Conductivity
๐ฑ Electrical Conductance (G)
๐ Reciprocal of resistance
G=1/R
Unit: Siemens (S)
โญ Specific Conductivity (ฮบ)
Conductance of solution of: โ๏ธ 1 cm length
โ๏ธ 1 cmยฒ area
Depends on:
Concentration
Temperature
Nature of electrolyte
โญ Molar Conductivity (ฮm)
(ฮm)=kร1000/C
Unit: S cmยฒ molโปยน
๐ C = molarity
โ๏ธ Increases on dilution
โ๏ธ Maximum value at infinite dilution โ ฮยฐm
Strong vs Weak Electrolyte
Feature :Strong :Weak
Ionisation :Complete :Partial
ฮm with dilution :Slight โ :Sharp โ
Kohlrausch law :โ๏ธ Applicable
: โ๏ธ Applicable
#Kohlrauschโs Law
At infinite dilution:
ฮmยฐ=(ฮmยฐ+) + ((ฮmยฐ_)
โ๏ธ Helps calculate:
ฮยฐm of weak electrolytes
Degree of dissociation
Ka, Kb
#NEETHOTPOINTS
โ๏ธ Nernst eqn at 298 K โ 0.0591/n
โ๏ธ At equilibrium โ E = 0
โ๏ธ Unit of ฮบ โ S cmโปยน
โ๏ธ ฮm increases with dilution
โ๏ธ Maximum conductivity โ Infinite dilution
@Ayano1me @Neetugpoll @neetugquiz
๐ฑ Electrical Conductance (G)
๐ Reciprocal of resistance
G=1/R
Unit: Siemens (S)
โญ Specific Conductivity (ฮบ)
Conductance of solution of: โ๏ธ 1 cm length
โ๏ธ 1 cmยฒ area
Depends on:
Concentration
Temperature
Nature of electrolyte
โญ Molar Conductivity (ฮm)
(ฮm)=kร1000/C
Unit: S cmยฒ molโปยน
๐ C = molarity
โ๏ธ Increases on dilution
โ๏ธ Maximum value at infinite dilution โ ฮยฐm
Strong vs Weak Electrolyte
Feature :Strong :Weak
Ionisation :Complete :Partial
ฮm with dilution :Slight โ :Sharp โ
Kohlrausch law :โ๏ธ Applicable
: โ๏ธ Applicable
#Kohlrauschโs Law
At infinite dilution:
ฮmยฐ=(ฮmยฐ+) + ((ฮmยฐ_)
โ๏ธ Helps calculate:
ฮยฐm of weak electrolytes
Degree of dissociation
Ka, Kb
#NEETHOTPOINTS
โ๏ธ Nernst eqn at 298 K โ 0.0591/n
โ๏ธ At equilibrium โ E = 0
โ๏ธ Unit of ฮบ โ S cmโปยน
โ๏ธ ฮm increases with dilution
โ๏ธ Maximum conductivity โ Infinite dilution
@Ayano1me @Neetugpoll @neetugquiz
๐ฅ2โค1๐1๐ฏ1
#ChemicalKinetics
โญ First Order Reaction
๐ฑ Definition
Reaction whose rate depends on concentration of one reactant raised to power 1
๐ Rate law:
Rate =k(A)
๐ข Integrated Rate Equation
K=2.303/t log (A)โข/(A)
๐ Where:
๏ฟฝ = rate constant
๏ฟฝ = time
๏ฟฝ = initial concentration
๏ฟฝ = concentration at time t
#Halflife (tยฝ)
Time for concentration to become half
t1/2=0.693/k
โญIndependent of initial concentration (#veryimp )
Units
โ๏ธ Rate constant (k) โ sโปยน
Graph (Direct MCQ)
โ๏ธ log[A] vs t โ Straight line
โ๏ธ Slope โ โk/2.303
Examples
โ๏ธ Radioactive decay
โ๏ธ Decomposition of NโOโ
โ๏ธ Acid hydrolysis of esters (pseudo-first order)
#NEETHOTPOINTS (1st Order)
โ๏ธ Half-life independent of concentration
โ๏ธ Unit of k โ sโปยน
โ๏ธ Straight line graph โ log[A] vs t
โ๏ธ Pseudo-first order โ One reactant in excess
@Ayano1me @Neetugpoll @NeetugQuiz
โญ First Order Reaction
๐ฑ Definition
Reaction whose rate depends on concentration of one reactant raised to power 1
๐ Rate law:
Rate =k(A)
๐ข Integrated Rate Equation
K=2.303/t log (A)โข/(A)
๐ Where:
๏ฟฝ = rate constant
๏ฟฝ = time
๏ฟฝ = initial concentration
๏ฟฝ = concentration at time t
#Halflife (tยฝ)
Time for concentration to become half
t1/2=0.693/k
โญIndependent of initial concentration (#veryimp )
Units
โ๏ธ Rate constant (k) โ sโปยน
Graph (Direct MCQ)
โ๏ธ log[A] vs t โ Straight line
โ๏ธ Slope โ โk/2.303
Examples
โ๏ธ Radioactive decay
โ๏ธ Decomposition of NโOโ
โ๏ธ Acid hydrolysis of esters (pseudo-first order)
#NEETHOTPOINTS (1st Order)
โ๏ธ Half-life independent of concentration
โ๏ธ Unit of k โ sโปยน
โ๏ธ Straight line graph โ log[A] vs t
โ๏ธ Pseudo-first order โ One reactant in excess
@Ayano1me @Neetugpoll @NeetugQuiz
๐1๐1๐1
#Arrhenius Equation
๐ฑ Shows effect of temperature on rate constant
โญ Equation
K=Ae^-ea/Rt
๐ Where:
๏ฟฝ = rate constant
๏ฟฝ = Arrhenius factor / frequency factor
๏ฟฝ = Activation energy
๏ฟฝ = Gas constant
๏ฟฝ = Temperature (K)
โญ Log Form (Most Used)
LogK=logA-Ea/2.303RT
โญ Two Temperature Form
Log K2/K2=Ea/2.303R(T2-T1/T2โขT1)
#Graph
โ๏ธ log k vs 1/T โ Straight line
โ๏ธ Slope โ โEa / 2.303R
โ๏ธ Intercept โ log A
#Effect of Catalyst
โ๏ธ Lowers Ea
โ๏ธ Does NOT change ฮH
โ๏ธ Increases rate
#NEETHOTPOINTS
โ๏ธ Higher Ea โ Slower reaction
โ๏ธ Catalyst โ lowers Ea
โ๏ธ Temperature โ โ k โ
โ๏ธ Straight line โ log k vs 1/T
โ๏ธ Unit of Ea โ J molโปยน
@Ayano1me @Neetugpoll Neetugquiz
๐ฑ Shows effect of temperature on rate constant
โญ Equation
K=Ae^-ea/Rt
๐ Where:
๏ฟฝ = rate constant
๏ฟฝ = Arrhenius factor / frequency factor
๏ฟฝ = Activation energy
๏ฟฝ = Gas constant
๏ฟฝ = Temperature (K)
โญ Log Form (Most Used)
LogK=logA-Ea/2.303RT
โญ Two Temperature Form
Log K2/K2=Ea/2.303R(T2-T1/T2โขT1)
#Graph
โ๏ธ log k vs 1/T โ Straight line
โ๏ธ Slope โ โEa / 2.303R
โ๏ธ Intercept โ log A
#Effect of Catalyst
โ๏ธ Lowers Ea
โ๏ธ Does NOT change ฮH
โ๏ธ Increases rate
#NEETHOTPOINTS
โ๏ธ Higher Ea โ Slower reaction
โ๏ธ Catalyst โ lowers Ea
โ๏ธ Temperature โ โ k โ
โ๏ธ Straight line โ log k vs 1/T
โ๏ธ Unit of Ea โ J molโปยน
@Ayano1me @Neetugpoll Neetugquiz
๐ฅฐ1๐1๐1
General Physical Properties (d-Block)
โญ Atomic & Ionic Size
โ๏ธ Size decreases from left โ right (โ nuclear charge)
โ๏ธ After middle โ almost constant (poor shielding by d-electrons)
โญ Density
โ๏ธ Increases from 3d โ 4d โ 5d
๐ Reason:
Increase in atomic mass
Lanthanide contraction (5d elements smaller โ higher density)
โญ Melting & Boiling Points
โ๏ธ Very high
๐ Reason:
Strong metallic bonding
Involvement of d-electrons
๐ Exceptions:
Zn, Cd, Hg โ low m.p.
โ๏ธ Hg โ liquid (weak metallic bonding)
โญ Variable Oxidation States
โ๏ธ Due to similar energy of (nโ1)d & ns electrons
๐ Example:
Fe โ +2, +3
Mn โ +2 to +7
โญ Magnetic Properties
โ๏ธ Paramagnetic โ unpaired electrons
โ๏ธ Diamagnetic โ all paired
๐ Magnetic moment:
U=โn(n+2)
โญ Colour
โ๏ธ Due to dโd transitions
โ๏ธ Znยฒโบ, Cdยฒโบ โ colourless (dยนโฐ)
@Ayano1me @Neetugpoll @neetugquiz
โญ Atomic & Ionic Size
โ๏ธ Size decreases from left โ right (โ nuclear charge)
โ๏ธ After middle โ almost constant (poor shielding by d-electrons)
โญ Density
โ๏ธ Increases from 3d โ 4d โ 5d
๐ Reason:
Increase in atomic mass
Lanthanide contraction (5d elements smaller โ higher density)
โญ Melting & Boiling Points
โ๏ธ Very high
๐ Reason:
Strong metallic bonding
Involvement of d-electrons
๐ Exceptions:
Zn, Cd, Hg โ low m.p.
โ๏ธ Hg โ liquid (weak metallic bonding)
โญ Variable Oxidation States
โ๏ธ Due to similar energy of (nโ1)d & ns electrons
๐ Example:
Fe โ +2, +3
Mn โ +2 to +7
โญ Magnetic Properties
โ๏ธ Paramagnetic โ unpaired electrons
โ๏ธ Diamagnetic โ all paired
๐ Magnetic moment:
U=โn(n+2)
โญ Colour
โ๏ธ Due to dโd transitions
โ๏ธ Znยฒโบ, Cdยฒโบ โ colourless (dยนโฐ)
@Ayano1me @Neetugpoll @neetugquiz
โก1๐1๐1
๐ Lanthanide Contraction (VERY HIGH YIELD ๐ฅ)
๐ฑ Definition
Gradual decrease in atomic & ionic radii of lanthanides from La โ Lu
#Reason
โ๏ธ Poor shielding effect of 4f-electrons
โ๏ธ Effective nuclear charge increases
๐ฅ Consequences of Lanthanide Contraction
1๏ธโฃ Similar size of 4d & 5d elements
๐ Zr โ Hf
๐ Chemical properties similar
2๏ธโฃ High density of 5d elements
๐ Reason:
Smaller size
Higher mass
3๏ธโฃ Difficulty in separation of lanthanides
๐ Very similar radii & properties
4๏ธโฃ Basic strength of hydroxides decreases
๐ La(OH)โ > Lu(OH)โ
5๏ธโฃ Decrease in ionic radii of Lnยณโบ ions
๐ Affects coordination number & complex formation
#NEETHOTPOINTS
โ๏ธ Poor shielding โ 4f electrons
โ๏ธ Cause of ZrโHf similarity โ Lanthanide contraction
โ๏ธ Colour in d-block โ dโd transition
โ๏ธ Colour in f-block โ fโf transition
โ๏ธ Most stable oxidation state of lanthanides โ +3
@Ayano1me @Neetugpoll @neetugquiz
๐ฑ Definition
Gradual decrease in atomic & ionic radii of lanthanides from La โ Lu
#Reason
โ๏ธ Poor shielding effect of 4f-electrons
โ๏ธ Effective nuclear charge increases
๐ฅ Consequences of Lanthanide Contraction
1๏ธโฃ Similar size of 4d & 5d elements
๐ Zr โ Hf
๐ Chemical properties similar
2๏ธโฃ High density of 5d elements
๐ Reason:
Smaller size
Higher mass
3๏ธโฃ Difficulty in separation of lanthanides
๐ Very similar radii & properties
4๏ธโฃ Basic strength of hydroxides decreases
๐ La(OH)โ > Lu(OH)โ
5๏ธโฃ Decrease in ionic radii of Lnยณโบ ions
๐ Affects coordination number & complex formation
#NEETHOTPOINTS
โ๏ธ Poor shielding โ 4f electrons
โ๏ธ Cause of ZrโHf similarity โ Lanthanide contraction
โ๏ธ Colour in d-block โ dโd transition
โ๏ธ Colour in f-block โ fโf transition
โ๏ธ Most stable oxidation state of lanthanides โ +3
@Ayano1me @Neetugpoll @neetugquiz
๐1๐ฅ1๐1
#CoordinationCompounds
Valence Bond Theory (VBT) & Isomerism (NCERT โข NEET)
๐ฑ Coordination Compound
A compound in which: โ๏ธ Central metal atom/ion
โ๏ธ Surrounded by ligands
โ๏ธ Linked by coordinate bonds
๐ Example: [Co(NHโ)โ]Clโ
โญ #ValenceBondTheory (VBT)
๐ฑ Explains: โ๏ธ Geometry
โ๏ธ Magnetic behaviour
โ๏ธ Hybridisation
๐น Postulates of VBT
โ๏ธ Metal ion provides empty orbitals
โ๏ธ Ligands donate lone pair
โ๏ธ Overlap โ coordinate bond
โ๏ธ Paired/unpaired electrons decide magnetic nature
โญ #Hybridisation&Geometry
Hybridisation :Geometry
dยฒspยณ / spยณdยฒ :Octahedral
spยณ : Tetrahedral
dspยฒ : Square planar
#InnerOrbitalvsOuterOrbitalComplex
โญ Inner Orbital Complex (Low spin)
โ๏ธ Uses (nโ1)d orbitals
โ๏ธ Pairing of electrons occurs
โ๏ธ Strong field ligands
๐ Example:
[Co(NHโ)โ]ยณโบ โ dยฒspยณ (octahedral)
โญ Outer Orbital Complex (High spin)
โ๏ธ Uses nd orbitals
โ๏ธ No pairing
โ๏ธ Weak field ligands
๐ Example:
[FeFโ]ยณโป โ spยณdยฒ (octahedral)
#MagneticNature (VBT)
โ๏ธ Unpaired eโป โ Paramagnetic
โ๏ธ Paired eโป โ Diamagnetic
๐ Example:
[Ni(CN)โ]ยฒโป โ Diamagnetic (dspยฒ)
[NiClโ]ยฒโป โ Paramagnetic (spยณ)
โ ๏ธ Limitations of VBT
โ Cannot explain colour
โ Cannot explain strong vs weak ligands clearly
โ No quantitative explanation of spectra
@Ayano1me @Neetugpoll @Neetugquiz
Valence Bond Theory (VBT) & Isomerism (NCERT โข NEET)
๐ฑ Coordination Compound
A compound in which: โ๏ธ Central metal atom/ion
โ๏ธ Surrounded by ligands
โ๏ธ Linked by coordinate bonds
๐ Example: [Co(NHโ)โ]Clโ
โญ #ValenceBondTheory (VBT)
๐ฑ Explains: โ๏ธ Geometry
โ๏ธ Magnetic behaviour
โ๏ธ Hybridisation
๐น Postulates of VBT
โ๏ธ Metal ion provides empty orbitals
โ๏ธ Ligands donate lone pair
โ๏ธ Overlap โ coordinate bond
โ๏ธ Paired/unpaired electrons decide magnetic nature
โญ #Hybridisation&Geometry
Hybridisation :Geometry
dยฒspยณ / spยณdยฒ :Octahedral
spยณ : Tetrahedral
dspยฒ : Square planar
#InnerOrbitalvsOuterOrbitalComplex
โญ Inner Orbital Complex (Low spin)
โ๏ธ Uses (nโ1)d orbitals
โ๏ธ Pairing of electrons occurs
โ๏ธ Strong field ligands
๐ Example:
[Co(NHโ)โ]ยณโบ โ dยฒspยณ (octahedral)
โญ Outer Orbital Complex (High spin)
โ๏ธ Uses nd orbitals
โ๏ธ No pairing
โ๏ธ Weak field ligands
๐ Example:
[FeFโ]ยณโป โ spยณdยฒ (octahedral)
#MagneticNature (VBT)
โ๏ธ Unpaired eโป โ Paramagnetic
โ๏ธ Paired eโป โ Diamagnetic
๐ Example:
[Ni(CN)โ]ยฒโป โ Diamagnetic (dspยฒ)
[NiClโ]ยฒโป โ Paramagnetic (spยณ)
โ ๏ธ Limitations of VBT
โ Cannot explain colour
โ Cannot explain strong vs weak ligands clearly
โ No quantitative explanation of spectra
@Ayano1me @Neetugpoll @Neetugquiz
๐1๐ณ1๐1
Isomerism in Coordination Compounds
๐ฑ Compounds with same formula but different arrangement
โญ #Structural Isomerism
1๏ธโฃ Ionisation Isomerism
โ๏ธ Exchange between ligand & counter ion
๐ Example:
[Co(NHโ)โ SOโ]Br
[Co(NHโ)โ Br]SOโ
2๏ธโฃ Solvate (Hydrate) Isomerism
โ๏ธ Water inside or outside coordination sphere
๐ Example:
[Cr(HโO)โ]Clโ
[Cr(HโO)โ Cl]ClโยทHโO
3๏ธโฃ Linkage Isomerism
โ๏ธ Ambidentate ligands
๐ Example:
NOโโป โ nitro / nitrito
SCNโป โ thiocyanato / isothiocyanato
4๏ธโฃ Coordination Isomerism
โ๏ธ Between cationic & anionic complexes
๐ Example:
[Co(NHโ)โ][Cr(CN)โ]
[Cr(NHโ)โ][Co(CN)โ]
โญ #Stereoisomerism
1๏ธโฃ Geometrical Isomerism
โ๏ธ cisโtrans
๐ Examples:
[Pt(NHโ)โClโ]
[Co(NHโ)โClโ]โบ
2๏ธโฃ Optical Isomerism
โ๏ธ Non-superimposable mirror images
โ๏ธ d & l forms
๐ Example:
[Co(en)โ]ยณโบ
#NEETHOTPOINTS
โ๏ธ Square planar โ dspยฒ
โ๏ธ Strong ligand โ pairing โ inner orbital
โ๏ธ Ambidentate ligand โ linkage isomerism
โ๏ธ cisโtrans in square planar & octahedral
โ๏ธ Optical isomerism โ no plane of symmetry
@Ayano1me @Neetugpoll @Neetugquiz
๐ฑ Compounds with same formula but different arrangement
โญ #Structural Isomerism
1๏ธโฃ Ionisation Isomerism
โ๏ธ Exchange between ligand & counter ion
๐ Example:
[Co(NHโ)โ SOโ]Br
[Co(NHโ)โ Br]SOโ
2๏ธโฃ Solvate (Hydrate) Isomerism
โ๏ธ Water inside or outside coordination sphere
๐ Example:
[Cr(HโO)โ]Clโ
[Cr(HโO)โ Cl]ClโยทHโO
3๏ธโฃ Linkage Isomerism
โ๏ธ Ambidentate ligands
๐ Example:
NOโโป โ nitro / nitrito
SCNโป โ thiocyanato / isothiocyanato
4๏ธโฃ Coordination Isomerism
โ๏ธ Between cationic & anionic complexes
๐ Example:
[Co(NHโ)โ][Cr(CN)โ]
[Cr(NHโ)โ][Co(CN)โ]
โญ #Stereoisomerism
1๏ธโฃ Geometrical Isomerism
โ๏ธ cisโtrans
๐ Examples:
[Pt(NHโ)โClโ]
[Co(NHโ)โClโ]โบ
2๏ธโฃ Optical Isomerism
โ๏ธ Non-superimposable mirror images
โ๏ธ d & l forms
๐ Example:
[Co(en)โ]ยณโบ
#NEETHOTPOINTS
โ๏ธ Square planar โ dspยฒ
โ๏ธ Strong ligand โ pairing โ inner orbital
โ๏ธ Ambidentate ligand โ linkage isomerism
โ๏ธ cisโtrans in square planar & octahedral
โ๏ธ Optical isomerism โ no plane of symmetry
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๐1๐คฉ1๐1
#Haloalkanes
Alkanes in which H is replaced by halogen (F, Cl, Br, I)
๐ General formula: RโX
๐ Nucleophilic Substitution Reactions
โญ SN1 Reaction (Unimolecular)
๐ฑ Rate depends on only one species
๐ Rate = k[RโX]
๐น Mechanism (2 Step)
1๏ธโฃ RโX โ Rโบ + Xโป (Slow, RDS)
2๏ธโฃ Rโบ + Nuโป โ RโNu (Fast)
โญ Key Features
โ๏ธ Formation of carbocation
โ๏ธ Rearrangement possible
โ๏ธ Racemisation occurs
โ๏ธ Favoured by polar protic solvents
โญ Order of Reactivity
3ยฐ > 2ยฐ > 1ยฐ > CHโ
๐ Reason: Carbocation stability
โญ SN2 Reaction (Bimolecular)
๐ฑ Single step reaction
๐ Rate = k[RโX][Nuโป]
๐น Mechanism
โ๏ธ Backside attack
โ๏ธ Transition state formation
โ๏ธ Simultaneous bond making & breaking
โญ Key Features
โ๏ธ No carbocation
โ๏ธ No rearrangement
โ๏ธ Inversion of configuration (Walden inversion)
โ๏ธ Favoured by polar aprotic solvents
โญ Order of Reactivity
CHโ > 1ยฐ > 2ยฐ >> 3ยฐ
๐ Reason: Steric hindrance
SN1 vs SN2 (Direct MCQ)
Feature :SN1 :SN2
Steps :2 :1
Rate depends on :RโX :RโX & Nuโป
Intermediate :Carbocation :None
Rearrangement :โ๏ธ :โ
Stereochemistry :Racemisation
: Inversion
Favoured by ;3ยฐ haloalkane
: 1ยฐ haloalkane
@Ayano1me @Neetugpoll @Neetugquiz
Alkanes in which H is replaced by halogen (F, Cl, Br, I)
๐ General formula: RโX
๐ Nucleophilic Substitution Reactions
โญ SN1 Reaction (Unimolecular)
๐ฑ Rate depends on only one species
๐ Rate = k[RโX]
๐น Mechanism (2 Step)
1๏ธโฃ RโX โ Rโบ + Xโป (Slow, RDS)
2๏ธโฃ Rโบ + Nuโป โ RโNu (Fast)
โญ Key Features
โ๏ธ Formation of carbocation
โ๏ธ Rearrangement possible
โ๏ธ Racemisation occurs
โ๏ธ Favoured by polar protic solvents
โญ Order of Reactivity
3ยฐ > 2ยฐ > 1ยฐ > CHโ
๐ Reason: Carbocation stability
โญ SN2 Reaction (Bimolecular)
๐ฑ Single step reaction
๐ Rate = k[RโX][Nuโป]
๐น Mechanism
โ๏ธ Backside attack
โ๏ธ Transition state formation
โ๏ธ Simultaneous bond making & breaking
โญ Key Features
โ๏ธ No carbocation
โ๏ธ No rearrangement
โ๏ธ Inversion of configuration (Walden inversion)
โ๏ธ Favoured by polar aprotic solvents
โญ Order of Reactivity
CHโ > 1ยฐ > 2ยฐ >> 3ยฐ
๐ Reason: Steric hindrance
SN1 vs SN2 (Direct MCQ)
Feature :SN1 :SN2
Steps :2 :1
Rate depends on :RโX :RโX & Nuโป
Intermediate :Carbocation :None
Rearrangement :โ๏ธ :โ
Stereochemistry :Racemisation
: Inversion
Favoured by ;3ยฐ haloalkane
: 1ยฐ haloalkane
@Ayano1me @Neetugpoll @Neetugquiz
๐1๐ณ1๐1
#PreparationofHaloalkanes
โญ 1๏ธโฃ From Alcohols
โ๏ธ Using HX
๐ Reactivity:
3ยฐ > 2ยฐ > 1ยฐ
โ๏ธ Using PClโ / PClโ / SOClโ
๐ SOClโ best โ gaseous by-products
โญ 2๏ธโฃ From Alkenes
โ๏ธ Addition of HX (Markovnikov rule)
โ๏ธ Anti-Markovnikov (HBr + peroxide)
โญ 3๏ธโฃ From Alkanes
โ๏ธ Free radical halogenation
โ๏ธ Less selective
โญ 4๏ธโฃ Finkelstein Reaction
โ๏ธ RโCl / RโBr + NaI (acetone) โ RโI
โญ 5๏ธโฃ Swarts Reaction
โ๏ธ RโCl / RโBr โ RโF
โ๏ธ Using AgF / HgโFโ
#NEETHOTPOINTS
โ๏ธ SN1 โ Carbocation intermediate
โ๏ธ SN2 โ Walden inversion
โ๏ธ 3ยฐ haloalkane โ SN1 favoured
โ๏ธ SOClโ โ best for RโCl
โ๏ธ Anti-Markovnikov โ HBr + peroxide
@Ayano1me @Neetugpoll @Neetugquiz
โญ 1๏ธโฃ From Alcohols
โ๏ธ Using HX
๐ Reactivity:
3ยฐ > 2ยฐ > 1ยฐ
โ๏ธ Using PClโ / PClโ / SOClโ
๐ SOClโ best โ gaseous by-products
โญ 2๏ธโฃ From Alkenes
โ๏ธ Addition of HX (Markovnikov rule)
โ๏ธ Anti-Markovnikov (HBr + peroxide)
โญ 3๏ธโฃ From Alkanes
โ๏ธ Free radical halogenation
โ๏ธ Less selective
โญ 4๏ธโฃ Finkelstein Reaction
โ๏ธ RโCl / RโBr + NaI (acetone) โ RโI
โญ 5๏ธโฃ Swarts Reaction
โ๏ธ RโCl / RโBr โ RโF
โ๏ธ Using AgF / HgโFโ
#NEETHOTPOINTS
โ๏ธ SN1 โ Carbocation intermediate
โ๏ธ SN2 โ Walden inversion
โ๏ธ 3ยฐ haloalkane โ SN1 favoured
โ๏ธ SOClโ โ best for RโCl
โ๏ธ Anti-Markovnikov โ HBr + peroxide
@Ayano1me @Neetugpoll @Neetugquiz
โค1๐ฅฐ1๐1๐ฏ1
#Alcohols
Organic compounds containing โOH group attached to spยณ carbon
๐ General formula: RโOH
โญ #PreparationofAlcohols
1๏ธโฃ From Alkenes
โ๏ธ Acid-catalysed hydration
RCH=CH2+H+/H20 = RCH(OH) -CH3
๐ Follows Markovnikovโs rule
HydroborationโOxidation
RCH=CH2+BH3/THF, H2O2/OH^- = RCH2-CH2OH
๐ Anti-Markovnikov, no rearrangement
2๏ธโฃ From Haloalkanes
R-X+Aq KOH= ROH
3๏ธโฃ From Aldehydes & Ketones
โ๏ธ Reduction using:
NaBHโ
LiAlHโ
๐ Aldehyde โ 1ยฐ alcohol
๐ Ketone โ 2ยฐ alcohol
4๏ธโฃ From Grignard Reagent
RMGX+ HCHO=1ยฐ alcohol
RMGX+ RCHO=2ยฐalcohol
RMGX+R2CO=3ยฐalcohol
#NEETHOTPOINTS (Alcohol)
โ๏ธ Hydroboration โ Anti-Markovnikov
โ๏ธ NaBHโ milder than LiAlHโ
โ๏ธ Grignard reagent + HCHO โ 1ยฐ alcohol
@Ayano1me @Neetugpoll @Neetugquiz
Organic compounds containing โOH group attached to spยณ carbon
๐ General formula: RโOH
โญ #PreparationofAlcohols
1๏ธโฃ From Alkenes
โ๏ธ Acid-catalysed hydration
RCH=CH2+H+/H20 = RCH(OH) -CH3
๐ Follows Markovnikovโs rule
HydroborationโOxidation
RCH=CH2+BH3/THF, H2O2/OH^- = RCH2-CH2OH
๐ Anti-Markovnikov, no rearrangement
2๏ธโฃ From Haloalkanes
R-X+Aq KOH= ROH
3๏ธโฃ From Aldehydes & Ketones
โ๏ธ Reduction using:
NaBHโ
LiAlHโ
๐ Aldehyde โ 1ยฐ alcohol
๐ Ketone โ 2ยฐ alcohol
4๏ธโฃ From Grignard Reagent
RMGX+ HCHO=1ยฐ alcohol
RMGX+ RCHO=2ยฐalcohol
RMGX+R2CO=3ยฐalcohol
#NEETHOTPOINTS (Alcohol)
โ๏ธ Hydroboration โ Anti-Markovnikov
โ๏ธ NaBHโ milder than LiAlHโ
โ๏ธ Grignard reagent + HCHO โ 1ยฐ alcohol
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅ1๐1๐ณ1
Ethers
Organic compounds with โOโ linkage
๐ General formula: RโOโRโฒ
Williamson Ether Synthesis (Very High Yield ๐ฅ)
๐ Best method to prepare ethers
RONA+R'X = ROR' + Nax
โ๏ธ Involves SN2 mechanism
โ๏ธ Best with 1ยฐ haloalkane
โ 3ยฐ haloalkane โ Elimination occurs
๐ For unsymmetrical ether:
Use bulky group as alkoxide
Smaller group as haloalkane
โญ Reaction of Ether with HI
๐ Ether cleavage by HI / HBr
๐น Mechanism
โ๏ธ Protonation of ether oxygen
โ๏ธ Iโป attacks alkyl group
#CaseWiseReaction
1๏ธโฃ Symmetrical Ether
R-O-R+ 2HI = 2RI + H20
2๏ธโฃ Unsymmetrical Ether
โ๏ธ If one group is 3ยฐ โ Cleavage at 3ยฐ carbon (SN1)
โ๏ธ If both are 1ยฐ โ Iโป attacks less hindered carbon (SN2)
๐ Example:
CH3-O-C2H5 + HI = Ch3I + C2H5OH
NEETHOTPOINTS (Ether)
โ๏ธ Williamson โ SN2 reaction
โ๏ธ Best haloalkane โ 1ยฐ
โ๏ธ Ether cleavage โ HI > HBr
โ๏ธ 3ยฐ ether โ SN1 cleavage
โ๏ธ Unsymmetrical ether โ less hindered side breaks
@Ayano1me @Neetugpoll @Neetugquiz
Organic compounds with โOโ linkage
๐ General formula: RโOโRโฒ
Williamson Ether Synthesis (Very High Yield ๐ฅ)
๐ Best method to prepare ethers
RONA+R'X = ROR' + Nax
โ๏ธ Involves SN2 mechanism
โ๏ธ Best with 1ยฐ haloalkane
โ 3ยฐ haloalkane โ Elimination occurs
๐ For unsymmetrical ether:
Use bulky group as alkoxide
Smaller group as haloalkane
โญ Reaction of Ether with HI
๐ Ether cleavage by HI / HBr
๐น Mechanism
โ๏ธ Protonation of ether oxygen
โ๏ธ Iโป attacks alkyl group
#CaseWiseReaction
1๏ธโฃ Symmetrical Ether
R-O-R+ 2HI = 2RI + H20
2๏ธโฃ Unsymmetrical Ether
โ๏ธ If one group is 3ยฐ โ Cleavage at 3ยฐ carbon (SN1)
โ๏ธ If both are 1ยฐ โ Iโป attacks less hindered carbon (SN2)
๐ Example:
CH3-O-C2H5 + HI = Ch3I + C2H5OH
NEETHOTPOINTS (Ether)
โ๏ธ Williamson โ SN2 reaction
โ๏ธ Best haloalkane โ 1ยฐ
โ๏ธ Ether cleavage โ HI > HBr
โ๏ธ 3ยฐ ether โ SN1 cleavage
โ๏ธ Unsymmetrical ether โ less hindered side breaks
@Ayano1me @Neetugpoll @Neetugquiz
๐ณ2โค1
Aldehyde Ketone & Carbohydrates
1๏ธโฃ Important Name Reactions & Tests
โ #Aldehydes
โญTollensโ Test
Aldehyde + [Ag(NH3) 2}^+โ Silver mirror
๐ Ketone โ (except ฮฑ-hydroxy ketone
โญFehlingโs Test ๐ตโก๏ธ๐ด
Aliphatic aldehyde โ Red ppt (CuโO)
๐ Aromatic aldehyde โ
โญBenedictโs Test
Similar to Fehlingโs (for reducing sugars)
โญSchiffโs Test
Pink colour โ Aldehyde present
#Ketones
โญIodoform Test ๐ก
Group present: โCOCHโ
Positive for:
Acetone
Ethanol
2ยฐ alcohol with โCHOHโCHโ
โญ 2,4-DNP Test
Orange / yellow ppt โ Carbonyl present (Ald/Ket)
#ImportantNameReactions
โญAldol Condensation
Aldehyde/Ketone with ฮฑ-H โ ฮฒ-hydroxy aldehyde โ ฮฑ,ฮฒ-unsat compound
โญ Cannizzaro Reaction
Aldehyde without ฮฑ-H โ Alcohol + Acid (base medium)
โญClemmensen Reduction
Zn-Hg /HCL - C=O โ โCHโโ
โญWolffโKishner Reduction
NH2NH2/KOHโ C=O โ โCHโโ
#CarbohydratesImportantTests
Molisch Test โ Violet ring (general test)
Fehling / Benedict โ Red ppt (reducing sugar)
Barfoed Test โ Monosaccharide (+ fast)
Iodine Test โ Blue colour (starch)
Osazone Test โ Needle shaped crystals (glucose = fructose)
@Ayano1me @Neetugpoll @Neetugquiz
1๏ธโฃ Important Name Reactions & Tests
โ #Aldehydes
โญTollensโ Test
Aldehyde + [Ag(NH3) 2}^+โ Silver mirror
๐ Ketone โ (except ฮฑ-hydroxy ketone
โญFehlingโs Test ๐ตโก๏ธ๐ด
Aliphatic aldehyde โ Red ppt (CuโO)
๐ Aromatic aldehyde โ
โญBenedictโs Test
Similar to Fehlingโs (for reducing sugars)
โญSchiffโs Test
Pink colour โ Aldehyde present
#Ketones
โญIodoform Test ๐ก
Group present: โCOCHโ
Positive for:
Acetone
Ethanol
2ยฐ alcohol with โCHOHโCHโ
โญ 2,4-DNP Test
Orange / yellow ppt โ Carbonyl present (Ald/Ket)
#ImportantNameReactions
โญAldol Condensation
Aldehyde/Ketone with ฮฑ-H โ ฮฒ-hydroxy aldehyde โ ฮฑ,ฮฒ-unsat compound
โญ Cannizzaro Reaction
Aldehyde without ฮฑ-H โ Alcohol + Acid (base medium)
โญClemmensen Reduction
Zn-Hg /HCL - C=O โ โCHโโ
โญWolffโKishner Reduction
NH2NH2/KOHโ C=O โ โCHโโ
#CarbohydratesImportantTests
Molisch Test โ Violet ring (general test)
Fehling / Benedict โ Red ppt (reducing sugar)
Barfoed Test โ Monosaccharide (+ fast)
Iodine Test โ Blue colour (starch)
Osazone Test โ Needle shaped crystals (glucose = fructose)
@Ayano1me @Neetugpoll @Neetugquiz
๐2
2: #NucleophilicAdditionReactions
๐ General Reaction
RCHO/R-CO-R'+NU^- = Additional product
๐ Reactivity Order
Aldehyde > Ketone
(H- > CHโ- > bulky alkyl)
#ImportantNucleophiles
HCN โ Cyanohydrin
NaHSOโ โ Bisulphite compound
RMgX (Grignard)
HCHO โ 1ยฐ alcohol
Aldehyde โ 2ยฐ alcohol
Ketone โ 3ยฐ alcohol
NHโOH โ Oxime
NHโNHโ โ Hydrazone
2,4-DNP โ Orange ppt
#NCERTDirectPoints
Aldehydes oxidise easily โ๏ธ
Ketones resist oxidation โ
Formaldehyde is most reactive
Benzaldehyde โ Fehling test
@Ayano1me @Neetugpoll @Neetugquiz
๐ General Reaction
RCHO/R-CO-R'+NU^- = Additional product
๐ Reactivity Order
Aldehyde > Ketone
(H- > CHโ- > bulky alkyl)
#ImportantNucleophiles
HCN โ Cyanohydrin
NaHSOโ โ Bisulphite compound
RMgX (Grignard)
HCHO โ 1ยฐ alcohol
Aldehyde โ 2ยฐ alcohol
Ketone โ 3ยฐ alcohol
NHโOH โ Oxime
NHโNHโ โ Hydrazone
2,4-DNP โ Orange ppt
#NCERTDirectPoints
Aldehydes oxidise easily โ๏ธ
Ketones resist oxidation โ
Formaldehyde is most reactive
Benzaldehyde โ Fehling test
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅฐ2๐1
#AMINES Topic : 9
1๏ธโฃ Important Name Reactions & Tests
#NameReactions
Hoffmann Bromamide Reaction
1โญ Amide โ 1ยฐ amine (one C less)
RCONH2+ BR2+KOH = RNH2
2โญGabriel Phthalimide Synthesis
Alkyl halide โ 1ยฐ aliphatic amine only
๐ Aromatic โ
3โญ Carbylamine Reaction (Confirmatory for 1ยฐ amine)
(bad smell)
R-NH2+CHCl3+KOH=R-NC
Hinsberg Test
1ยฐ amine โ soluble sulphonamide
2ยฐ amine โ insoluble
3ยฐ amine โ no reaction
Diazotisation Reaction
Aromatic 1ยฐ amine + Nano2/HCL(0ยฐ-5ยฐ)โ Diazonium salt
#Tests
โญNitrous Acid Test
1ยฐ aliphatic โ Nโ gas
1ยฐ aromatic โ diazonium salt
2ยฐ โ nitrosoamine
3ยฐ โ salt formation
โญAcetylation Test
1ยฐ & 2ยฐ amines react; 3ยฐ โ
@Ayano1me @Neetugpoll @Neetugquiz
1๏ธโฃ Important Name Reactions & Tests
#NameReactions
Hoffmann Bromamide Reaction
1โญ Amide โ 1ยฐ amine (one C less)
RCONH2+ BR2+KOH = RNH2
2โญGabriel Phthalimide Synthesis
Alkyl halide โ 1ยฐ aliphatic amine only
๐ Aromatic โ
3โญ Carbylamine Reaction (Confirmatory for 1ยฐ amine)
(bad smell)
R-NH2+CHCl3+KOH=R-NC
Hinsberg Test
1ยฐ amine โ soluble sulphonamide
2ยฐ amine โ insoluble
3ยฐ amine โ no reaction
Diazotisation Reaction
Aromatic 1ยฐ amine + Nano2/HCL(0ยฐ-5ยฐ)โ Diazonium salt
#Tests
โญNitrous Acid Test
1ยฐ aliphatic โ Nโ gas
1ยฐ aromatic โ diazonium salt
2ยฐ โ nitrosoamine
3ยฐ โ salt formation
โญAcetylation Test
1ยฐ & 2ยฐ amines react; 3ยฐ โ
@Ayano1me @Neetugpoll @Neetugquiz
๐2๐1๐1
2๏ธโฃ Basic Nature of Amines
๐ #ReasonofBasicity
Due to lone pair on N
Electron donating groups โ basicity
Electron withdrawing groups โ basicity
๐ Basic Strength Order (NCERT)
โญGas phase:
3ยฐ>2ยฐ>1ยฐ>NH3
โญAqueous solution:
2ยฐ>1ยฐ>3ยฐ>NH3
๐ Due to solvation + steric hindrance
โญAromatic ๐ Aliphatic
โญAliphatic amines > NHโ > Aromatic amines
โญAniline less basic due to resonance (lone pair delocalisation)
โ ๏ธ #ImportantNCERTPoints
โญAniline reacts with HNOโ at low temp
โญBasicity increases with +I effect
โญOrtho substituted aniline โ less basic (steric + H-bonding)
#NEETTrapLines
โญCarbylamine test โ only 1ยฐ amine
โญGabriel synthesis โ only 1ยฐ aliphatic amine
โญAromatic amines form diazonium salts
@Ayano1me @Neetugpoll @Neetugquiz
๐ #ReasonofBasicity
Due to lone pair on N
Electron donating groups โ basicity
Electron withdrawing groups โ basicity
๐ Basic Strength Order (NCERT)
โญGas phase:
3ยฐ>2ยฐ>1ยฐ>NH3
โญAqueous solution:
2ยฐ>1ยฐ>3ยฐ>NH3
๐ Due to solvation + steric hindrance
โญAromatic ๐ Aliphatic
โญAliphatic amines > NHโ > Aromatic amines
โญAniline less basic due to resonance (lone pair delocalisation)
โ ๏ธ #ImportantNCERTPoints
โญAniline reacts with HNOโ at low temp
โญBasicity increases with +I effect
โญOrtho substituted aniline โ less basic (steric + H-bonding)
#NEETTrapLines
โญCarbylamine test โ only 1ยฐ amine
โญGabriel synthesis โ only 1ยฐ aliphatic amine
โญAromatic amines form diazonium salts
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅ2๐2๐1
#BIOMOLECULES
โญ1๏ธโฃ CARBOHYDRATES
Definition
Polyhydroxy aldehydes or ketones or substances which give them on hydrolysis
๐ General formula: Cโ(HโO)โ
โญ Classification of Carbohydrates
โญ 1๏ธโฃ Monosaccharides
โ๏ธ Cannot be hydrolysed further
โ๏ธ Sweet, crystalline
๐ Examples:
Glucose (Aldohexose)
Fructose (Ketohexose)
Ribose
โญ 2๏ธโฃ Oligosaccharides
โ๏ธ 2โ10 monosaccharide units
๐ Examples:
Sucrose (Glucose + Fructose) โ reducing
Maltose (Glucose + Glucose) โ๏ธ reducing
Lactose (Glucose + Galactose) โ๏ธ reducing
โญ3๏ธโฃ Polysaccharides
โ๏ธ High molecular weight
โ๏ธ Non-sweet
๐ Examples:
Starch โ plant storage
Glycogen โ animal storage
Cellulose โ structural (
Reducing ๐ Non-Reducing Sugars
โ๏ธ Free aldehyde / ketone group โ Reducing
๐ Reducing: Glucose, Fructose, Maltose, Lactose
๐ Non-reducing: Sucrose
#ImportantNCERTConcepts
โญ D & L Configuration
Based on position of โOH on penultimate carbon
Glucose โ D-glucose
โญ Anomers
Differ at anomeric carbon (C-1 in glucose)
ฮฑ-glucose & ฮฒ-glucose
โญ Epimers
Differ at one carbon (except anomeric)
Glucose & Galactose (C-4)
โญ Glycosidic Bond
Link between two monosaccharides
In sucrose โ ฮฑ-1,ฮฒ-2
#RemeberGuys
Tollenโs / Fehlingโs โ reducing sugars
Iodine test โ starch (blue-black)
@Ayano1me @Neetugpoll @Neetugquiz
โญ1๏ธโฃ CARBOHYDRATES
Definition
Polyhydroxy aldehydes or ketones or substances which give them on hydrolysis
๐ General formula: Cโ(HโO)โ
โญ Classification of Carbohydrates
โญ 1๏ธโฃ Monosaccharides
โ๏ธ Cannot be hydrolysed further
โ๏ธ Sweet, crystalline
๐ Examples:
Glucose (Aldohexose)
Fructose (Ketohexose)
Ribose
โญ 2๏ธโฃ Oligosaccharides
โ๏ธ 2โ10 monosaccharide units
๐ Examples:
Sucrose (Glucose + Fructose) โ reducing
Maltose (Glucose + Glucose) โ๏ธ reducing
Lactose (Glucose + Galactose) โ๏ธ reducing
โญ3๏ธโฃ Polysaccharides
โ๏ธ High molecular weight
โ๏ธ Non-sweet
๐ Examples:
Starch โ plant storage
Glycogen โ animal storage
Cellulose โ structural (
Reducing ๐ Non-Reducing Sugars
โ๏ธ Free aldehyde / ketone group โ Reducing
๐ Reducing: Glucose, Fructose, Maltose, Lactose
๐ Non-reducing: Sucrose
#ImportantNCERTConcepts
โญ D & L Configuration
Based on position of โOH on penultimate carbon
Glucose โ D-glucose
โญ Anomers
Differ at anomeric carbon (C-1 in glucose)
ฮฑ-glucose & ฮฒ-glucose
โญ Epimers
Differ at one carbon (except anomeric)
Glucose & Galactose (C-4)
โญ Glycosidic Bond
Link between two monosaccharides
In sucrose โ ฮฑ-1,ฮฒ-2
#RemeberGuys
Tollenโs / Fehlingโs โ reducing sugars
Iodine test โ starch (blue-black)
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅ2๐ฅฐ2๐1
#PROTEINS
โญ Definition
Polymers of ฮฑ-amino acids joined by peptide bonds
๐ Peptide bond: โCOโNHโ
โญ Amino Acids
๐ General formula:
NHโโCH(R)โCOOH
โ๏ธ Zwitterion in aqueous solution
โ๏ธ 20 standard amino acids
#Classificationof AminoAcids
โญ Based on Nutrition
Essential โ Diet required
Non-essential โ Synthesised in body
โญBased on Charge
Acidic: Aspartic, Glutamic
Basic: Lysine, Arginine
Neutral: Glycine, Alanine
#ProteinStructureLevels
โญ 1๏ธโฃ Primary
โ๏ธ Sequence of amino acids
โ๏ธ Most specific
โญ 2๏ธโฃ Secondary
โ๏ธ ฮฑ-helix
โ๏ธ ฮฒ-pleated sheet
๐ Stabilised by H-bonds
โญ 3๏ธโฃ Tertiary
โ๏ธ 3D folding
โ๏ธ Stabilised by:
Disulfide bonds
Ionic bonds
H-bonds
โญ 4๏ธโฃ Quaternary
โ๏ธ More than one polypeptide chain
๐ Example: Haemoglobin
#TypesofProteins
โญFibrous โ Structural (Keratin, Collagen)
โญGlobular โ Functional (Enzymes)
โญDenaturation
โ๏ธ Loss of biological activity
โ Primary structure unchanged
๐ Causes:
Heat
pH change
๐ Example:
Boiled egg white
#NEETHOTPOINTS
โ๏ธ Disulfide bond โ Cysteine
โ๏ธ Enzymes โ globular proteins
โ๏ธ Sucrose โ non-reducing
โ๏ธ Cellulose โ ฮฒ-glucose polymer
@Ayano1me @Neetugpoll @Neetugquiz
โญ Definition
Polymers of ฮฑ-amino acids joined by peptide bonds
๐ Peptide bond: โCOโNHโ
โญ Amino Acids
๐ General formula:
NHโโCH(R)โCOOH
โ๏ธ Zwitterion in aqueous solution
โ๏ธ 20 standard amino acids
#Classificationof AminoAcids
โญ Based on Nutrition
Essential โ Diet required
Non-essential โ Synthesised in body
โญBased on Charge
Acidic: Aspartic, Glutamic
Basic: Lysine, Arginine
Neutral: Glycine, Alanine
#ProteinStructureLevels
โญ 1๏ธโฃ Primary
โ๏ธ Sequence of amino acids
โ๏ธ Most specific
โญ 2๏ธโฃ Secondary
โ๏ธ ฮฑ-helix
โ๏ธ ฮฒ-pleated sheet
๐ Stabilised by H-bonds
โญ 3๏ธโฃ Tertiary
โ๏ธ 3D folding
โ๏ธ Stabilised by:
Disulfide bonds
Ionic bonds
H-bonds
โญ 4๏ธโฃ Quaternary
โ๏ธ More than one polypeptide chain
๐ Example: Haemoglobin
#TypesofProteins
โญFibrous โ Structural (Keratin, Collagen)
โญGlobular โ Functional (Enzymes)
โญDenaturation
โ๏ธ Loss of biological activity
โ Primary structure unchanged
๐ Causes:
Heat
pH change
๐ Example:
Boiled egg white
#NEETHOTPOINTS
โ๏ธ Disulfide bond โ Cysteine
โ๏ธ Enzymes โ globular proteins
โ๏ธ Sucrose โ non-reducing
โ๏ธ Cellulose โ ฮฒ-glucose polymer
@Ayano1me @Neetugpoll @Neetugquiz
๐3๐ฏ1
๐ง๐ข๐ฃ ๐ฎ๐ฌ ๐๐๐๐ ๐ช๐๐๐๐๐ง๐๐๐ ๐ง๐ข๐ฃ๐๐๐ฆ โ ๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ
โญ #๐ฃ๐๐ฌ๐ฆ๐๐๐๐๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ญ: ๐ฆ๐ข๐๐จ๐ง๐๐ข๐ก
โญ ๐๐๐๐๐ ๐ฆ๐ข๐๐จ๐ง๐๐ข๐ก
โญ ๐๐ข๐๐๐๐๐๐ง๐๐ฉ๐ ๐ฃ๐ฅ๐ข๐ฃ๐๐ฅ๐ง๐๐๐ฆ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ฎ๐๐๐๐๐ง๐ฅ๐ข๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ
โญ ๐ก๐๐ฅ๐ก๐ฆ๐ง ๐๐ค๐จ๐๐ง๐๐ข๐ก
โญ ๐๐ข๐ก๐๐จ๐๐ง๐๐ฉ๐๐ง๐ฌ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ฏ: ๐๐๐๐ ๐๐๐๐ ๐๐๐ก๐๐ง๐๐๐ฆ
โญ ๐๐๐ฅ๐ฆ๐ง ๐ข๐ฅ๐๐๐ฅ ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ
โญ ๐๐ฅ๐ฅ๐๐๐ก๐๐จ๐ฆ ๐๐ค๐จ๐๐ง๐๐ข๐ก
โญ #๐๐ก๐ข๐ฅ๐๐๐ก๐๐ ๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ฐ: ๐ & ๐ ๐๐๐ข๐๐ ๐๐๐๐ ๐๐ก๐ง๐ฆ
โญ ๐ฃ๐๐ฌ๐ฆ๐๐๐๐ ๐ฃ๐ฅ๐ข๐ฃ๐๐ฅ๐ง๐๐๐ฆ & ๐ฅ๐๐๐ฆ๐ข๐ก๐๐ก๐
โญ ๐๐๐ก๐ง๐๐๐ก๐ข๐๐ ๐๐ข๐ก๐ง๐ฅ๐๐๐ง๐๐ข๐ก
๐๐๐๐ฃ๐ง๐๐ฅ ๐ฑ: ๐๐ข๐ข๐ฅ๐๐๐ก๐๐ง๐๐ข๐ก ๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ
โญ ๐ฉ๐๐๐๐ก๐๐ ๐๐ข๐ก๐ ๐ง๐๐๐ข๐ฅ๐ฌ (๐ฉ๐๐ง)
โญ ๐๐ฆ๐ข๐ ๐๐ฅ๐๐ฆ๐
โญ #๐ข๐ฅ๐๐๐ก๐๐ ๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ฒ: ๐๐๐๐ข๐๐๐๐๐ก๐๐ฆ & ๐๐๐๐ข๐๐ฅ๐๐ก๐๐ฆ
โญ ๐ฆ๐ก๐ญ & ๐ฆ๐ก๐ฎ ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ
โญ ๐ฃ๐ฅ๐๐ฃ๐๐ฅ๐๐ง๐๐ข๐ก ๐ข๐ ๐๐๐๐ข๐๐๐๐๐ก๐๐ฆ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ณ: ๐๐๐๐ข๐๐ข๐๐ฆ, ๐ฃ๐๐๐ก๐ข๐๐ฆ & ๐๐ง๐๐๐ฅ๐ฆ
โญ ๐ฃ๐ฅ๐๐ฃ๐๐ฅ๐๐ง๐๐ข๐ก ๐ข๐ ๐๐๐๐ข๐๐ข๐๐ฆ
โญ ๐ช๐๐๐๐๐๐ ๐ฆ๐ข๐ก ๐๐ง๐๐๐ฅ ๐ฆ๐ฌ๐ก๐ง๐๐๐ฆ๐๐ฆ
๐๐ ๐ฅ๐๐๐๐ง๐๐ข๐ก
๐๐๐๐ฃ๐ง๐๐ฅ ๐ด: ๐๐๐๐๐๐ฌ๐๐๐ฆ, ๐๐๐ง๐ข๐ก๐๐ฆ & ๐๐๐ฅ๐๐ข๐ซ๐ฌ๐๐๐ ๐๐๐๐๐ฆ
โญ ๐ก๐๐ ๐ ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ / ๐ง๐๐ฆ๐ง๐ฆ
โญ ๐ก๐จ๐๐๐๐ข๐ฃ๐๐๐๐๐ ๐๐๐๐๐ง๐๐ข๐ก ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ต: ๐๐ ๐๐ก๐๐ฆ
โญ ๐ก๐๐ ๐ ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ / ๐ง๐๐ฆ๐ง๐ฆ
โญ ๐๐๐ฆ๐๐ ๐ก๐๐ง๐จ๐ฅ๐ ๐ข๐ ๐๐ ๐๐ก๐๐ฆ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ญ๐ฌ: ๐๐๐ข๐ ๐ข๐๐๐๐จ๐๐๐ฆ
โญ ๐๐๐ฅ๐๐ข๐๐ฌ๐๐ฅ๐๐ง๐๐ฆ
โญ ๐ฃ๐ฅ๐ข๐ง๐๐๐ก๐ฆ
@Ayano1me @Neetugpoll @Neetugquiz
โญ #๐ฃ๐๐ฌ๐ฆ๐๐๐๐๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ญ: ๐ฆ๐ข๐๐จ๐ง๐๐ข๐ก
โญ ๐๐๐๐๐ ๐ฆ๐ข๐๐จ๐ง๐๐ข๐ก
โญ ๐๐ข๐๐๐๐๐๐ง๐๐ฉ๐ ๐ฃ๐ฅ๐ข๐ฃ๐๐ฅ๐ง๐๐๐ฆ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ฎ๐๐๐๐๐ง๐ฅ๐ข๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ
โญ ๐ก๐๐ฅ๐ก๐ฆ๐ง ๐๐ค๐จ๐๐ง๐๐ข๐ก
โญ ๐๐ข๐ก๐๐จ๐๐ง๐๐ฉ๐๐ง๐ฌ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ฏ: ๐๐๐๐ ๐๐๐๐ ๐๐๐ก๐๐ง๐๐๐ฆ
โญ ๐๐๐ฅ๐ฆ๐ง ๐ข๐ฅ๐๐๐ฅ ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ
โญ ๐๐ฅ๐ฅ๐๐๐ก๐๐จ๐ฆ ๐๐ค๐จ๐๐ง๐๐ข๐ก
โญ #๐๐ก๐ข๐ฅ๐๐๐ก๐๐ ๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ฐ: ๐ & ๐ ๐๐๐ข๐๐ ๐๐๐๐ ๐๐ก๐ง๐ฆ
โญ ๐ฃ๐๐ฌ๐ฆ๐๐๐๐ ๐ฃ๐ฅ๐ข๐ฃ๐๐ฅ๐ง๐๐๐ฆ & ๐ฅ๐๐๐ฆ๐ข๐ก๐๐ก๐
โญ ๐๐๐ก๐ง๐๐๐ก๐ข๐๐ ๐๐ข๐ก๐ง๐ฅ๐๐๐ง๐๐ข๐ก
๐๐๐๐ฃ๐ง๐๐ฅ ๐ฑ: ๐๐ข๐ข๐ฅ๐๐๐ก๐๐ง๐๐ข๐ก ๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ
โญ ๐ฉ๐๐๐๐ก๐๐ ๐๐ข๐ก๐ ๐ง๐๐๐ข๐ฅ๐ฌ (๐ฉ๐๐ง)
โญ ๐๐ฆ๐ข๐ ๐๐ฅ๐๐ฆ๐
โญ #๐ข๐ฅ๐๐๐ก๐๐ ๐๐๐๐ ๐๐ฆ๐ง๐ฅ๐ฌ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ฒ: ๐๐๐๐ข๐๐๐๐๐ก๐๐ฆ & ๐๐๐๐ข๐๐ฅ๐๐ก๐๐ฆ
โญ ๐ฆ๐ก๐ญ & ๐ฆ๐ก๐ฎ ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ
โญ ๐ฃ๐ฅ๐๐ฃ๐๐ฅ๐๐ง๐๐ข๐ก ๐ข๐ ๐๐๐๐ข๐๐๐๐๐ก๐๐ฆ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ณ: ๐๐๐๐ข๐๐ข๐๐ฆ, ๐ฃ๐๐๐ก๐ข๐๐ฆ & ๐๐ง๐๐๐ฅ๐ฆ
โญ ๐ฃ๐ฅ๐๐ฃ๐๐ฅ๐๐ง๐๐ข๐ก ๐ข๐ ๐๐๐๐ข๐๐ข๐๐ฆ
โญ ๐ช๐๐๐๐๐๐ ๐ฆ๐ข๐ก ๐๐ง๐๐๐ฅ ๐ฆ๐ฌ๐ก๐ง๐๐๐ฆ๐๐ฆ
๐๐ ๐ฅ๐๐๐๐ง๐๐ข๐ก
๐๐๐๐ฃ๐ง๐๐ฅ ๐ด: ๐๐๐๐๐๐ฌ๐๐๐ฆ, ๐๐๐ง๐ข๐ก๐๐ฆ & ๐๐๐ฅ๐๐ข๐ซ๐ฌ๐๐๐ ๐๐๐๐๐ฆ
โญ ๐ก๐๐ ๐ ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ / ๐ง๐๐ฆ๐ง๐ฆ
โญ ๐ก๐จ๐๐๐๐ข๐ฃ๐๐๐๐๐ ๐๐๐๐๐ง๐๐ข๐ก ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ต: ๐๐ ๐๐ก๐๐ฆ
โญ ๐ก๐๐ ๐ ๐ฅ๐๐๐๐ง๐๐ข๐ก๐ฆ / ๐ง๐๐ฆ๐ง๐ฆ
โญ ๐๐๐ฆ๐๐ ๐ก๐๐ง๐จ๐ฅ๐ ๐ข๐ ๐๐ ๐๐ก๐๐ฆ
๐๐๐๐ฃ๐ง๐๐ฅ ๐ญ๐ฌ: ๐๐๐ข๐ ๐ข๐๐๐๐จ๐๐๐ฆ
โญ ๐๐๐ฅ๐๐ข๐๐ฌ๐๐ฅ๐๐ง๐๐ฆ
โญ ๐ฃ๐ฅ๐ข๐ง๐๐๐ก๐ฆ
@Ayano1me @Neetugpoll @Neetugquiz
โค5โคโ๐ฅ2๐ฏ2๐ฅฐ1๐1
#Day 1
#MOLECONCEPTALLIMPORTANTFORMULAE (NEET)
#BasicRelations
โญNumber of moles (n) = mass (m) / molar mass (M)
โญMass (m) = number of moles (n) ร molar mass (M)
โญNumber of particles (N) = n ร NA
โญNumber of moles (n) = N / NA
โญAvogadro number (NA) = 6.022 ร 10^23
#Gases
โญNumber of moles at STP (n) = volume (V in litres) / 22.4
โญIdeal gas equation
P ร V = n ร R ร T
โญDensity of gas (d) = (P ร M) / (R ร T)
โญMolar mass of gas (M) = (d ร R ร T) / P
#Solutions
โญMolarity (M) = number of moles of solute / volume of solution (in litre)
โญMolality (m) = number of moles of solute / mass of solvent (in kg)
โญNormality (N) = number of equivalents / volume of solution (in litre)
โญStrength of solution (g/L) = molarity ร molar mass
โญDilution Formula
M1 ร V1 = M2 ร V2
โญEquivalent Concept
Equivalent mass = molar mass / n-factor
โญNumber of equivalents = mass / equivalent mass
โญMole Fraction
Mole fraction of A (XA) = moles of A / (moles of A + moles of B)
XA + XB = 1
โญLimitingReagent
Required moles = given moles / stoichiometric coefficient
The reactant with least required moles is the limiting reagent
Percentage Composition
โญPercentage of element = (mass of element / molar mass of compound) ร 100
โญEmpirical and Molecular Formula
Empirical formula mass = sum of atomic masses in empirical formula
n = molecular mass / empirical formula mass
โญMolecular formula = empirical formula ร n
โญGas Mixture (Daltonโs Law)
Total pressure = P1 + P2 + P3 + โฆ
โญPartial pressure of gas A
PA = XA ร Ptotal
Redox Reactions
โญNormality ร Volume = constant
N1 ร V1 = N2 ร V2
n-factor = number of electrons lost or gained
#ImportantConstants
STP = 273 K and 1 atm
Gas constant
R = 0.0821 L atm molโปยน Kโปยน
R = 8.314 J molโปยน Kโปยน
#MOLECONCEPTALLIMPORTANTFORMULAE (NEET)
#BasicRelations
โญNumber of moles (n) = mass (m) / molar mass (M)
โญMass (m) = number of moles (n) ร molar mass (M)
โญNumber of particles (N) = n ร NA
โญNumber of moles (n) = N / NA
โญAvogadro number (NA) = 6.022 ร 10^23
#Gases
โญNumber of moles at STP (n) = volume (V in litres) / 22.4
โญIdeal gas equation
P ร V = n ร R ร T
โญDensity of gas (d) = (P ร M) / (R ร T)
โญMolar mass of gas (M) = (d ร R ร T) / P
#Solutions
โญMolarity (M) = number of moles of solute / volume of solution (in litre)
โญMolality (m) = number of moles of solute / mass of solvent (in kg)
โญNormality (N) = number of equivalents / volume of solution (in litre)
โญStrength of solution (g/L) = molarity ร molar mass
โญDilution Formula
M1 ร V1 = M2 ร V2
โญEquivalent Concept
Equivalent mass = molar mass / n-factor
โญNumber of equivalents = mass / equivalent mass
โญMole Fraction
Mole fraction of A (XA) = moles of A / (moles of A + moles of B)
XA + XB = 1
โญLimitingReagent
Required moles = given moles / stoichiometric coefficient
The reactant with least required moles is the limiting reagent
Percentage Composition
โญPercentage of element = (mass of element / molar mass of compound) ร 100
โญEmpirical and Molecular Formula
Empirical formula mass = sum of atomic masses in empirical formula
n = molecular mass / empirical formula mass
โญMolecular formula = empirical formula ร n
โญGas Mixture (Daltonโs Law)
Total pressure = P1 + P2 + P3 + โฆ
โญPartial pressure of gas A
PA = XA ร Ptotal
Redox Reactions
โญNormality ร Volume = constant
N1 ร V1 = N2 ร V2
n-factor = number of electrons lost or gained
#ImportantConstants
STP = 273 K and 1 atm
Gas constant
R = 0.0821 L atm molโปยน Kโปยน
R = 8.314 J molโปยน Kโปยน
โคโ๐ฅ6
#SIGNIFICANTFIGURES
๐ฑ Definition
Digits which convey certainty + one uncertain digit
โญ Rules to Count Significant Figures
โ๏ธ All non-zero digits โ significant
โ๏ธ Zeros between non-zero โ significant
โ๏ธ Leading zeros โ โ not significant
โ๏ธ Trailing zeros โ significant only with decimal
๐ Examples:
0.0045 โ 2 SF
2.300 โ 4 SF
1500 โ 2 SF (without decimal)
โโ Addition / Subtraction
Result โ least decimal places
๐ Example:
12.11 + 0.2 = 12.3
โ๏ธโ Multiplication / Division
Result โ least significant figures
๐ Example:
2.5 ร 1.23 = 3.1 (2 SF)
๐ข Rounding Off Rules
Next digit < 5 โ same
Next digit โฅ 5 โ +1
๐ 2.34 โ 2.3
๐ 2.36 โ 2.4
#NEETHOTPOINTS
โ๏ธ Exact numbers โ infinite SF
โ๏ธ Unit conversion โ SF maintained
โ๏ธ Final answer rounding last step
@Ayano1me @Neetugpoll @Neetugquiz
๐ฑ Definition
Digits which convey certainty + one uncertain digit
โญ Rules to Count Significant Figures
โ๏ธ All non-zero digits โ significant
โ๏ธ Zeros between non-zero โ significant
โ๏ธ Leading zeros โ โ not significant
โ๏ธ Trailing zeros โ significant only with decimal
๐ Examples:
0.0045 โ 2 SF
2.300 โ 4 SF
1500 โ 2 SF (without decimal)
โโ Addition / Subtraction
Result โ least decimal places
๐ Example:
12.11 + 0.2 = 12.3
โ๏ธโ Multiplication / Division
Result โ least significant figures
๐ Example:
2.5 ร 1.23 = 3.1 (2 SF)
๐ข Rounding Off Rules
Next digit < 5 โ same
Next digit โฅ 5 โ +1
๐ 2.34 โ 2.3
๐ 2.36 โ 2.4
#NEETHOTPOINTS
โ๏ธ Exact numbers โ infinite SF
โ๏ธ Unit conversion โ SF maintained
โ๏ธ Final answer rounding last step
@Ayano1me @Neetugpoll @Neetugquiz
โค6๐2