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๐ŸŽžChemical Thermodynamics

โœ…Basic Terminology:

๐ŸŽฏSystem- Part of the universe under investigation.

๐ŸŽฏOpen System- A system which can exchange both energy and matter with its surroundings.

๐ŸŽฏClosed System- A system which permits passage of energy but not mass, across its boundary.

๐ŸŽฏIsolated system- A system which can neither exchange energy nor matter with its surrounding.

๐ŸŽฏSurroundings- Part of the universe other than system, which can interact with it.

๐ŸŽฏBoundary- Anything which separates system from surrounding.

๐ŸŽฏState variables- The variables which are required to be defined in order to define state of any system i.e. pressure, volume, mass, temperature, surface area, etc.

๐ŸŽฏState Functions- Property of system which depend only on the state of the system and not on the path. Example: Pressure, volume, temperature, internal energy, enthalpy, entropy etc.

๐ŸŽฏIntensive properties- Properties of a system which do not depend on mass of the system i.e. temperature, pressure, density, concentration,

๐ŸŽฏExtensive properties- Properties of a system which depend on mass of the system i.e. volume, energy, enthalpy, entropy etc.

๐ŸŽฏProcess- Path along which state of a system changes.

๐ŸŽฏIsothermal process- Process which takes place at constant temperature

๐ŸŽฏIsobaric process- Process which takes place at constant pressure

๐ŸŽฏIsochoric process- Process which takes place at constant volume.

๐ŸŽฏAdiabatic process- Process during which transfer of heat cannot take place between system and surrounding.

๐ŸŽฏCyclic process- Process in which system comes back to its initial state after undergoing series of changes.

๐ŸŽฏReversible process- Process during which the system always departs infinitesimally from the state of equilibrium i.e. its direction can be reversed at any moment.

๐ŸŽฏIrriversible Process- This type of process is fast and gets completed in a single step. This process cannot be reversed. All the natural processes are of this type.

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โœ…MODAL VERBS

๐Ÿ“šList of Modal Verbs

What is a modal verb?

The modal verbs of English are a small class of auxiliary verbs used to express possibility, obligation, advice, permission, ability, โ€ฆ

Modal verbs list in the English language: Can, Could, May, Might, Will, Would, Must, Shall, Should, Ought toโ€ฆ

Modal Verbs: Rules & Examples

Learn how and when to use modal verbs in English with rules and example sentences.

๐ŸŽฏ1. โ€˜Canโ€™ and โ€˜couldโ€™ are used to refer to skills and abilities.
For example:

He can cover a hundred metres in under ten seconds.

My father could see perfectly before the age of fifty.

I canโ€™t ride a horse.

๐ŸŽฏ2. โ€˜Mustโ€™ is used to indicate that something is necessary or of extreme importance, and โ€˜shouldโ€™ is used to suggest that something is advisable.
For example:

You must do your homework.

You mustnโ€™t skip school.

You should say sorry.

You shouldnโ€™t smoke.

๐ŸŽฏ3. โ€˜Canโ€™, โ€˜couldโ€™ and โ€˜mayโ€™ are used to ask for, give and withhold permission.
For example:

Can I try my hand at it?

Could we disperse early today?

You may not enter the premises.

๐ŸŽฏ4. โ€˜Willโ€™ and โ€˜wouldโ€™ are used to refer to habits and inclinations.
For example:

When I was a child, I would often climb trees.

I will never refuse you anything.

He would never do such a thing.

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แŠฅแˆตแŠช แ‹›แˆฌ แ‹ฐแŒแˆž แŠ แŠ•แ‹ณแŠ•แ‹ต แАแŒˆแˆฎแ‰ฝแŠ• แŠฅแŠ•แˆ›แˆญแข แˆˆ แˆ›แ‰ตแˆชแŠญ แ‹ญแŒ แ‰…แˆ›แˆแข

แŽแˆญแˆ™แˆ‹แŠ• แ‹ˆแ‹ฐ แŒŽแŠ• แˆˆแˆ˜แƒแ แˆตแˆˆแˆ›แ‹ญแˆ˜แ‰ฝ แ‹ˆแ‹ฐ แ‰ณแ‰ฝ แАแ‹ แ‹จแƒแแŠฉแ‰ตแข๐Ÿ˜”๐Ÿ˜”

โžก๏ธ Neither of
โžก๏ธ Either of
โžก๏ธ Each of
โžก๏ธ Every one of
+
Plural noun (subject)
+
Singular Verb.

แ‹ซแ‹ แŠฅแŠ•แ‹ฐแАแŒˆแˆญแŠณแ‰ฝแˆ แŽแˆญแˆ™แˆ‹แ‹แŠ• แ‹ˆแ‹ฐ แŒŽแŠ• แˆˆแˆ˜แƒแ แˆตแˆˆแˆ›แ‹ญแˆ˜แ‰ฝ แ‹ˆแ‹ฐ แ‰ณแ‰ฝ แАแ‹ แ‹จแƒแแŠฉแ‰ต แข แŠฅแˆตแŠช แŠฅแŠ“แ‰ฅแˆซแˆซแ‹๐Ÿ˜๐Ÿ˜

#1โญ Neither of

Neither of แŠซแˆแŠ• แ‰ แˆ—แˆ‹ แ‹จแˆšแˆ˜แŒฃแ‹ subject แˆ˜แˆ†แŠ• แ‹ซแˆˆแ‰ แ‰ต plural subject แАแ‹แข แŠจ plural subject แ‰ฑ แ‰€แŒฅแˆŽ แ‹จแˆšแˆ˜แŒฃแ‹ verb แ‹ฐแŒแˆž singular Verb แАแ‹แข๐Ÿค—๐Ÿค— แ‰ แŠ แŒญแˆฉ แŠจ Neither of แ‰€แŒฅแˆŽ plural subject แŠฅแŠ•แŒ แ‰€แˆ›แˆˆแŠ• แก verb แ‰ก แŒแŠ• ๐Ÿ™Š singular Verb แАแ‹ แ‹จแˆšแˆ†แАแ‹แข

๐Ÿค” Examples

Neither of the students....... disturbing now.

A) is B) are

โ˜น๏ธ๐Ÿ˜• แˆ˜แˆแˆฑ แˆแŠ•แ‹ตแŠ• แАแ‹ แ‹จแˆšแˆ†แАแ‹??

แŠฅแŠ•แŒแ‹ฒแˆ… แ‰…แ‹ตแˆ แŠฅแŠ•แ‹ฐแАแŒˆแˆญแŠณแ‰ฝแˆแก

แŠจ Neither of แ‰€แŒฅแˆŽ แ‹จแˆšแˆ˜แŒฃแ‹ plural subject แАแ‹แข แŠจ plural subject แ‰€แŒฅแˆŽ แ‹ฐแŒแˆž singular Verb แАแ‹แข๐Ÿ˜‡ แˆตแˆˆแ‹šแˆ… แ‰ แ‹šแˆ… แŒฅแ‹ซแ‰„ แˆ˜แˆฐแˆจแ‰ต

Neither of + the students ( plural subject) + is ( singular Verb ) แ‹ญแˆ†แŠ“แˆแข

แˆตแˆˆแ‹šแˆ… แˆ˜แˆแˆฑ

๐Ÿค— Neither of the students is disturbing now.

๐Ÿ˜ณ๐Ÿ˜ณ๐Ÿคฃ๐Ÿคฃ แŠ แ‹ญแŒˆแˆญแˆแˆ แŒแŠ•
The students แ‰ฐแ‰ฅแˆŽ is แŠ• แˆ˜แŒ แ‰€แˆแข แˆ…แŒ แˆ…แŒ แАแ‹ แŠ แˆˆ แ‰ฃแˆป๐Ÿฅบ๐Ÿฅบ

#2โญ Either of

Either of แŠซแˆแŠ• แ‰ แˆ—แˆ‹ แ‹จแˆšแˆ˜แŒฃแ‹ plural subject แˆฒแˆ†แŠ• แŠจ plural subject แ‰ฑ แ‰€แŒฅแˆŽ แ‹จแˆšแˆ˜แŒฃแ‹ verb แ‹ฐแŒแˆž singular Verb แАแ‹แข แ‰  แŠ แŒญแˆฉ

๐Ÿค— แŠจ Either of แ‰ แˆ—แˆ‹ plural subject แŠ• แŠฅแŠ•แŒ แ‰€แˆ›แˆˆแŠ•แก แŠจ plural subject แ‰ฑ แ‰ แˆ—แˆ‹ แ‹ฐแŒแˆž singular Verb แŠฅแŠ•แŒ แ‰€แˆ›แˆˆแŠ•แข

๐Ÿ˜๐Ÿ˜Example

Either of the workers....... to take the blame.

A) has B) have

๐Ÿ˜ข๐Ÿ˜ข แˆ˜แˆแˆฑ??? แˆแ‰ณ แ‰ แˆ‰๐Ÿ˜๐Ÿ˜

แ‰…แ‹ตแˆ แŠฅแŠ•แ‹ฐแАแŒˆแˆญแŠณแ‰ฝแˆ แŠจ Either of แ‰€แŒฅแˆŽ plural subject แŠฅแŠ•แŒ แ‰€แˆ›แˆˆแŠ• แข แŠจ plural subject แ‰€แŒฅแˆŽ แ‹ฐแŒแˆž singular Verb แŠฅแŠ•แŒ แ‰€แˆ›แˆˆแŠ•แข แˆตแˆˆแ‹šแˆ… แก แ‰ แ‹šแˆ… แŒฅแ‹ซแ‰„ แˆ˜แˆฐแˆจแ‰ต

แŠจ Either of แ‰€แŒฅแˆŽ แ‹ซแˆˆแ‹ the workers แ‹จแˆšแˆˆแ‹ plural subject แАแ‹แข แˆตแˆˆแ‹šแˆ… แŠจ plural subject แ‰ฑ แ‰€แŒฅแˆŽ แ‹จแˆšแˆ˜แŒฃแ‹ แ‹ฐแŒแˆž singular Verb แАแ‹ แข แˆตแˆˆแ‹šแˆ… แˆ˜แˆแˆฑ

Has แ‹ˆแ‹ญแˆต have ?? แ‰ฐแŠ“แŒˆแˆฉ แŠฅแŠ•แŒ…๐Ÿ˜‚๐Ÿ˜‚ แ‰ แ‰ƒ แŠฅแˆฑแŠ• แˆตแ‰ตแŒˆแˆจแ แ‰ณแ‹ˆแˆซแ‹‹แˆˆแˆ…แข๐Ÿ˜ข

แŠจ has แŠฅแŠ“ แŠจ have แ‹จแ‰ฑ แАแ‹ singular Verb?๐Ÿ˜ณ Has แАแ‹ แŠฅแˆบแข แˆตแˆˆแ‹šแˆ… แˆ˜แˆแˆฑ๐Ÿ‘‡๐Ÿ‘‡

๐Ÿค— Either of the workers has to take the blame.

๐Ÿ˜ค๐Ÿ˜ฑ แŠ แ‹ญแŒˆแˆญแˆแˆ แŒแŠ•?? The workers แ‰ฐแ‰ฅแˆŽ has แŠ• แˆตแŠ•แŒ แ‰€แˆแข แˆ…แŒ แˆ…แŒ แАแ‹๐Ÿค“


#3โญ Each of

Each of แŠซแˆแŠ• แ‰ แˆ—แˆ‹ แ‹จแˆšแˆ˜แŒฃแ‹ plural subject แˆฒแˆ†แŠ• แŠจ plural subject แ‰ฑ แ‰€แŒฅแˆŽ แ‹จแˆšแˆ˜แŒฃแ‹ verb แ‹ฐแŒแˆž singular Verb แ‹ญแˆ†แŠ“แˆแข แ‰ แŠ แŒญแˆฉ

แŠจ Each of แ‰ แˆ—แˆ‹ plural subject แŠ• แŠฅแŠ•แŒ แ‰€แˆ›แˆˆแŠ• แก แŠจ plural subject แ‰ฑ แ‰ แˆ—แˆ‹ แ‹ฐแŒแˆž singular Verb แŠฅแŠ•แŒ แ‰€แˆ›แˆˆแŠ•แข

๐Ÿค”๐Ÿ˜‹ Example

Each of the books ......... stolen yesterday.

A) was B) were

๐Ÿ˜Š Well แŠฅแŠ•แŒแ‹ฒแˆ… แŠจ Each of แ‰ แˆ—แˆ‹ the books แ‹จแˆšแˆˆแ‹แŠ• plural subject แАแ‹ แ‹จแˆ˜แŒฃแ‹แข แŠจ the books( แŠจ plural subject) แ‰ แˆ—แˆ‹ แ‹จแˆšแˆ˜แŒฃแ‹ แ‹ฐแŒแˆž singular Verb แАแ‹แข แˆตแˆˆแ‹šแˆ… was แ‹ˆแ‹ญแˆต were ?? แ‹จแ‰ฑ แАแ‹ singular Verb?? Was แАแ‹ แŠฃ แข แˆตแˆˆแ‹šแˆ… แˆ˜แˆแˆฑ

๐Ÿ˜บ๐Ÿ˜บ Each of the books was stolen yesterday.

๐Ÿ˜ฅแŒ‰แ‹ต แŠฅแŠฎ แАแ‹๐Ÿ˜‚ the books แ‰ฐแ‰ฅแˆŽ was๐Ÿ˜” แข แˆ…แŒ แˆ…แŒ แАแ‹แข

#4โญ Every one of

Every one of แŠซแˆแŠ• แ‰ แˆ—แˆ‹ แ‹จแˆšแˆ˜แŒฃแ‹ plural subject แˆฒแˆ†แŠ• แŠจ plural subject แ‰ฑ แ‰€แŒฅแˆŽ แ‹ฐแŒแˆž แ‹จแˆšแˆ˜แŒฃแ‹ singular Verb แ‹ญแˆ†แŠ“แˆแข

๐Ÿค” Example

Every one of the teachers ......... unhappy of his/her monthly salary.

A) is B) are

แŠจ Every one of แ‰ แˆ—แˆ‹ แ‹จแˆ˜แŒฃแ‹ the teachers แ‹จแˆšแˆˆแ‹ plural subject แАแ‹แข the teachers แŠจแˆšแˆˆแ‹ plural subject แ‰€แŒฅแˆŽ แ‹จแˆšแˆ˜แŒฃแ‹ verb แ‹ฐแŒแˆž singular Verb แАแ‹แข แˆตแˆˆแ‹šแˆ… แˆ˜แˆแˆฑ แก

๐Ÿ˜๐Ÿ˜’ Every one of the teachers is unhappy of his/her monthly salary.

"แŠ แ‹ญแŠจแ‰ฅแ‹ตแˆ แ‹ˆแ‹ญ แ‰ แˆแ‰ฅ แ‹ซแˆˆแŠ• แˆฐแ‹ แˆ˜แˆญแˆณแ‰ต" แŠ แˆˆ แ‹˜แ‹แŠ™๐Ÿ˜‚๐Ÿ˜‚

แŠ แ‹ญแŠจแ‰ฅแ‹ตแˆ แ‹ˆแ‹ญ the teachers แ‰ฐแ‰ฅแˆŽ is แŠ• แˆ˜แŒ แ‰€แˆแข๐Ÿ˜”๐Ÿ˜
แˆ…แŒ แˆ…แŒ แАแ‹ แ‰ฅแˆแˆ แ‰ฃแˆป๐Ÿ˜ก๐Ÿ˜ก

แŒแŠ• แŠฅแ‹šแŒ‹ แˆ›แˆตแ‰ฐแ‹‹แˆ แ‹ซแˆˆแ‰ฅแŠ• แАแŒˆแˆญ

Every of แŠ แ‹ญแ‰ฃแˆแˆแข แ‰ แˆ…แŒ แ‹ซแˆตแ‰€แŒฃแˆ ๐Ÿ™†โ€โ™‚๐Ÿ˜ณโ€ okay๐Ÿ˜’

Every one of แАแ‹ แ‹จแˆšแ‰ฃแˆˆแ‹๐Ÿ˜Š

แ‹จแ‹›แˆฌแ‹ แŠญแˆ‹แˆต แ‰ แ‹šแˆ… แ‹ญแ‰ฅแ‰ƒแŠ•๐Ÿ˜ข

๐Ÿ™ˆ แˆ›แˆตแ‰ณแ‹ˆแˆป ๐Ÿ™Š

แŠจแˆ‹แ‹ญ แ‹จแ‰ฐแˆ›แˆญแŠ“แ‰ธแ‹ แˆ…แŒŽแ‰ฝ แ‰  British English แ‰ฅแ‰ป แАแ‹ แ‹จแˆšแ‹ซแŒˆแˆˆแŒแˆ‰แ‰ตแข แ‰  American English แˆฒแˆ†แŠ• แ‹ฐแŒแˆž แˆŒแˆ‹ แˆ…แŒ แŠ แˆ‹แ‰ธแ‹แข แˆˆ Entrance แŒฅแ‹ซแ‰„ แŒแŠ• แˆ˜แˆแˆณแ‰ฝแŠ• แ‹จแˆšแˆ†แАแ‹ แ‰  British English แˆตแˆˆแˆ†แА แŠจแˆ‹แ‹ญ แ‹ซแˆˆแ‹แŠ• แŠ–แ‰ต แ‰ฐแˆจแ‹ฑแ‰ต๐Ÿค•๐Ÿค•

๐Ÿ™„ แˆ›แˆตแ‰ณแ‹ˆแˆป ๐Ÿ™†

"None of" แ‹ฐแŒแˆž แ‹จแˆซแˆฑ แ‹จแˆ†แА special case แŠ แˆˆแ‹แข แ‰ แ‰€แŒฃแ‹ญ แŠฅแŠ“แ‹จแ‹‹แˆˆแŠ•!

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