Yes, the pawn can be taken en passant. Which is practically forced, as Black is threatening to capture on h3. A bishop sac on g2 is also looming. 22…Kd8 23.Qe3 is less clear (23.Qxf7? Rxh3).
At the cost of another pawn, the king has found a safe place. All Black’s other pieces are pointing at the white king. White is utterly helpless.
Here the 1997 Junior World Champion slips up. He could have reached the desired better endgame with the cunning 30…Bxc6 31.Nxc6 Bf4 32.Bxf4 Nxf4 33.Nxd8 (33.Kf1 Rd7) 33…Ne2+ 34.Kf1 Nxc1 35.Nb7 Rc2.
Another mistake, after which White obtains a typical good knight versus bad bishop and is even a pawn to the good.
31…Rxc1 32.Rxc1 exd5 33.Nc6 Rc8! 34.Bxd6 Bb7 leaves White only slightly better.
37…Rb2 38.Rc3 Be2 39.Nb4 Bd1 40.Nxd5 Bxb3 41.Nxb6 Ba2 42.Rc6 Rb5 43.a4 Ra5 44.Rc5