Q1. (AssertionโReason type)
Assertion (A): Atomic radius generally decreases from left to right in a period.
Reason (R): Nuclear charge increases while number of shells remains same.
Options:
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q2.
Which element has maximum electronegativity?
(1) Oxygen
(2) Nitrogen
(3) Fluorine
(4) Chlorine
Question:3 Which of the following has largest atomic size?
(1) Na
(2) Mg
(3) Al
(4) Si
Question 4
Assertion (A): Ionization enthalpy generally increases from left to right in a period.
Reason (R): Atomic size decreases and nuclear charge increases across a period.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Question:5
Assertion (A): Electron affinity of halogens is high.
Reason (R): Halogens have one electron less than noble gas configuration.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Question:6
Assertion (A): Metallic character increases down a group.
Reason (R): Atomic size increases and ionization enthalpy decreases down the group.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
๐ฅ3๐ฅฐ3๐คฉ1
1๏ธโฃ #DUALBEHAVIOUROFMATTER โญ
โ๏ธ Matter shows dual nature:
๐ Particle nature
๐ Wave nature
โ๏ธ This concept proved that classical physics fails at atomic scale
NEET point:
โ๏ธ Dual behaviour mainly observed for microscopic particles (electron, proton)
2๏ธโฃ #PARTICLENATUREOFMATTER โญ
โ๏ธ Matter consists of discrete particles
โ๏ธ Particle nature supported by:
๐ Photoelectric effect
๐ Compton effect
๐ Evidence:
โ๏ธ Emission of electrons only when threshold frequency is reached
3๏ธโฃ #WAVENATUREOFMATTER โญ
โ๏ธ Proposed by de Broglie
โ๏ธ Every moving particle behaves like a wave
๐ de Broglie hypothesis:
โ๏ธ ฮป โ 1/p
๐ de Broglie wavelength:
โ๏ธ ฮป = h / mv
Where:
โ๏ธ h = Planckโs constant
โ๏ธ m = mass
โ๏ธ v = velocity
NEET point:
โ๏ธ Wave nature important for electrons
4๏ธโฃ #ELECTROMAGNETICRADIATION โญ
โ๏ธ Energy travels as waves
โ๏ธ Does not require medium
๐ Examples:
โ๏ธ Radio waves
โ๏ธ Microwaves
โ๏ธ Infrared
โ๏ธ Visible light
โ๏ธ UV, X-rays, ฮณ-rays
๐ Relation:
โ๏ธ c = ฮฝฮป
5๏ธโฃ #PHOTOELECTRICEFFECT โก โญ
โ๏ธ Emission of electrons when light falls on metal surface
๐ Key observations:
โ๏ธ Threshold frequency (ฮฝโ) exists
โ๏ธ No emission below ฮฝโ
โ๏ธ Intensity โ โ number of electrons โ
โ๏ธ Frequency โ โ kinetic energy โ
๐ Einsteinโs photoelectric equation:
โ๏ธ hฮฝ = hฮฝโ + ยฝmvยฒ
NEET trap
โ๏ธ KE depends on frequency, NOT intensity
6๏ธโฃ #WAVEPARTICLEDUALITY โญ
โ๏ธ Light behaves as:
๐ Wave โ interference, diffraction
๐ Particle โ photoelectric effect
โ๏ธ Matter behaves as:
๐ Particle โ mass, momentum
๐ Wave โ de Broglie wavelength
NEET clarity:
โ๏ธ Dual behaviour is complementary, not simultaneous
7๏ธโฃ #IMPORTANCEOFDEBROGLIEWAVE โญ
โ๏ธ Basis of Bohrโs model modification
โ๏ธ Explains stability of orbits
โ๏ธ Used in electron microscope
๐ Special cases:
โ๏ธ For electron (accelerated by V):
ฮป = h / โ(2meV)
8๏ธโฃ #NEETONELINERS
โ๏ธ Dual nature โ matter + radiation
โ๏ธ Threshold frequency โ metal dependent
โ๏ธ de Broglie wavelength inversely โ velocity
โ๏ธ Electron shows wave nature more clearly
9๏ธโฃ #FORMULASUMMARY (MUST REVISE )
โ๏ธ ฮป = h / mv
โ๏ธ c = ฮฝฮป
โ๏ธ E = hฮฝ
โ๏ธ hฮฝ = hฮฝโ + ยฝmvยฒ
โ๏ธ ฮป = h / โ(2meV)
๐ #REAL_SENSESUMMARY โญ
โ๏ธ Classical physics โ at atomic scale
โ๏ธ Quantum ideas โ๏ธ required
โ๏ธ Wave nature dominates for small particles
โ๏ธ Foundation of modern chemistry & physics
@Ayano1me @Neetugpoll @Neetugquiz
โ๏ธ Matter shows dual nature:
๐ Particle nature
๐ Wave nature
โ๏ธ This concept proved that classical physics fails at atomic scale
NEET point:
โ๏ธ Dual behaviour mainly observed for microscopic particles (electron, proton)
2๏ธโฃ #PARTICLENATUREOFMATTER โญ
โ๏ธ Matter consists of discrete particles
โ๏ธ Particle nature supported by:
๐ Photoelectric effect
๐ Compton effect
๐ Evidence:
โ๏ธ Emission of electrons only when threshold frequency is reached
3๏ธโฃ #WAVENATUREOFMATTER โญ
โ๏ธ Proposed by de Broglie
โ๏ธ Every moving particle behaves like a wave
๐ de Broglie hypothesis:
โ๏ธ ฮป โ 1/p
๐ de Broglie wavelength:
โ๏ธ ฮป = h / mv
Where:
โ๏ธ h = Planckโs constant
โ๏ธ m = mass
โ๏ธ v = velocity
NEET point:
โ๏ธ Wave nature important for electrons
4๏ธโฃ #ELECTROMAGNETICRADIATION โญ
โ๏ธ Energy travels as waves
โ๏ธ Does not require medium
๐ Examples:
โ๏ธ Radio waves
โ๏ธ Microwaves
โ๏ธ Infrared
โ๏ธ Visible light
โ๏ธ UV, X-rays, ฮณ-rays
๐ Relation:
โ๏ธ c = ฮฝฮป
5๏ธโฃ #PHOTOELECTRICEFFECT โก โญ
โ๏ธ Emission of electrons when light falls on metal surface
๐ Key observations:
โ๏ธ Threshold frequency (ฮฝโ) exists
โ๏ธ No emission below ฮฝโ
โ๏ธ Intensity โ โ number of electrons โ
โ๏ธ Frequency โ โ kinetic energy โ
๐ Einsteinโs photoelectric equation:
โ๏ธ hฮฝ = hฮฝโ + ยฝmvยฒ
NEET trap
โ๏ธ KE depends on frequency, NOT intensity
6๏ธโฃ #WAVEPARTICLEDUALITY โญ
โ๏ธ Light behaves as:
๐ Wave โ interference, diffraction
๐ Particle โ photoelectric effect
โ๏ธ Matter behaves as:
๐ Particle โ mass, momentum
๐ Wave โ de Broglie wavelength
NEET clarity:
โ๏ธ Dual behaviour is complementary, not simultaneous
7๏ธโฃ #IMPORTANCEOFDEBROGLIEWAVE โญ
โ๏ธ Basis of Bohrโs model modification
โ๏ธ Explains stability of orbits
โ๏ธ Used in electron microscope
๐ Special cases:
โ๏ธ For electron (accelerated by V):
ฮป = h / โ(2meV)
8๏ธโฃ #NEETONELINERS
โ๏ธ Dual nature โ matter + radiation
โ๏ธ Threshold frequency โ metal dependent
โ๏ธ de Broglie wavelength inversely โ velocity
โ๏ธ Electron shows wave nature more clearly
9๏ธโฃ #FORMULASUMMARY (MUST REVISE )
โ๏ธ ฮป = h / mv
โ๏ธ c = ฮฝฮป
โ๏ธ E = hฮฝ
โ๏ธ hฮฝ = hฮฝโ + ยฝmvยฒ
โ๏ธ ฮป = h / โ(2meV)
๐ #REAL_SENSESUMMARY โญ
โ๏ธ Classical physics โ at atomic scale
โ๏ธ Quantum ideas โ๏ธ required
โ๏ธ Wave nature dominates for small particles
โ๏ธ Foundation of modern chemistry & physics
@Ayano1me @Neetugpoll @Neetugquiz
โค3๐ฅฐ2๐2๐2
1๏ธโฃ #DIPOLEMOMENT
๐ Measure of polarity of a bond or molecule
2๏ธโฃ #DEFINITION
โ๏ธ Product of magnitude of charge (q) and distance (d) between centres of +ve and โve charges
โ๏ธ ฮผ = q ร d
โ๏ธ Vector quantity
โ๏ธ Direction โ from negative to positive charge
3๏ธโฃ #UNITS
โ๏ธ SI unit โ Coulomb metre (Cยทm)
โ๏ธ Practical unit โ Debye (D)
๐ 1 Debye = 3.336 ร 10โปยณโฐ Cยทm
4๏ธโฃ #BONDDIPOLEMOMENT
โ๏ธ Due to electronegativity difference
โ๏ธ Greater ฮEN โ greater dipole moment
๐ HโCl > HโBr > HโI
5๏ธโฃ #MOLECULARDIPOLEMOMENT
โ๏ธ Vector sum of all bond dipoles
โ๏ธ Depends on molecular shape & symmetry
6๏ธโฃ #EFFECTOFSHAPE
โ๏ธ Symmetrical molecule โ ฮผ = 0
โ๏ธ Unsymmetrical molecule โ ฮผ โ 0
๐ Examples:
โ๏ธ COโ โ ฮผ = 0 (linear)
โ๏ธ BFโ โ ฮผ = 0 (trigonal planar)
โ๏ธ HโO โ ฮผ โ 0 (bent)
โ๏ธ NHโ โ ฮผ โ 0 (pyramidal)
7๏ธโฃ #APPLICATIONS
โ๏ธ Polarity determination
โ๏ธ Molecular geometry
โ๏ธ Ionic character
โ๏ธ Distinguishing cisโtrans isomers
๐ cis โ ฮผ โ 0
๐ trans โ ฮผ = 0
8๏ธโฃ #IMPORTANTNCERTPOINTS
โ๏ธ Lone pair increases dipole moment
โ๏ธ Symmetry can cancel dipole moment
โ๏ธ Polar bonds may give zero ฮผ
9๏ธโฃ #NEETTRAPS
โ Polar bond โ polar molecule
โ Zero ฮผ โ non-polar bonds
โ Shape ignored = wrong answer
HF>HCL but ch3cl>ch3F ( DM)
@Ayano1me @Neetugpoll @Neetugquiz
๐ Measure of polarity of a bond or molecule
2๏ธโฃ #DEFINITION
โ๏ธ Product of magnitude of charge (q) and distance (d) between centres of +ve and โve charges
โ๏ธ ฮผ = q ร d
โ๏ธ Vector quantity
โ๏ธ Direction โ from negative to positive charge
3๏ธโฃ #UNITS
โ๏ธ SI unit โ Coulomb metre (Cยทm)
โ๏ธ Practical unit โ Debye (D)
๐ 1 Debye = 3.336 ร 10โปยณโฐ Cยทm
4๏ธโฃ #BONDDIPOLEMOMENT
โ๏ธ Due to electronegativity difference
โ๏ธ Greater ฮEN โ greater dipole moment
๐ HโCl > HโBr > HโI
5๏ธโฃ #MOLECULARDIPOLEMOMENT
โ๏ธ Vector sum of all bond dipoles
โ๏ธ Depends on molecular shape & symmetry
6๏ธโฃ #EFFECTOFSHAPE
โ๏ธ Symmetrical molecule โ ฮผ = 0
โ๏ธ Unsymmetrical molecule โ ฮผ โ 0
๐ Examples:
โ๏ธ COโ โ ฮผ = 0 (linear)
โ๏ธ BFโ โ ฮผ = 0 (trigonal planar)
โ๏ธ HโO โ ฮผ โ 0 (bent)
โ๏ธ NHโ โ ฮผ โ 0 (pyramidal)
7๏ธโฃ #APPLICATIONS
โ๏ธ Polarity determination
โ๏ธ Molecular geometry
โ๏ธ Ionic character
โ๏ธ Distinguishing cisโtrans isomers
๐ cis โ ฮผ โ 0
๐ trans โ ฮผ = 0
8๏ธโฃ #IMPORTANTNCERTPOINTS
โ๏ธ Lone pair increases dipole moment
โ๏ธ Symmetry can cancel dipole moment
โ๏ธ Polar bonds may give zero ฮผ
9๏ธโฃ #NEETTRAPS
โ Polar bond โ polar molecule
โ Zero ฮผ โ non-polar bonds
โ Shape ignored = wrong answer
HF>HCL but ch3cl>ch3F ( DM)
@Ayano1me @Neetugpoll @Neetugquiz
๐2โค1๐1๐ฅ1๐1
Aaj 8 bje all book module ka link
โค3๐ฅ3๐2๐1
1๏ธโฃ #VSEPRTHEORY
๐ VSEPR = Valence Shell Electron Pair Repulsion theory
๐ Used to predict shape of molecules and ions.
2๏ธโฃ #BASICIDEA
โ๏ธ Electron pairs in valence shell repel each other
โ๏ธ They arrange themselves to minimise repulsion
โ๏ธ Shape depends on number of electron pairs around central atom
3๏ธโฃ #TYPESOFELECTRONPAIRS
โ๏ธ Bond pair (BP) โ shared electrons
โ๏ธ Lone pair (LP) โ unshared electrons
๐ Lone pair occupies more space than bond pair
4๏ธโฃ #ORDEROFREPULSION (VERY IMP ๐ฅ)
โ๏ธ LPโLP > LPโBP > BPโBP
๐ This order decides distortion in shape
5๏ธโฃ #ELECTRONGEOMETRYVS MOLECULARGEOMETRY
โ๏ธ Electron geometry โ arrangement of all electron pairs
โ๏ธ Molecular geometry โ arrangement of atoms only
๐ Lone pairs affect molecular shape, not electron geometry
6๏ธโฃ #IDEALGEOMETRIES (NO LONE PAIR)
โ๏ธ 2 BP โ Linear โ 180ยฐ โ BeClโ
โ๏ธ 3 BP โ Trigonal planar โ 120ยฐ โ BFโ
โ๏ธ 4 BP โ Tetrahedral โ 109.5ยฐ โ CHโ
โ๏ธ 5 BP โ Trigonal bipyramidal โ PClโ
โ๏ธ 6 BP โ Octahedral โ SFโ
7๏ธโฃ #EFFECTOFLONEPAIR
โ๏ธ Lone pair reduces bond angle
โ๏ธ More lone pairs โ more deviation from ideal shape
๐ Examples:
โ๏ธ CHโ โ 109.5ยฐ
โ๏ธ NHโ โ 107ยฐ
โ๏ธ HโO โ 104.5ยฐ
8๏ธโฃ #SPECIALCASESTRIGONALBIPYRAMIDAL
โ๏ธ Axial positions โ more repulsion
โ๏ธ Equatorial positions โ less repulsion
๐ Lone pair occupies equatorial position first
๐ Example:
โ๏ธ SFโ โ seesaw
โ๏ธ ClFโ โ T-shape
โ๏ธ XeFโ โ linear
9๏ธโฃ #SPECIALCASEOFOCTAHEDRAL
โ๏ธ One lone pair โ square pyramidal
โ๏ธ Two lone pairs โ square planar
๐ Examples:
โ๏ธ BrFโ โ square pyramidal
โ๏ธ XeFโ โ square planar
๐ #NEETIMPORTANTPOINTS ๐จ
โ๏ธ Lone pair causes maximum repulsion
โ๏ธ Shape decided by LP + BP count
โ๏ธ VSEPR explains shape, not bonding strength
โ๏ธ Used mainly for p-block compounds
1๏ธโฃ1๏ธโฃ #LIMITATIONSOFVSEPR
โ๏ธ Cannot explain bond length accurately
โ๏ธ Not applicable for transition metals
โ๏ธ Fails for odd-electron molecules
1๏ธโฃ2๏ธโฃ #ONELINEREVISION
Molecular shape is decided by repulsion between electron pairs around the central atom.
@Ayano1me @Neetugpoll @Neetugquiz
๐ VSEPR = Valence Shell Electron Pair Repulsion theory
๐ Used to predict shape of molecules and ions.
2๏ธโฃ #BASICIDEA
โ๏ธ Electron pairs in valence shell repel each other
โ๏ธ They arrange themselves to minimise repulsion
โ๏ธ Shape depends on number of electron pairs around central atom
3๏ธโฃ #TYPESOFELECTRONPAIRS
โ๏ธ Bond pair (BP) โ shared electrons
โ๏ธ Lone pair (LP) โ unshared electrons
๐ Lone pair occupies more space than bond pair
4๏ธโฃ #ORDEROFREPULSION (VERY IMP ๐ฅ)
โ๏ธ LPโLP > LPโBP > BPโBP
๐ This order decides distortion in shape
5๏ธโฃ #ELECTRONGEOMETRYVS MOLECULARGEOMETRY
โ๏ธ Electron geometry โ arrangement of all electron pairs
โ๏ธ Molecular geometry โ arrangement of atoms only
๐ Lone pairs affect molecular shape, not electron geometry
6๏ธโฃ #IDEALGEOMETRIES (NO LONE PAIR)
โ๏ธ 2 BP โ Linear โ 180ยฐ โ BeClโ
โ๏ธ 3 BP โ Trigonal planar โ 120ยฐ โ BFโ
โ๏ธ 4 BP โ Tetrahedral โ 109.5ยฐ โ CHโ
โ๏ธ 5 BP โ Trigonal bipyramidal โ PClโ
โ๏ธ 6 BP โ Octahedral โ SFโ
7๏ธโฃ #EFFECTOFLONEPAIR
โ๏ธ Lone pair reduces bond angle
โ๏ธ More lone pairs โ more deviation from ideal shape
๐ Examples:
โ๏ธ CHโ โ 109.5ยฐ
โ๏ธ NHโ โ 107ยฐ
โ๏ธ HโO โ 104.5ยฐ
8๏ธโฃ #SPECIALCASESTRIGONALBIPYRAMIDAL
โ๏ธ Axial positions โ more repulsion
โ๏ธ Equatorial positions โ less repulsion
๐ Lone pair occupies equatorial position first
๐ Example:
โ๏ธ SFโ โ seesaw
โ๏ธ ClFโ โ T-shape
โ๏ธ XeFโ โ linear
9๏ธโฃ #SPECIALCASEOFOCTAHEDRAL
โ๏ธ One lone pair โ square pyramidal
โ๏ธ Two lone pairs โ square planar
๐ Examples:
โ๏ธ BrFโ โ square pyramidal
โ๏ธ XeFโ โ square planar
๐ #NEETIMPORTANTPOINTS ๐จ
โ๏ธ Lone pair causes maximum repulsion
โ๏ธ Shape decided by LP + BP count
โ๏ธ VSEPR explains shape, not bonding strength
โ๏ธ Used mainly for p-block compounds
1๏ธโฃ1๏ธโฃ #LIMITATIONSOFVSEPR
โ๏ธ Cannot explain bond length accurately
โ๏ธ Not applicable for transition metals
โ๏ธ Fails for odd-electron molecules
1๏ธโฃ2๏ธโฃ #ONELINEREVISION
Molecular shape is decided by repulsion between electron pairs around the central atom.
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅ2๐2โค1๐1
โค2๐คฉ1๐ฏ1๐1
Chemistry booster series
https://t.me/+5VTfeOK6KxJkYWQ1
Old m Copyright aa gya ๐again upload krenge 3500+ video
Btw share krdo needy students ko baad m link na milegi
Btw share krdo needy students ko baad m link na milegi
๐ฏ4โค2๐1๐1
1๏ธโฃ #MOLECULARORBITALTHEORY
๐ Molecular Orbital Theory (MOT) explains bonding, bond order and magnetic nature of molecules.
๐ Proposed by Hund and Mulliken.
2๏ธโฃ #BASICIDEA
โ๏ธ Atomic orbitals of bonded atoms combine to form molecular orbitals
โ๏ธ Molecular orbitals belong to the entire molecule
โ๏ธ Number of MOs formed = number of AOs combined
3๏ธโฃ #CONDITIONSFORCOMBINATION
โ๏ธ Comparable energy of AOs
โ๏ธ Proper orientation
โ๏ธ Significant overlap
4๏ธโฃ #TYPESOFMOLECULARORBITALS
โ๏ธ Bonding MO
โ๏ธ Antibonding MO
โ๏ธ Non-bonding MO (rare in diatomic molecules)
5๏ธโฃ #BONDINGMO
โ๏ธ Formed by constructive overlap
โ๏ธ Lower energy than AOs
โ๏ธ Increases stability
๐ Denoted by: ฯ, ฯ
6๏ธโฃ #ANTIBONDINGMO
โ๏ธ Formed by destructive overlap
โ๏ธ Higher energy
โ๏ธ Decreases stability
๐ Denoted by: ฯ*, ฯ*
7๏ธโฃ #ELECTRONFILLINGRULES
โ๏ธ Aufbau principle
โ๏ธ Pauli exclusion principle
โ๏ธ Hundโs rule of maximum multiplicity
8๏ธโฃ #ENERGYORDEROFDIATOMICMOLECULES โญ
๐ For Bโ, Cโ, Nโ:
ฯ1s < ฯ1s < ฯ2s < ฯ2s < ฯ2p < ฯ2p < ฯ2p < ฯ2p
๐ For Oโ, Fโ, Neโ:
ฯ1s < ฯ1s < ฯ2s < ฯ2s < ฯ2p < ฯ2p < ฯ2p < ฯ2p
9๏ธโฃ #BONORDER (VERY IMP )
๐ Formula:
Bond order = (Nb โ Na) / 2
โ๏ธ Nb = bonding electrons
โ๏ธ Na = antibonding electrons
๐ Interpretation:
โ๏ธ Higher bond order โ stronger bond
โ๏ธ Bond order = 0 โ molecule does not exist
๐ #MAGNETICNATURE
โ๏ธ Unpaired electrons โ paramagnetic
โ๏ธ All electrons paired โ diamagnetic
๐ Example:
โ๏ธ Oโ โ paramagnetic
โ๏ธ Nโ โ diamagnetic
1๏ธโฃ1๏ธโฃ #IMPORTANTEXAMPLES (NEET ๐ฅ)
โ๏ธ Hโ โ bond order = 1
โ๏ธ Heโ โ bond order = 0 (does not exist)
โ๏ธ Oโโบ โ bond order increases
โ๏ธ Oโโป โ bond order decreases
1๏ธโฃ2๏ธโฃ #LIMITATIONSOFMOT
โ๏ธ Complex for polyatomic molecules
โ๏ธ Does not explain shape clearly
1๏ธโฃ3๏ธโฃ #NEETIMPORTANTPOINTS
โ๏ธ MOT explains paramagnetism of Oโ
โ๏ธ Energy order changes after Nโ
โ๏ธ Bond order decides stability
1๏ธโฃ4๏ธโฃ #ONELINEREVISION
Molecular Orbital Theory explains bonding by delocalised molecular orbitals and predicts bond order and magnetic nature
@Ayano1me @Neetugpoll @Neetugquiz
๐ Molecular Orbital Theory (MOT) explains bonding, bond order and magnetic nature of molecules.
๐ Proposed by Hund and Mulliken.
2๏ธโฃ #BASICIDEA
โ๏ธ Atomic orbitals of bonded atoms combine to form molecular orbitals
โ๏ธ Molecular orbitals belong to the entire molecule
โ๏ธ Number of MOs formed = number of AOs combined
3๏ธโฃ #CONDITIONSFORCOMBINATION
โ๏ธ Comparable energy of AOs
โ๏ธ Proper orientation
โ๏ธ Significant overlap
4๏ธโฃ #TYPESOFMOLECULARORBITALS
โ๏ธ Bonding MO
โ๏ธ Antibonding MO
โ๏ธ Non-bonding MO (rare in diatomic molecules)
5๏ธโฃ #BONDINGMO
โ๏ธ Formed by constructive overlap
โ๏ธ Lower energy than AOs
โ๏ธ Increases stability
๐ Denoted by: ฯ, ฯ
6๏ธโฃ #ANTIBONDINGMO
โ๏ธ Formed by destructive overlap
โ๏ธ Higher energy
โ๏ธ Decreases stability
๐ Denoted by: ฯ*, ฯ*
7๏ธโฃ #ELECTRONFILLINGRULES
โ๏ธ Aufbau principle
โ๏ธ Pauli exclusion principle
โ๏ธ Hundโs rule of maximum multiplicity
8๏ธโฃ #ENERGYORDEROFDIATOMICMOLECULES โญ
๐ For Bโ, Cโ, Nโ:
ฯ1s < ฯ1s < ฯ2s < ฯ2s < ฯ2p < ฯ2p < ฯ2p < ฯ2p
๐ For Oโ, Fโ, Neโ:
ฯ1s < ฯ1s < ฯ2s < ฯ2s < ฯ2p < ฯ2p < ฯ2p < ฯ2p
9๏ธโฃ #BONORDER (VERY IMP )
๐ Formula:
Bond order = (Nb โ Na) / 2
โ๏ธ Nb = bonding electrons
โ๏ธ Na = antibonding electrons
๐ Interpretation:
โ๏ธ Higher bond order โ stronger bond
โ๏ธ Bond order = 0 โ molecule does not exist
๐ #MAGNETICNATURE
โ๏ธ Unpaired electrons โ paramagnetic
โ๏ธ All electrons paired โ diamagnetic
๐ Example:
โ๏ธ Oโ โ paramagnetic
โ๏ธ Nโ โ diamagnetic
1๏ธโฃ1๏ธโฃ #IMPORTANTEXAMPLES (NEET ๐ฅ)
โ๏ธ Hโ โ bond order = 1
โ๏ธ Heโ โ bond order = 0 (does not exist)
โ๏ธ Oโโบ โ bond order increases
โ๏ธ Oโโป โ bond order decreases
1๏ธโฃ2๏ธโฃ #LIMITATIONSOFMOT
โ๏ธ Complex for polyatomic molecules
โ๏ธ Does not explain shape clearly
1๏ธโฃ3๏ธโฃ #NEETIMPORTANTPOINTS
โ๏ธ MOT explains paramagnetism of Oโ
โ๏ธ Energy order changes after Nโ
โ๏ธ Bond order decides stability
1๏ธโฃ4๏ธโฃ #ONELINEREVISION
Molecular Orbital Theory explains bonding by delocalised molecular orbitals and predicts bond order and magnetic nature
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅฐ2โค1๐ฏ1
1๏ธโฃ #VALENCEBONDTHEORY
๐ Valence Bond Theory (VBT) explains formation of covalent bonds by overlap of atomic orbitals.
๐ Proposed by Heitler and London.
2๏ธโฃ #BASICIDEA
โ๏ธ Atoms bond to achieve stable electronic configuration
โ๏ธ Half-filled atomic orbitals overlap
โ๏ธ Electrons pair with opposite spins
๐ Greater overlap โ stronger bond
3๏ธโฃ #CONDITIONSFOROVERLAP
โ๏ธ Half-filled orbitals
โ๏ธ Comparable energy of orbitals
โ๏ธ Proper orientation
4๏ธโฃ #TYPESOFOBOND
โ๏ธ Sigma (ฯ) bond
โ๏ธ Pi (ฯ) bond
5๏ธโฃ #SIGMABOND
โ๏ธ Formed by head-on overlap
โ๏ธ Stronger than ฯ bond
โ๏ธ Electron density along internuclear axis
๐ Overlap types:
โ๏ธ sโs
โ๏ธ sโp
โ๏ธ pโp
6๏ธโฃ #PIBOND
โ๏ธ Formed by sidewise overlap
โ๏ธ Weaker than ฯ bond
โ๏ธ Electron density above & below axis
๐ Formed by pโp overlap only
7๏ธโฃ #HYBRIDISATION
๐ Mixing of atomic orbitals of similar energy to form hybrid orbitals.
โ๏ธ Number of hybrid orbitals = number of AOs mixed
8๏ธโฃ #TYPESOFHYBRIDISATION
โ๏ธ sp โ linear โ 180ยฐ โ BeClโ
โ๏ธ spยฒ โ trigonal planar โ 120ยฐ โ BFโ
โ๏ธ spยณ โ tetrahedral โ 109.5ยฐ โ CHโ
โ๏ธ dspยฒ โ square planar โ [Ni(CN)โ]ยฒโป
โ๏ธ dยฒspยณ โ octahedral โ [Co(NHโ)โ]ยณโบ
9๏ธโฃ #VALENCEBONDTHEORYINCOORDINATIONCOMPOUNDS
โ๏ธ Central metal provides empty orbitals
โ๏ธ Ligands donate lone pair
โ๏ธ Coordinate bond formed by overlap
๐ #MAGNETICNATURE
โ๏ธ Unpaired electrons โ paramagnetic
โ๏ธ Paired electrons โ diamagnetic
๐ Example:
โ๏ธ [Ni(CN)โ]ยฒโป โ diamagnetic
โ๏ธ [NiClโ]ยฒโป โ paramagnetic
1๏ธโฃ1๏ธโฃ #LIMITATIONSOFVBT
โ๏ธ Cannot explain colour of compounds
โ๏ธ Cannot explain strong vs weak ligands clearly
โ๏ธ No quantitative explanation of spectra
1๏ธโฃ2๏ธโฃ #NEETIMPORTANTPOINTS
โ๏ธ ฯ bond is stronger than ฯ bond
โ๏ธ Multiple bonds = 1 ฯ + remaining ฯ
โ๏ธ Hybridisation explains geometry
1๏ธโฃ3๏ธโฃ #ONELINEREVISION
Valence Bond Theory explains bonding by orbital overlap and predicts bond type, strength and geometry.
@Ayano1me @Neetugpoll @Neetugquiz
๐ Valence Bond Theory (VBT) explains formation of covalent bonds by overlap of atomic orbitals.
๐ Proposed by Heitler and London.
2๏ธโฃ #BASICIDEA
โ๏ธ Atoms bond to achieve stable electronic configuration
โ๏ธ Half-filled atomic orbitals overlap
โ๏ธ Electrons pair with opposite spins
๐ Greater overlap โ stronger bond
3๏ธโฃ #CONDITIONSFOROVERLAP
โ๏ธ Half-filled orbitals
โ๏ธ Comparable energy of orbitals
โ๏ธ Proper orientation
4๏ธโฃ #TYPESOFOBOND
โ๏ธ Sigma (ฯ) bond
โ๏ธ Pi (ฯ) bond
5๏ธโฃ #SIGMABOND
โ๏ธ Formed by head-on overlap
โ๏ธ Stronger than ฯ bond
โ๏ธ Electron density along internuclear axis
๐ Overlap types:
โ๏ธ sโs
โ๏ธ sโp
โ๏ธ pโp
6๏ธโฃ #PIBOND
โ๏ธ Formed by sidewise overlap
โ๏ธ Weaker than ฯ bond
โ๏ธ Electron density above & below axis
๐ Formed by pโp overlap only
7๏ธโฃ #HYBRIDISATION
๐ Mixing of atomic orbitals of similar energy to form hybrid orbitals.
โ๏ธ Number of hybrid orbitals = number of AOs mixed
8๏ธโฃ #TYPESOFHYBRIDISATION
โ๏ธ sp โ linear โ 180ยฐ โ BeClโ
โ๏ธ spยฒ โ trigonal planar โ 120ยฐ โ BFโ
โ๏ธ spยณ โ tetrahedral โ 109.5ยฐ โ CHโ
โ๏ธ dspยฒ โ square planar โ [Ni(CN)โ]ยฒโป
โ๏ธ dยฒspยณ โ octahedral โ [Co(NHโ)โ]ยณโบ
9๏ธโฃ #VALENCEBONDTHEORYINCOORDINATIONCOMPOUNDS
โ๏ธ Central metal provides empty orbitals
โ๏ธ Ligands donate lone pair
โ๏ธ Coordinate bond formed by overlap
๐ #MAGNETICNATURE
โ๏ธ Unpaired electrons โ paramagnetic
โ๏ธ Paired electrons โ diamagnetic
๐ Example:
โ๏ธ [Ni(CN)โ]ยฒโป โ diamagnetic
โ๏ธ [NiClโ]ยฒโป โ paramagnetic
1๏ธโฃ1๏ธโฃ #LIMITATIONSOFVBT
โ๏ธ Cannot explain colour of compounds
โ๏ธ Cannot explain strong vs weak ligands clearly
โ๏ธ No quantitative explanation of spectra
1๏ธโฃ2๏ธโฃ #NEETIMPORTANTPOINTS
โ๏ธ ฯ bond is stronger than ฯ bond
โ๏ธ Multiple bonds = 1 ฯ + remaining ฯ
โ๏ธ Hybridisation explains geometry
1๏ธโฃ3๏ธโฃ #ONELINEREVISION
Valence Bond Theory explains bonding by orbital overlap and predicts bond type, strength and geometry.
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅ2๐1๐1
Q1.
Assertion (A): In Oโ molecule, two electrons remain unpaired in molecular orbitals.
Reason (R): The last electrons of Oโ occupy degenerate ฯ* antibonding orbitals according to Hundโs rule.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q2.
Assertion (A): Bond order of Nโ molecule is 3.
Reason (R): Nโ has more electrons in bonding molecular orbitals than in antibonding molecular orbitals.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q3.
Assertion (A): Heโ molecule does not exist.
Reason (R): Number of electrons in bonding and antibonding orbitals of Heโ are equal.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q1.
Assertion (A): According to VBT, a covalent bond is formed by overlap of half-filled atomic orbitals.
Reason (R): Overlap of orbitals increases electron density between two nuclei.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q2.
Assertion (A): A ฯ-bond is stronger than a ฯ-bond.
Reason (R): ฯ-bond is formed by head-on overlap whereas ฯ-bond is formed by sidewise overlap.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q3.
Assertion (A): Valence Bond Theory cannot explain paramagnetism of Oโ molecule.
Reason (R): VBT does not consider molecular orbitals and electron delocalisation.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
โค1๐1๐ณ1๐1
๐1๐ฅ1๐1๐ฏ1
1๏ธโฃ #KINETICTHEORYOFGASES
โ๏ธ Explains macroscopic properties of gases
โ๏ธ Based on molecular motion
โ๏ธ Applies mainly to ideal gases
2๏ธโฃ #BASICPOSTULATES
โ๏ธ Gas consists of very large number of molecules
โ๏ธ Molecules are point masses (negligible volume)
โ๏ธ Distance between molecules โซ molecular size
โ๏ธ Molecules move randomly in all directions
3๏ธโฃ #NATUREOFMOLECULARMOTION
โ๏ธ Continuous
โ๏ธ Random
โ๏ธ Straight-line motion between collisions
๐ Velocity constantly changes due to collisions
4๏ธโฃ #INTERMOLECULARFORCES
โ๏ธ Negligible attractive forces
โ๏ธ No repulsion except during collision
๐ Valid only for ideal gases
5๏ธโฃ #COLLISIONS (VERY IMP ๐ฅ)
โ๏ธ Collisions are perfectly elastic
โ๏ธ Occur between:
โช๏ธ Moleculeโmolecule
โช๏ธ Moleculeโwall
๐ No loss of kinetic energy
6๏ธโฃ #PRESSUREOFGAS
โ๏ธ Due to collision of gas molecules with container walls
โ๏ธ More collisions โ more pressure
๐ Pressure โ number of collisions
7๏ธโฃ #KINETICENERGY
โ๏ธ Average kinetic energy depends only on temperature
โ๏ธ Independent of pressure & volume
๐ Formula:
Average K.E. = (3/2) kT (per molecule)
Average K.E. = (3/2) RT (per mole)
8๏ธโฃ #TEMPERATURESIGNIFICANCE
โ๏ธ Measure of average kinetic energy
โ๏ธ At 0 K โ molecular motion stops (ideal case)
๐ Higher T โ higher molecular speed
9๏ธโฃ #SPEEDOFGASMOLECULES
โ๏ธ Three types:
โช๏ธ Most probable speed (vโ)
โช๏ธ Average speed (vโแตฅ)
โช๏ธ RMS speed (vแตฃโโ)
๐ Relation:
vโ < vโแตฅ < vแตฃโโ
๐ #SPEEDFORMULAE (NEET FAVORITE โค๏ธ)
โ๏ธ vโ = โ(2RT / M)
โ๏ธ vโแตฅ = โ(8RT / ฯM)
โ๏ธ vแตฃโโ = โ(3RT / M)
๐ M in kg molโปยน
1๏ธโฃ1๏ธโฃ #GRAHAMLAW (LINKED CONCEPT)
โ๏ธ Rate โ 1 / โM
โ๏ธ Lighter gas diffuses faster
1๏ธโฃ2๏ธโฃ #DEVIATIONFROMIDEALBEHAVIOUR
โ๏ธ Real gases deviate at:
โช๏ธ High pressure
โช๏ธ Low temperature
๐ Cause:
โ๏ธ Finite molecular volume
โ๏ธ Intermolecular attraction
1๏ธโฃ3๏ธโฃ #LIMITATIONSOFKTG
โ Cannot explain liquefaction
โ Fails at high pressure
โ Assumes zero molecular volume
1๏ธโฃ4๏ธโฃ #NEETONELINERS
โ๏ธ Pressure independent of mass of gas
โ๏ธ KE โ absolute temperature
โ๏ธ Elastic collision = KE conserved
โ๏ธ At same T โ all gases have same average KE
@Ayano1me @Neetugpoll @Neetugquiz
โ๏ธ Explains macroscopic properties of gases
โ๏ธ Based on molecular motion
โ๏ธ Applies mainly to ideal gases
2๏ธโฃ #BASICPOSTULATES
โ๏ธ Gas consists of very large number of molecules
โ๏ธ Molecules are point masses (negligible volume)
โ๏ธ Distance between molecules โซ molecular size
โ๏ธ Molecules move randomly in all directions
3๏ธโฃ #NATUREOFMOLECULARMOTION
โ๏ธ Continuous
โ๏ธ Random
โ๏ธ Straight-line motion between collisions
๐ Velocity constantly changes due to collisions
4๏ธโฃ #INTERMOLECULARFORCES
โ๏ธ Negligible attractive forces
โ๏ธ No repulsion except during collision
๐ Valid only for ideal gases
5๏ธโฃ #COLLISIONS (VERY IMP ๐ฅ)
โ๏ธ Collisions are perfectly elastic
โ๏ธ Occur between:
โช๏ธ Moleculeโmolecule
โช๏ธ Moleculeโwall
๐ No loss of kinetic energy
6๏ธโฃ #PRESSUREOFGAS
โ๏ธ Due to collision of gas molecules with container walls
โ๏ธ More collisions โ more pressure
๐ Pressure โ number of collisions
7๏ธโฃ #KINETICENERGY
โ๏ธ Average kinetic energy depends only on temperature
โ๏ธ Independent of pressure & volume
๐ Formula:
Average K.E. = (3/2) kT (per molecule)
Average K.E. = (3/2) RT (per mole)
8๏ธโฃ #TEMPERATURESIGNIFICANCE
โ๏ธ Measure of average kinetic energy
โ๏ธ At 0 K โ molecular motion stops (ideal case)
๐ Higher T โ higher molecular speed
9๏ธโฃ #SPEEDOFGASMOLECULES
โ๏ธ Three types:
โช๏ธ Most probable speed (vโ)
โช๏ธ Average speed (vโแตฅ)
โช๏ธ RMS speed (vแตฃโโ)
๐ Relation:
vโ < vโแตฅ < vแตฃโโ
๐ #SPEEDFORMULAE (NEET FAVORITE โค๏ธ)
โ๏ธ vโ = โ(2RT / M)
โ๏ธ vโแตฅ = โ(8RT / ฯM)
โ๏ธ vแตฃโโ = โ(3RT / M)
๐ M in kg molโปยน
1๏ธโฃ1๏ธโฃ #GRAHAMLAW (LINKED CONCEPT)
โ๏ธ Rate โ 1 / โM
โ๏ธ Lighter gas diffuses faster
1๏ธโฃ2๏ธโฃ #DEVIATIONFROMIDEALBEHAVIOUR
โ๏ธ Real gases deviate at:
โช๏ธ High pressure
โช๏ธ Low temperature
๐ Cause:
โ๏ธ Finite molecular volume
โ๏ธ Intermolecular attraction
1๏ธโฃ3๏ธโฃ #LIMITATIONSOFKTG
โ Cannot explain liquefaction
โ Fails at high pressure
โ Assumes zero molecular volume
1๏ธโฃ4๏ธโฃ #NEETONELINERS
โ๏ธ Pressure independent of mass of gas
โ๏ธ KE โ absolute temperature
โ๏ธ Elastic collision = KE conserved
โ๏ธ At same T โ all gases have same average KE
@Ayano1me @Neetugpoll @Neetugquiz
โค2๐คฉ1๐1
Q1.
Assertion (A): Average kinetic energy of gas molecules is directly proportional to absolute temperature.
Reason (R): Increase in temperature increases the speed of gas molecules.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q2.
Assertion (A): At constant temperature, pressure of a gas is inversely proportional to volume.
Reason (R): Number of collisions of gas molecules with container walls increases when volume decreases.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Assertion (A): Root mean square (rms) speed of gas molecules depends on the nature of gas.
Reason (R): rms speed is inversely proportional to the square root of molar mass.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
๐ฏ2โค1๐ฅ1
1๏ธโฃ #THERMODYNAMICS
โ๏ธ Branch of chemistry dealing with energy changes
โ๏ธ Studies relation between heat, work & energy
โ๏ธ Does NOT tell rate or mechanism of reaction
2๏ธโฃ #THERMODYNAMICSYSTEM
โ๏ธ Part of universe under study
๐ Types:
โ๏ธ Open system โ exchanges mass + energy
โ๏ธ Closed system โ exchanges only energy
โ๏ธ Isolated system โ no exchange
3๏ธโฃ #SURROUNDINGS
โ๏ธ Rest of universe except system
๐ Universe = System + Surroundings
4๏ธโฃ #STATEFUNCTION
โ๏ธ Depends only on initial & final state
โ๏ธ Path independent
๐ Examples:
โ๏ธ Internal energy (U)
โ๏ธ Enthalpy (H)
โ๏ธ Entropy (S)
5๏ธโฃ #PATHFUNCTION
โ๏ธ Depends on path followed
๐ Examples:
โ๏ธ Heat (q)
โ๏ธ Work (w)
6๏ธโฃ #ZEROTHLAWOFTHERMODYNAMICS
โ๏ธ If A is in thermal equilibrium with B
โ๏ธ And B is in thermal equilibrium with C
โ๏ธ Then A is also in thermal equilibrium with C
๐ Basis of temperature measurement
7๏ธโฃ #FIRSTLAWOFTHERMODYNAMICS (VERY IMP )
โ๏ธ Law of conservation of energy
โ๏ธ Energy cannot be created or destroyed
๐ Mathematical form:
ฮU = q + w
โ๏ธ ฮU = change in internal energy
โ๏ธ q = heat absorbed by system
โ๏ธ w = work done on system
8๏ธโฃ #SIGNCONVENTION (NEET โ ๏ธ)
โ๏ธ Heat absorbed โ q = +ve
โ๏ธ Heat released โ q = โve
โ๏ธ Work done on system โ w = +ve
โ๏ธ Work done by system โ w = โve
9๏ธโฃ #WORKDONEINGASEXPANSION
โ๏ธ w = โPฮV
๐ Expansion (ฮV +ve) โ w โve
๐ Compression (ฮV โve) โ w +ve
๐ #SPECIALCASES
โ๏ธ At constant volume
w = 0
ฮU = q
โ๏ธ At constant pressure
qโ = ฮH
1๏ธโฃ1๏ธโฃ #ENTHALPY
โ๏ธ Heat content of system
โ๏ธ H = U + PV
๐ Change in enthalpy:
ฮH = ฮU + ฮ(PV)
1๏ธโฃ2๏ธโฃ #SECONDLAWOFTHERMODYNAMICS
โ๏ธ Natural processes occur in direction of increase in entropy
โ๏ธ Total entropy of universe always increases
๐ ฮS(universe) > 0 โ spontaneous
๐ ฮS(universe) = 0 โ equilibrium
1๏ธโฃ3๏ธโฃ #ENTROPY
โ๏ธ Measure of randomness or disorder
โ๏ธ Higher disorder โ higher entropy
๐ Solid < Liquid < Gas
1๏ธโฃ4๏ธโฃ #GIBBSFREEENERGY ( IMPORTANT )
โ๏ธ G = H โ TS
๐ Change in Gibbs energy:
ฮG = ฮH โ TฮS
โ๏ธ ฮG < 0 โ spontaneous
โ๏ธ ฮG = 0 โ equilibrium
โ๏ธ ฮG > 0 โ non-spontaneous
1๏ธโฃ5๏ธโฃ #THIRDLAWOFTHERMODYNAMICS
โ๏ธ Entropy of perfectly crystalline solid at 0 K is zero
๐ S = 0 at 0 K
1๏ธโฃ6๏ธโฃ #NEETONELINERS
โ๏ธ Internal energy is state function
โ๏ธ Heat & work are path functions
โ๏ธ First law is special case of energy conservation
โ๏ธ Entropy predicts spontaneity
โ๏ธ Gibbs energy decides feasibility
@Ayano1me @Neetugpoll @Neetugquiz
โ๏ธ Branch of chemistry dealing with energy changes
โ๏ธ Studies relation between heat, work & energy
โ๏ธ Does NOT tell rate or mechanism of reaction
2๏ธโฃ #THERMODYNAMICSYSTEM
โ๏ธ Part of universe under study
๐ Types:
โ๏ธ Open system โ exchanges mass + energy
โ๏ธ Closed system โ exchanges only energy
โ๏ธ Isolated system โ no exchange
3๏ธโฃ #SURROUNDINGS
โ๏ธ Rest of universe except system
๐ Universe = System + Surroundings
4๏ธโฃ #STATEFUNCTION
โ๏ธ Depends only on initial & final state
โ๏ธ Path independent
๐ Examples:
โ๏ธ Internal energy (U)
โ๏ธ Enthalpy (H)
โ๏ธ Entropy (S)
5๏ธโฃ #PATHFUNCTION
โ๏ธ Depends on path followed
๐ Examples:
โ๏ธ Heat (q)
โ๏ธ Work (w)
6๏ธโฃ #ZEROTHLAWOFTHERMODYNAMICS
โ๏ธ If A is in thermal equilibrium with B
โ๏ธ And B is in thermal equilibrium with C
โ๏ธ Then A is also in thermal equilibrium with C
๐ Basis of temperature measurement
7๏ธโฃ #FIRSTLAWOFTHERMODYNAMICS (VERY IMP )
โ๏ธ Law of conservation of energy
โ๏ธ Energy cannot be created or destroyed
๐ Mathematical form:
ฮU = q + w
โ๏ธ ฮU = change in internal energy
โ๏ธ q = heat absorbed by system
โ๏ธ w = work done on system
8๏ธโฃ #SIGNCONVENTION (NEET โ ๏ธ)
โ๏ธ Heat absorbed โ q = +ve
โ๏ธ Heat released โ q = โve
โ๏ธ Work done on system โ w = +ve
โ๏ธ Work done by system โ w = โve
9๏ธโฃ #WORKDONEINGASEXPANSION
โ๏ธ w = โPฮV
๐ Expansion (ฮV +ve) โ w โve
๐ Compression (ฮV โve) โ w +ve
๐ #SPECIALCASES
โ๏ธ At constant volume
w = 0
ฮU = q
โ๏ธ At constant pressure
qโ = ฮH
1๏ธโฃ1๏ธโฃ #ENTHALPY
โ๏ธ Heat content of system
โ๏ธ H = U + PV
๐ Change in enthalpy:
ฮH = ฮU + ฮ(PV)
1๏ธโฃ2๏ธโฃ #SECONDLAWOFTHERMODYNAMICS
โ๏ธ Natural processes occur in direction of increase in entropy
โ๏ธ Total entropy of universe always increases
๐ ฮS(universe) > 0 โ spontaneous
๐ ฮS(universe) = 0 โ equilibrium
1๏ธโฃ3๏ธโฃ #ENTROPY
โ๏ธ Measure of randomness or disorder
โ๏ธ Higher disorder โ higher entropy
๐ Solid < Liquid < Gas
1๏ธโฃ4๏ธโฃ #GIBBSFREEENERGY ( IMPORTANT )
โ๏ธ G = H โ TS
๐ Change in Gibbs energy:
ฮG = ฮH โ TฮS
โ๏ธ ฮG < 0 โ spontaneous
โ๏ธ ฮG = 0 โ equilibrium
โ๏ธ ฮG > 0 โ non-spontaneous
1๏ธโฃ5๏ธโฃ #THIRDLAWOFTHERMODYNAMICS
โ๏ธ Entropy of perfectly crystalline solid at 0 K is zero
๐ S = 0 at 0 K
1๏ธโฃ6๏ธโฃ #NEETONELINERS
โ๏ธ Internal energy is state function
โ๏ธ Heat & work are path functions
โ๏ธ First law is special case of energy conservation
โ๏ธ Entropy predicts spontaneity
โ๏ธ Gibbs energy decides feasibility
@Ayano1me @Neetugpoll @Neetugquiz
๐ฅ2โค1๐1๐1
Q1. Zeroth Law
Assertion (A): If two systems are separately in thermal equilibrium with a third system, they are in thermal equilibrium with each other.
Reason (R): All systems in thermal equilibrium have the same temperature.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q2. First Law
Assertion (A): Internal energy of an isolated system remains constant.
Reason (R): Energy can neither be created nor destroyed, only converted from one form to another.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q3. Second Law
Assertion (A): Heat cannot spontaneously flow from a colder body to a hotter body.
Reason (R): Total entropy of an isolated system always increases for a spontaneous process.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
Q4. Third Law
Assertion (A): Entropy of a perfectly crystalline substance is zero at absolute zero temperature.
Reason (R): At absolute zero, only one microstate is possible.
(1) A & R both true and R is correct explanation
(2) A & R both true but R is not correct explanation
(3) A true, R false
(4) A false, R true
๐คฉ3โค1๐ณ1
โญ ๐๐๐ ๐ชEE (๐๐ก, ๐๐, ๐ ๐ ๐ฆ๐ง๐๐ฅ, ๐ ๐๐ & so on) ๐ฎ๐ฌ๐ฎ๐ฒ
โญ ๐ข๐๐ ๐๐๐๐ง๐จ๐ฅ๐๐ฆ โ ๐จ๐ก๐๐ ๐ฌ + ๐๐ก ๐@๐ง๐ + ๐ฆ@๐ฉ@๐ + ๐ข๐ง๐๐๐ฅ ๐ง๐ข๐ฃ ๐ง๐๐๐๐๐๐ฅ๐ฆ
โญ ๐จ๐ก๐๐ ๐ฌ (๐ง๐ก๐ , ๐ฅ๐, ๐ฌ๐ฆ๐ฌ, ๐๐๐๐, ๐ฆ๐ง ๐ฆ๐๐ฅ, ๐๐ก๐ฆ๐๐ ๐๐๐ ๐ฆ๐๐ฅ & So On ) ๐ฎ๐ฌ๐ฎ๐ฒ
โญ ๐ฆ@๐ฉ@๐ (๐๐ ๐ฆ๐๐ฅ, ๐๐ฆ๐๐๐ฆ๐ ๐๐๐๐ฃ๐๐ฌ๐ ๐ฆ๐๐ฅ, ๐ฃ๐๐ฅ๐ฉ๐๐ญ ๐๐๐๐ก, ๐ฉ๐
๐ฆ๐๐ฅ & ๐ฆ๐ข ๐ข๐ก) ๐ฎ๐ฌ๐ฎ๐ฒ
โญ ๐๐ข๐ฃ๐ฌ๐ฅ๐๐๐๐ง ๐๐๐๐๐จ๐ฃ ๐ข๐ ๐๐๐ ๐ข๐ ๐ง๐๐๐ฆ
โญ ๐ข๐๐ ๐๐๐๐ง๐จ๐ฅ๐๐ฆ โ ๐จ๐ก๐๐ ๐ฌ + ๐๐ก ๐@๐ง๐ + ๐ฆ@๐ฉ@๐ + ๐ข๐ง๐๐๐ฅ ๐ง๐ข๐ฃ ๐ง๐๐๐๐๐๐ฅ๐ฆ
โญ ๐จ๐ก๐๐ ๐ฌ (๐ง๐ก๐ , ๐ฅ๐, ๐ฌ๐ฆ๐ฌ, ๐๐๐๐, ๐ฆ๐ง ๐ฆ๐๐ฅ, ๐๐ก๐ฆ๐๐ ๐๐๐ ๐ฆ๐๐ฅ & So On ) ๐ฎ๐ฌ๐ฎ๐ฒ
โญ ๐ฆ@๐ฉ@๐ (๐๐ ๐ฆ๐๐ฅ, ๐๐ฆ๐๐๐ฆ๐ ๐๐๐๐ฃ๐๐ฌ๐ ๐ฆ๐๐ฅ, ๐ฃ๐๐ฅ๐ฉ๐๐ญ ๐๐๐๐ก, ๐ฉ๐
๐ฆ๐๐ฅ & ๐ฆ๐ข ๐ข๐ก) ๐ฎ๐ฌ๐ฎ๐ฒ
โญ ๐๐ข๐ฃ๐ฌ๐ฅ๐๐๐๐ง ๐๐๐๐๐จ๐ฃ ๐ข๐ ๐๐๐ ๐ข๐ ๐ง๐๐๐ฆ
๐2๐1
Chemistry booster series
โญ ๐๐๐ ๐ชEE (๐๐ก, ๐๐, ๐ ๐ ๐ฆ๐ง๐๐ฅ, ๐ ๐๐ & so on) ๐ฎ๐ฌ๐ฎ๐ฒ โญ ๐ข๐๐ ๐๐๐๐ง๐จ๐ฅ๐๐ฆ โ ๐จ๐ก๐๐ ๐ฌ + ๐๐ก ๐@๐ง๐ + ๐ฆ@๐ฉ@๐ + ๐ข๐ง๐๐๐ฅ ๐ง๐ข๐ฃ ๐ง๐๐๐๐๐๐ฅ๐ฆ โญ ๐จ๐ก๐๐ ๐ฌ (๐ง๐ก๐ , ๐ฅ๐, ๐ฌ๐ฆ๐ฌ, ๐๐๐๐, ๐ฆ๐ง ๐ฆ๐๐ฅ, ๐๐ก๐ฆ๐๐ ๐๐๐ ๐ฆ๐๐ฅ & So On ) ๐ฎ๐ฌ๐ฎ๐ฒ โญ ๐ฆ@๐ฉ@๐ (๐๐ ๐ฆ๐๐ฅ, ๐๐ฆ๐๐๐ฆ๐ ๐๐๐๐ฃ๐๐ฌ๐ ๐ฆ๐๐ฅ, ๐ฃ๐๐ฅ๐ฉ๐๐ญ ๐๐๐๐ก, ๐ฉ๐ ๐ฆ๐๐ฅ & ๐ฆ๐ข ๐ข๐ก) ๐ฎ๐ฌ๐ฎ๐ฒ โญ ๐๐ข๐ฃ๐ฌ๐ฅ๐๐๐๐งโฆ
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๐1๐1๐ณ1
1๏ธโฃ #GIBBSFREEENERGY
โ๏ธ Thermodynamic state function
โ๏ธ Determines spontaneity of process
โ๏ธ Denoted by G
๐ Relation:
G = H โ TS
2๏ธโฃ #TERMSINFORMULA
โ๏ธ H โ Enthalpy
โ๏ธ T โ Absolute temperature (K)
โ๏ธ S โ Entropy
๐ Unit of G โ Joule
3๏ธโฃ #CHANGEINGIBBSENERGY
๐ Formula:
ฮG = ฮH โ TฮS
โ๏ธ Applies at constant T & P
4๏ธโฃ #SIGNIFICANCEOFฮG (VERY IMP )
โ๏ธ ฮG < 0 โ Spontaneous process
โ๏ธ ฮG = 0 โ Equilibrium
โ๏ธ ฮG > 0 โ Non-spontaneous
5๏ธโฃ #CASESBASEDONฮHANDฮS
โ๏ธ ฮH < 0 and ฮS > 0
Process spontaneous at all temperatures
โ๏ธ ฮH > 0 and ฮS < 0
Process non-spontaneous at all temperatures
โ๏ธ ฮH < 0 and ฮS < 0
Spontaneous at low temperature
โ๏ธ ฮH > 0 and ฮS > 0
Spontaneous at high temperature
6๏ธโฃ #TEMPERATUREEFFECT
โ๏ธ Increase in T increases importance of entropy term
โ๏ธ TฮS dominates at high temperature
7๏ธโฃ #GIBBSENERGYATEQUILIBRIUM
โ๏ธ At equilibrium:
ฮG = 0
๐ Relation with equilibrium constant:
ฮGยฐ = โRT ln K
8๏ธโฃ #STANDARDGIBBSFREEENERGY
โ๏ธ Measured at:
โ๏ธ 1 bar pressure
โ๏ธ 298 K temperature
๐ Formula:
ฮGยฐ = ฮHยฐ โ TฮSยฐ
9๏ธโฃ #REACTIONQUOTIENTRELATION
๐ Formula:
ฮG = ฮGยฐ + RT ln Q
โ๏ธ Q = reaction quotient
๐ At equilibrium Q = K
๐ #MAXIMUMWORKCONCEPT
โ๏ธ ฮG gives maximum non-expansion work
โ๏ธ Useful in electrochemistry
๐ Electrical work = โฮG
1๏ธโฃ1๏ธโฃ #GIBBSENERGYINELECTROCHEMISTRY
๐ Relation:
ฮGยฐ = โnFEยฐ
โ๏ธ n = number of electrons
โ๏ธ F = Faraday constant
โ๏ธ Eยฐ = standard emf
1๏ธโฃ2๏ธโฃ #UNITSOFฮG
โ๏ธ Joule
โ๏ธ kJ molโปยน (mostly used in chemistry)
1๏ธโฃ3๏ธโฃ #NEET
โ๏ธ ฮG decides feasibility, not rate
โ๏ธ Spontaneous โ fast
โ๏ธ ฮG depends on T, P & composition
โ๏ธ ฮG is state function
1๏ธโฃ4๏ธโฃ #ONELINEREVISION
โ๏ธ Gibbs free energy predicts spontaneity
โ๏ธ ฮG = 0 at equilibrium
โ๏ธ Negative ฮG โ feasible process
โ๏ธ ฮGยฐ related to K and Eยฐ
โ๏ธ Thermodynamic state function
โ๏ธ Determines spontaneity of process
โ๏ธ Denoted by G
๐ Relation:
G = H โ TS
2๏ธโฃ #TERMSINFORMULA
โ๏ธ H โ Enthalpy
โ๏ธ T โ Absolute temperature (K)
โ๏ธ S โ Entropy
๐ Unit of G โ Joule
3๏ธโฃ #CHANGEINGIBBSENERGY
๐ Formula:
ฮG = ฮH โ TฮS
โ๏ธ Applies at constant T & P
4๏ธโฃ #SIGNIFICANCEOFฮG (VERY IMP )
โ๏ธ ฮG < 0 โ Spontaneous process
โ๏ธ ฮG = 0 โ Equilibrium
โ๏ธ ฮG > 0 โ Non-spontaneous
5๏ธโฃ #CASESBASEDONฮHANDฮS
โ๏ธ ฮH < 0 and ฮS > 0
Process spontaneous at all temperatures
โ๏ธ ฮH > 0 and ฮS < 0
Process non-spontaneous at all temperatures
โ๏ธ ฮH < 0 and ฮS < 0
Spontaneous at low temperature
โ๏ธ ฮH > 0 and ฮS > 0
Spontaneous at high temperature
6๏ธโฃ #TEMPERATUREEFFECT
โ๏ธ Increase in T increases importance of entropy term
โ๏ธ TฮS dominates at high temperature
7๏ธโฃ #GIBBSENERGYATEQUILIBRIUM
โ๏ธ At equilibrium:
ฮG = 0
๐ Relation with equilibrium constant:
ฮGยฐ = โRT ln K
8๏ธโฃ #STANDARDGIBBSFREEENERGY
โ๏ธ Measured at:
โ๏ธ 1 bar pressure
โ๏ธ 298 K temperature
๐ Formula:
ฮGยฐ = ฮHยฐ โ TฮSยฐ
9๏ธโฃ #REACTIONQUOTIENTRELATION
๐ Formula:
ฮG = ฮGยฐ + RT ln Q
โ๏ธ Q = reaction quotient
๐ At equilibrium Q = K
๐ #MAXIMUMWORKCONCEPT
โ๏ธ ฮG gives maximum non-expansion work
โ๏ธ Useful in electrochemistry
๐ Electrical work = โฮG
1๏ธโฃ1๏ธโฃ #GIBBSENERGYINELECTROCHEMISTRY
๐ Relation:
ฮGยฐ = โnFEยฐ
โ๏ธ n = number of electrons
โ๏ธ F = Faraday constant
โ๏ธ Eยฐ = standard emf
1๏ธโฃ2๏ธโฃ #UNITSOFฮG
โ๏ธ Joule
โ๏ธ kJ molโปยน (mostly used in chemistry)
1๏ธโฃ3๏ธโฃ #NEET
โ๏ธ ฮG decides feasibility, not rate
โ๏ธ Spontaneous โ fast
โ๏ธ ฮG depends on T, P & composition
โ๏ธ ฮG is state function
1๏ธโฃ4๏ธโฃ #ONELINEREVISION
โ๏ธ Gibbs free energy predicts spontaneity
โ๏ธ ฮG = 0 at equilibrium
โ๏ธ Negative ฮG โ feasible process
โ๏ธ ฮGยฐ related to K and Eยฐ
๐ฅ2๐1๐1
โญ ๐๐๐ ๐ชEE ๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐ (๐๐ก, ๐๐, ๐ ๐ ๐ฆ๐ง๐๐ฅ, ๐ ๐๐ & so on) ๐ฎ๐ฌ๐ฎ๐ฒ
โญ ๐ข๐๐ ๐๐๐๐ง๐จ๐ฅ๐๐ฆ ๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐โ ๐จ๐ก๐๐ ๐ฌ + ๐๐ก ๐@๐ง๐ + ๐ฆ@๐ฉ@๐ + ๐ข๐ง๐๐๐ฅ ๐ง๐ข๐ฃ ๐ง๐๐๐๐๐๐ฅ๐ฆ
โญ ๐จ๐ก๐๐ ๐ฌ ๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐ (๐ง๐ก๐ , ๐ฅ๐, ๐ฌ๐ฆ๐ฌ, ๐๐๐๐, ๐ฆ๐ง ๐ฆ๐๐ฅ, ๐๐ก๐ฆ๐๐ ๐๐๐ ๐ฆ๐๐ฅ & So On ) ๐ฎ๐ฌ๐ฎ๐ฒ
โญ ๐ฆ@๐ฉ@๐ ๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐(๐๐ ๐ฆ๐๐ฅ, ๐๐ฆ๐๐๐ฆ๐ ๐๐๐๐ฃ๐๐ฌ๐ ๐ฆ๐๐ฅ, ๐ฃ๐๐ฅ๐ฉ๐๐ญ ๐๐๐๐ก, ๐ฉ๐
๐ฆ๐๐ฅ & ๐ฆ๐ข ๐ข๐ก) ๐ฎ๐ฌ๐ฎ๐ฒ
โญ ๐๐ข๐ฃ๐ฌ๐ฅ๐๐๐๐ง ๐๐๐๐๐จ๐ฃ ๐ข๐ ๐๐๐๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐ ๐ข๐ ๐ง๐๐๐ฆ
โญ ๐ข๐๐ ๐๐๐๐ง๐จ๐ฅ๐๐ฆ ๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐โ ๐จ๐ก๐๐ ๐ฌ + ๐๐ก ๐@๐ง๐ + ๐ฆ@๐ฉ@๐ + ๐ข๐ง๐๐๐ฅ ๐ง๐ข๐ฃ ๐ง๐๐๐๐๐๐ฅ๐ฆ
โญ ๐จ๐ก๐๐ ๐ฌ ๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐ (๐ง๐ก๐ , ๐ฅ๐, ๐ฌ๐ฆ๐ฌ, ๐๐๐๐, ๐ฆ๐ง ๐ฆ๐๐ฅ, ๐๐ก๐ฆ๐๐ ๐๐๐ ๐ฆ๐๐ฅ & So On ) ๐ฎ๐ฌ๐ฎ๐ฒ
โญ ๐ฆ@๐ฉ@๐ ๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐(๐๐ ๐ฆ๐๐ฅ, ๐๐ฆ๐๐๐ฆ๐ ๐๐๐๐ฃ๐๐ฌ๐ ๐ฆ๐๐ฅ, ๐ฃ๐๐ฅ๐ฉ๐๐ญ ๐๐๐๐ก, ๐ฉ๐
๐ฆ๐๐ฅ & ๐ฆ๐ข ๐ข๐ก) ๐ฎ๐ฌ๐ฎ๐ฒ
โญ ๐๐ข๐ฃ๐ฌ๐ฅ๐๐๐๐ง ๐๐๐๐๐จ๐ฃ ๐ข๐ ๐๐๐๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐ ๐ข๐ ๐ง๐๐๐ฆ
โค1๐ฅ1๐1
Chemistry booster series
โญ ๐๐๐ ๐ชEE ๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐ (๐๐ก, ๐๐, ๐ ๐ ๐ฆ๐ง๐๐ฅ, ๐ ๐๐ & so on) ๐ฎ๐ฌ๐ฎ๐ฒ โญ ๐ข๐๐ ๐๐๐๐ง๐จ๐ฅ๐๐ฆ ๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐โ ๐จ๐ก๐๐ ๐ฌ + ๐๐ก ๐@๐ง๐ + ๐ฆ@๐ฉ@๐ + ๐ข๐ง๐๐๐ฅ ๐ง๐ข๐ฃ ๐ง๐๐๐๐๐๐ฅ๐ฆ โญ ๐จ๐ก๐๐ ๐ฌ ๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐ (๐ง๐ก๐ , ๐ฅ๐, ๐ฌ๐ฆ๐ฌ, ๐๐๐๐, ๐ฆ๐ง ๐ฆ๐๐ฅ, ๐๐ก๐ฆ๐๐ ๐๐๐ ๐ฆ๐๐ฅ & So On ) ๐ฎ๐ฌ๐ฎ๐ฒ โญ ๐ฆ@๐ฉ@๐ ๐๐ฅ๐๐๐ ๐๐ข๐ฅ๐๐(๐๐ ๐ฆ๐๐ฅ, ๐๐ฆ๐๐๐ฆ๐ ๐๐๐๐ฃ๐๐ฌ๐โฆ
Join kr lena all bcz in sbke full lec + crash course+ handwriting notes +short notes + test All in one milega
Haar batch ka even more then batch content
Haar batch ka even more then batch content
โค1๐คฉ1๐1
Q1.
Assertion (A): For a spontaneous process at constant temperature and pressure, ฮG is negative.
Reason (R): Spontaneous processes occur with decrease in Gibbs free energy.
Options:
(1) A & R true, R correct explanation
(2) A & R true, R not explanation
(3) A true, R false
(4) A false, R true
Q2.
Assertion (A): When ฮG = 0, the system is at equilibrium.
Reason (R): At equilibrium, forward and backward reaction rates are equal
Q3.
Assertion (A): A reaction with ฮH < 0 and ฮS < 0 is spontaneous at all temperatures.
Reason (R): Decrease in enthalpy always favours spontaneity.
Q5. (Numerical concept)
Assertion (A): If ฮH = โ40 kJ and ฮS = โ100 J Kโปยน, reaction is spontaneous at low temperature.
Reason (R): Negative ฮS disfavors spontaneity at high temperature
๐1๐1๐ณ1