ๐—ข๐—™ ๐—›๐—”๐—Ÿ๐—ข๐—”๐—Ÿ๐—ž๐—”๐—ก๐—˜๐—ฆ

๐—–๐—›๐—”๐—ฃ๐—ง๐—˜๐—ฅ ๐Ÿณ: ๐—”๐—Ÿ๐—–๐—ข๐—›๐—ข๐—Ÿ๐—ฆ, ๐—ฃ๐—›๐—˜๐—ก๐—ข๐—Ÿ๐—ฆ & ๐—˜๐—ง๐—›๐—˜๐—ฅ๐—ฆ

โญ ๐—ฃ๐—ฅ๐—˜๐—ฃ๐—”๐—ฅ๐—”๐—ง๐—œ๐—ข๐—ก ๐—ข๐—™ ๐—”๐—Ÿ๐—–๐—ข๐—›๐—ข๐—Ÿ๐—ฆ

โญ ๐—ช๐—œ๐—Ÿ๐—Ÿ๐—œ๐—”๐— ๐—ฆ๐—ข๐—ก ๐—˜๐—ง๐—›๐—˜๐—ฅ ๐—ฆ๐—ฌ๐—ก๐—ง๐—›๐—˜๐—ฆ๐—œ๐—ฆ
๐—›๐—œ ๐—ฅ๐—˜๐—”๐—–๐—ง๐—œ๐—ข๐—ก


๐—–๐—›๐—”๐—ฃ๐—ง๐—˜๐—ฅ ๐Ÿด: ๐—”๐—Ÿ๐——๐—˜๐—›๐—ฌ๐——๐—˜๐—ฆ, ๐—ž๐—˜๐—ง๐—ข๐—ก๐—˜๐—ฆ & ๐—–๐—”๐—ฅ๐—•๐—ข๐—ซ๐—ฌ๐—Ÿ๐—œ๐—– ๐—”๐—–๐—œ๐——๐—ฆ

โญ ๐—ก๐—”๐— ๐—˜ ๐—ฅ๐—˜๐—”๐—–๐—ง๐—œ๐—ข๐—ก๐—ฆ / ๐—ง๐—˜๐—ฆ๐—ง๐—ฆ

โญ ๐—ก๐—จ๐—–๐—Ÿ๐—˜๐—ข๐—ฃ๐—›๐—œ๐—Ÿ๐—œ๐—– ๐—”๐——๐——๐—œ๐—ง๐—œ๐—ข๐—ก ๐—ฅ๐—˜๐—”๐—–๐—ง๐—œ๐—ข๐—ก๐—ฆ

๐—–๐—›๐—”๐—ฃ๐—ง๐—˜๐—ฅ ๐Ÿต: ๐—”๐— ๐—œ๐—ก๐—˜๐—ฆ

โญ ๐—ก๐—”๐— ๐—˜ ๐—ฅ๐—˜๐—”๐—–๐—ง๐—œ๐—ข๐—ก๐—ฆ / ๐—ง๐—˜๐—ฆ๐—ง๐—ฆ

โญ ๐—•๐—”๐—ฆ๐—œ๐—– ๐—ก๐—”๐—ง๐—จ๐—ฅ๐—˜ ๐—ข๐—™ ๐—”๐— ๐—œ๐—ก๐—˜๐—ฆ


๐—–๐—›๐—”๐—ฃ๐—ง๐—˜๐—ฅ ๐Ÿญ๐Ÿฌ: ๐—•๐—œ๐—ข๐— ๐—ข๐—Ÿ๐—˜๐—–๐—จ๐—Ÿ๐—˜๐—ฆ

โญ ๐—–๐—”๐—ฅ๐—•๐—ข๐—›๐—ฌ๐——๐—ฅ๐—”๐—ง๐—˜๐—ฆ

โญ ๐—ฃ๐—ฅ๐—ข๐—ง๐—˜๐—œ๐—ก๐—ฆ

@Ayano1me @Neetugpoll @Neetugquiz
โค5โคโ€๐Ÿ”ฅ2๐Ÿ’ฏ2๐Ÿฅฐ1๐Ÿ˜1
#Day 1

#MOLECONCEPTALLIMPORTANTFORMULAE (NEET)

#BasicRelations

โญNumber of moles (n) = mass (m) / molar mass (M)

โญMass (m) = number of moles (n) ร— molar mass (M)

โญNumber of particles (N) = n ร— NA

โญNumber of moles (n) = N / NA

โญAvogadro number (NA) = 6.022 ร— 10^23

#Gases

โญNumber of moles at STP (n) = volume (V in litres) / 22.4

โญIdeal gas equation
P ร— V = n ร— R ร— T

โญDensity of gas (d) = (P ร— M) / (R ร— T)

โญMolar mass of gas (M) = (d ร— R ร— T) / P

#Solutions

โญMolarity (M) = number of moles of solute / volume of solution (in litre)

โญMolality (m) = number of moles of solute / mass of solvent (in kg)

โญNormality (N) = number of equivalents / volume of solution (in litre)

โญStrength of solution (g/L) = molarity ร— molar mass

โญDilution Formula
M1 ร— V1 = M2 ร— V2

โญEquivalent Concept
Equivalent mass = molar mass / n-factor

โญNumber of equivalents = mass / equivalent mass

โญMole Fraction
Mole fraction of A (XA) = moles of A / (moles of A + moles of B)
XA + XB = 1

โญLimitingReagent
Required moles = given moles / stoichiometric coefficient
The reactant with least required moles is the limiting reagent
Percentage Composition

โญPercentage of element = (mass of element / molar mass of compound) ร— 100

โญEmpirical and Molecular Formula
Empirical formula mass = sum of atomic masses in empirical formula
n = molecular mass / empirical formula mass

โญMolecular formula = empirical formula ร— n

โญGas Mixture (Daltonโ€™s Law)
Total pressure = P1 + P2 + P3 + โ€ฆ

โญPartial pressure of gas A
PA = XA ร— Ptotal
Redox Reactions

โญNormality ร— Volume = constant
N1 ร— V1 = N2 ร— V2
n-factor = number of electrons lost or gained

#ImportantConstants
STP = 273 K and 1 atm
Gas constant
R = 0.0821 L atm molโปยน Kโปยน
R = 8.314 J molโปยน Kโปยน
โคโ€๐Ÿ”ฅ6
#SIGNIFICANTFIGURES
๐ŸŒฑ Definition
Digits which convey certainty + one uncertain digit

โญ Rules to Count Significant Figures
โœ”๏ธ All non-zero digits โ†’ significant
โœ”๏ธ Zeros between non-zero โ†’ significant
โœ”๏ธ Leading zeros โ†’ โŒ not significant
โœ”๏ธ Trailing zeros โ†’ significant only with decimal

๐Ÿ“Œ Examples:
0.0045 โ†’ 2 SF
2.300 โ†’ 4 SF
1500 โ†’ 2 SF (without decimal)

โž•โž– Addition / Subtraction
Result โ†’ least decimal places
๐Ÿ“Œ Example:
12.11 + 0.2 = 12.3

โœ–๏ธโž— Multiplication / Division
Result โ†’ least significant figures
๐Ÿ“Œ Example:
2.5 ร— 1.23 = 3.1 (2 SF)

๐Ÿ”ข Rounding Off Rules
Next digit < 5 โ†’ same
Next digit โ‰ฅ 5 โ†’ +1
๐Ÿ“Œ 2.34 โ†’ 2.3
๐Ÿ“Œ 2.36 โ†’ 2.4

#NEETHOTPOINTS
โœ”๏ธ Exact numbers โ†’ infinite SF
โœ”๏ธ Unit conversion โ†’ SF maintained
โœ”๏ธ Final answer rounding last step

@Ayano1me @Neetugpoll @Neetugquiz
โค6๐Ÿ˜˜2
โค9๐Ÿ˜˜3